Skip to main content
Log in

Heterogeneous Cu–Mn oxides mediate efficiently TEMPO-catalyzed aerobic oxidation of alcohols

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Cu–Mn oxides in combination of 2,2,6,6-tetramethyl-piperidyl-1-oxy (TEMPO) were firstly used to catalyze aerobic selective oxidation of alcohols to carbonyl compounds. Such recyclable heterogeneous cocatalysts showed good catalytic performance in the process when the molar ratio of Cu and Mn is over 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Lenoir (2006) Angew. Chem. Int. Ed. 45 3206 Occurrence Handle10.1002/anie.200502702 Occurrence Handle1:CAS:528:DC%2BD28XlsVOht70%3D

    Article  CAS  Google Scholar 

  2. B.-Z. Zhan A. Thompson (2004) Tetrahedron 60 2917 Occurrence Handle10.1016/j.tet.2004.01.043 Occurrence Handle1:CAS:528:DC%2BD2cXhvV2ksrk%3D

    Article  CAS  Google Scholar 

  3. T. Mallat A. Baiker (2004) Chem. Rev. 104 3037 Occurrence Handle10.1021/cr0200116 Occurrence Handle1:CAS:528:DC%2BD2cXis1Cjtb8%3D

    Article  CAS  Google Scholar 

  4. R.A. Sheldon I.W.C.E. Arends (2006) J. Mol. Catal. A: Chemical 251 200 Occurrence Handle10.1016/j.molcata.2006.02.016 Occurrence Handle1:CAS:528:DC%2BD28XjvFylurk%3D

    Article  CAS  Google Scholar 

  5. F. Minisci C. Punta F. Recupero (2006) J. Mol. Catal. A: Chemical 251 129 Occurrence Handle10.1016/j.molcata.2006.02.011 Occurrence Handle1:CAS:528:DC%2BD28XjvFyltbw%3D

    Article  CAS  Google Scholar 

  6. R.-H. Liu X.-M. Liang C.-Y. Dong X.-Q. Hu (2004) J. Am. Chem. Soc. 126 4112 Occurrence Handle10.1021/ja031765k Occurrence Handle1:CAS:528:DC%2BD2cXhvF2iur4%3D

    Article  CAS  Google Scholar 

  7. R.-H. Liu X.-M. Liang C.-Y. Dong X.-J. Wang X.-Q. Hu (2005) J. Org. Chem. 70 729 Occurrence Handle10.1021/jo048369k Occurrence Handle1:CAS:528:DC%2BD2cXhtFCrur%2FP

    Article  CAS  Google Scholar 

  8. C.I. Herrerías T.Y. Zhang C.-J. Li (2006) Tetrahedron Lett. 47 13 Occurrence Handle10.1016/j.tetlet.2005.10.123

    Article  Google Scholar 

  9. A. Cecchetto F. Fontana F. Miniscia F. Recupero (2001) Tetrahedron Lett. 42 6651 Occurrence Handle10.1016/S0040-4039(01)01245-X Occurrence Handle1:CAS:528:DC%2BD3MXmt1yqsbc%3D

    Article  CAS  Google Scholar 

  10. M.F. Semmelhack C.R. Schmid D.A. Cortés C.S. Chou (1984) J. Am. Chem. Soc. 106 3374 Occurrence Handle10.1021/ja00323a064 Occurrence Handle1:CAS:528:DyaL2cXitVylsbc%3D

    Article  CAS  Google Scholar 

  11. G. Ragagnin B. Betzemeier S. Quici P. Knochel (2002) Tetrahedron 58 3985 Occurrence Handle10.1016/S0040-4020(02)00250-8 Occurrence Handle1:CAS:528:DC%2BD38Xjtlyjs74%3D

    Article  CAS  Google Scholar 

  12. P. Gamez, I.W.C.E. Arends, J. Reedijk and R.A. Sheldon, Chem. Commun. (2003) 2414

  13. A. Dijksman, I.W.C.E. Arends and R.A. Sheldon, Chem. Commun. (1999) 1591

  14. W.A. Herrmann J.P. Zoller R.W. Fischer (1999) J. Organomet. Chem. 579 404 Occurrence Handle10.1016/S0022-328X(99)00013-3 Occurrence Handle1:CAS:528:DyaK1MXktVGqt70%3D

    Article  CAS  Google Scholar 

  15. S. Cicchi M. Marradi A. Goti A. Brandi (2001) Tetrahedron Lett. 42 6503 Occurrence Handle10.1016/S0040-4039(01)01222-9 Occurrence Handle1:CAS:528:DC%2BD3MXmtFGitbk%3D

    Article  CAS  Google Scholar 

  16. X.-Q. Li J. Xu F. Wang J. Gao L.-P. Zhou G.-Y Yang (2006) Catal. Lett. 108 137 Occurrence Handle10.1007/s10562-006-0034-x Occurrence Handle1:CAS:528:DC%2BD28XktVaqtbw%3D

    Article  CAS  Google Scholar 

  17. W.-B. Li W.-B. Chu M. Zhuang J. Hua (2004) Catal. Today 93 205 Occurrence Handle10.1016/j.cattod.2004.06.042

    Article  Google Scholar 

  18. G. Cahiez and M. Alami, Encyclopedia of Reagents for Organic Synthesis (John Wiley and Sons, New York, 2001, Online)

  19. Y.-C. Son V.D. Makwana A.R. Howell S.L. Suib (2001) Angew. Chem. Int. Ed. 40 4280 Occurrence Handle10.1002/1521-3773(20011119)40:22<4280::AID-ANIE4280>3.0.CO;2-L Occurrence Handle1:CAS:528:DC%2BD3MXovFeisbc%3D

    Article  CAS  Google Scholar 

  20. L.-P. Zhou J. Xu H. Miao X-Q. Li F. Wang (2005) Catal. Lett. 99 231 Occurrence Handle10.1007/s10562-005-2128-2 Occurrence Handle1:CAS:528:DC%2BD2MXovFOnsQ%3D%3D

    Article  CAS  Google Scholar 

  21. A.A. Mirzaei H.R. Shaterian M. Habibi G.J. Hutchings S.H. Taylor (2003) Appl. Catal. A: General 253 499 Occurrence Handle10.1016/S0926-860X(03)00563-5 Occurrence Handle1:CAS:528:DC%2BD3sXot1Gqurk%3D

    Article  CAS  Google Scholar 

  22. F. Wang, G.-Y. Yang, W. Zhang, W.-H. Wu and J. Xu, Chem. Commun. (2003) 1172

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guanyu Yang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yang, G., Ma, J., Wang, W. et al. Heterogeneous Cu–Mn oxides mediate efficiently TEMPO-catalyzed aerobic oxidation of alcohols. Catal Lett 112, 83–87 (2006). https://doi.org/10.1007/s10562-006-0168-x

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-006-0168-x

Keywords

Navigation