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Catalysis Letters

, Volume 112, Issue 1–2, pp 83–87 | Cite as

Heterogeneous Cu–Mn oxides mediate efficiently TEMPO-catalyzed aerobic oxidation of alcohols

  • Guanyu Yang
  • Jiping Ma
  • Wei Wang
  • Junfeng Zhao
  • Xuesong Lin
  • Lipeng Zhou
  • Xinqin Gao
Article

Cu–Mn oxides in combination of 2,2,6,6-tetramethyl-piperidyl-1-oxy (TEMPO) were firstly used to catalyze aerobic selective oxidation of alcohols to carbonyl compounds. Such recyclable heterogeneous cocatalysts showed good catalytic performance in the process when the molar ratio of Cu and Mn is over 1.

Keywords

Cu-Mn Oxides TEMPO catalysis aerobic oxidation alcohols 

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References

  1. 1.
    Lenoir, D. 2006Angew. Chem. Int. Ed.453206CrossRefGoogle Scholar
  2. 2.
    Zhan, B.-Z., Thompson, A. 2004Tetrahedron602917CrossRefGoogle Scholar
  3. 3.
    Mallat, T., Baiker, A. 2004Chem. Rev.1043037CrossRefGoogle Scholar
  4. 4.
    Sheldon, R.A., Arends, I.W.C.E. 2006J. Mol. Catal. A: Chemical251200CrossRefGoogle Scholar
  5. 5.
    Minisci, F., Punta, C., Recupero, F. 2006J. Mol. Catal. A: Chemical251129CrossRefGoogle Scholar
  6. 6.
    Liu, R.-H., Liang, X.-M., Dong, C.-Y., Hu, X.-Q. 2004J. Am. Chem. Soc.1264112CrossRefGoogle Scholar
  7. 7.
    Liu, R.-H., Liang, X.-M., Dong, C.-Y., Wang, X.-J., Hu, X.-Q. 2005J. Org. Chem.70729CrossRefGoogle Scholar
  8. 8.
    Herrerías, C.I., Zhang, T.Y., Li, C.-J. 2006Tetrahedron Lett.4713CrossRefGoogle Scholar
  9. 9.
    Cecchetto, A., Fontana, F., Miniscia, F., Recupero, F. 2001Tetrahedron Lett.426651CrossRefGoogle Scholar
  10. 10.
    Semmelhack, M.F., Schmid, C.R., Cortés, D.A., Chou, C.S. 1984J. Am. Chem. Soc.1063374CrossRefGoogle Scholar
  11. 11.
    Ragagnin, G., Betzemeier, B., Quici, S., Knochel, P. 2002Tetrahedron583985CrossRefGoogle Scholar
  12. 12.
    P. Gamez, I.W.C.E. Arends, J. Reedijk and R.A. Sheldon, Chem. Commun. (2003) 2414Google Scholar
  13. 13.
    A. Dijksman, I.W.C.E. Arends and R.A. Sheldon, Chem. Commun. (1999) 1591Google Scholar
  14. 14.
    Herrmann, W.A., Zoller, J.P., Fischer, R.W. 1999J. Organomet. Chem.579404CrossRefGoogle Scholar
  15. 15.
    Cicchi, S., Marradi, M., Goti, A., Brandi, A. 2001Tetrahedron Lett.426503CrossRefGoogle Scholar
  16. 16.
    Li, X.-Q., Xu, J., Wang, F., Gao, J., Zhou, L.-P., Yang, G.-Y 2006Catal. Lett.108137CrossRefGoogle Scholar
  17. 17.
    Li, W.-B., Chu, W.-B., Zhuang, M., Hua, J. 2004Catal. Today93205CrossRefGoogle Scholar
  18. 18.
    G. Cahiez and M. Alami, Encyclopedia of Reagents for Organic Synthesis (John Wiley and Sons, New York, 2001, Online)Google Scholar
  19. 19.
    Son, Y.-C., Makwana, V.D., Howell, A.R., Suib, S.L. 2001Angew. Chem. Int. Ed.404280CrossRefGoogle Scholar
  20. 20.
    Zhou, L.-P., Xu, J., Miao, H., Li, X-Q., Wang, F. 2005Catal. Lett.99231CrossRefGoogle Scholar
  21. 21.
    Mirzaei, A.A., Shaterian, H.R., Habibi, M., Hutchings, G.J., Taylor, S.H. 2003Appl. Catal. A: General253499CrossRefGoogle Scholar
  22. 22.
    F. Wang, G.-Y. Yang, W. Zhang, W.-H. Wu and J. Xu, Chem. Commun. (2003) 1172Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Guanyu Yang
    • 1
  • Jiping Ma
    • 1
  • Wei Wang
    • 1
  • Junfeng Zhao
    • 1
  • Xuesong Lin
    • 1
  • Lipeng Zhou
    • 1
  • Xinqin Gao
    • 2
  1. 1.Department of ChemistryZhengzhou UniversityZhengzhouP.R. China
  2. 2.State Key Laboratory of Fine ChemicalsDalian University of TechnologyDalianP.R. China

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