Advertisement

Catalysis Letters

, Volume 104, Issue 1–2, pp 53–56 | Cite as

Catalytic Oxidation of Cyclohexane and Cyclooctene over a New Metalloporphyrin Supported on VOPO4 Catalyst

  • E. C. Zampronio
  • M. C. A. F. Gotardo
  • M. D. Assis
  • H. P. Oliveira
Article

In this work, we report the use of oxovanadium phosphate as support of the 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin iron (III) chloride (Fe(TDCPP)Cl) and of the 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin manganese (III) chloride (Mn(TDCPP)Cl) catalysts for cyclohexane and cyclooctene oxidations by iodosylbenzene. The catalytic results have shown that oxovanadium phosphate support is suitable for metalloporphyrin catalysts leading to an efficient system for the cyclooctene epoxidation and very selective for cyclohexane hydroxylation.

Keywords

oxovanadium phosphate metalloporphyrin epoxidation cyclooctene 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Groves, J.T., Nemo, T.E., Myers, R.S. 1979J. Am. Chem. Soc.1011032CrossRefGoogle Scholar
  2. 2.
    Cui, F., Dolphin, D. 1992Can. J. Chem.702314Google Scholar
  3. 3.
    B. Meunier, A. Robert, G. Pratviel and J. Bernadou, in: The Porphyrin Handbook, eds. K.M. Kadish, K.M. Smith and R. Guilard (Academic Press, New York, London, 2000) ch. 31Google Scholar
  4. 4.
    Mansuy, D. 1990Pure Appl Chem.62741Google Scholar
  5. 5.
    Dolphin, D., Traylor, T.G., Xie, L.Y. 1997Acc. Chem. Res.30251CrossRefGoogle Scholar
  6. 6.
    Bediuoui, F. 1995Coord. Chem. Rev.14439CrossRefGoogle Scholar
  7. 7.
    Evans, S., Lindsay Smith, J.R. 2001J. Chem. Soc., Perkin Trans.2174Google Scholar
  8. 8.
    J.R.L. Smith, in: Metalloporphyrins in Catalytic Oxidations, ed. R.A. Sheldon (Marcel Dekker, New York, 1994)Google Scholar
  9. 9.
    Sharefkin, G., Saltzman, H. 1963Org. Synth.4362Google Scholar
  10. 10.
    Johnson, J.W., Jacobson, A.J., Brody, J.F., Rich, S.M. 1982Inorg. Chem.213820CrossRefGoogle Scholar
  11. 11.
    Aldler, A.D., Longo, F.R., Kampas, F., Kim, J. 1970J. Inorg. Nucl. Chem.322443CrossRefGoogle Scholar
  12. 12.
    Kadish, K.M., Araullo-MacAdams, C., Han, B.C., Franzen, M.M. 1990J. Am. Chem. Soc.1128364CrossRefGoogle Scholar
  13. 13.
    Smith, K.M. 1975Porphyrins and MetalloporphyrinsElsevier Scientific Publishing CompanyAmsterdamGoogle Scholar
  14. 14.
    Doro, F.G., Lindsay Smith, J.R., Ferreira, A.G., Assis, M.D. 2000J. Mol. Catal. A : Chem.16497CrossRefGoogle Scholar
  15. 15.
    Schiavon, M.A., Iamamoto, Y., Nascimento, O.R., Assis, M.D. 2001J. Mol. Catal. A: Chem.174213CrossRefGoogle Scholar
  16. 16.
    Nakagaki, S., Machado, A.M., Wypych, F., Drechsel, S.M. 2002J. Colloid Interf. Sci.254158CrossRefGoogle Scholar
  17. 17.
    Assis, M.D., Lindsay Smith, J.R. 1998J. Chem. Soc., Perkin Trans.22221Google Scholar
  18. 18.
    Benedito, F.L., Nakagaki, S., Saczk, A.A., Peralta-Zamora, P.G., Costa, C.M.M. 2003Appl. Catal. A: Gen.2501CrossRefGoogle Scholar
  19. 19.
    Ayyappan, P., Ramanan, A., Torardi, C.C. 1998Inorg. Chem.373628CrossRefPubMedGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • E. C. Zampronio
    • 1
  • M. C. A. F. Gotardo
    • 1
  • M. D. Assis
    • 1
  • H. P. Oliveira
    • 1
  1. 1.Departamento de Química, FFCLRPUniversidade de São PauloRibeirão PretoBrasil

Personalised recommendations