Skip to main content
Log in

“Ethane oxychlorination” over γ-Al2O3 supported CuCl2–KCl–LaCl3

  • Published:
Catalysis Letters Aims and scope Submit manuscript

A study on γ-Al2O3 supported CuCl2/KCl/LaCl3 for ethane oxychlorination was carried out by means of XRD, XPS,TGA/DTA, BET TEM and ICP. The experimental results indicate that the catalytic properties of the 5 wt,%Cu–6 wt.%K–5 wt.%La/γ-A12O3 are optimal. This catalyst was studied in more detail and it was found that deactivation of the catalyst was due to carbon deposition and loss of active species of Cu+2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J.A. Allen A.J. Clark (1971) Rev. Pure Appl. Chem. 21 145

    Google Scholar 

  2. C.N. Kenney (1975) Catal. Rev. Sci. Eng. 11 IssueID2 197

    Google Scholar 

  3. J. Villadsen H. Livberg (1978) Catal. Rev. Scv. Eng. 17 IssueID2 203

    Google Scholar 

  4. J.S. Naworsky and E.S. Velez, Applied Industrial Catalysis, vol. 1 (Academic Press, San Diego, 1983), p. 239

  5. Yu. A. Treger V.N. Rozanov M.R. Hid L.M. Kartaschov (1988) Vsp. Khim. 57 IssueID4 577

    Google Scholar 

  6. H. Rigel H.D. Schindler M.C. Sze (1973) Chem. Eng. Progr. 69 IssueID10 89

    Google Scholar 

  7. J.A. Little C.N. Kenney (1985) J. Catal. 93 23

    Google Scholar 

  8. Lü Xueju Fei Qiang Cheng Tiexin et al. (2003) Chem. J. Chinese. Univ. 24 522

    Google Scholar 

  9. M. Fernández-García E. Gómez Rebollo A. Guerrero Ruiz et al. (1997) J. Catal. 172 146

    Google Scholar 

  10. M.R. Flid I.I. Kurlyandskaya Yu.A. Treger et al. (1997) The Proceeding of 3rd World Congress on Oxidation Catalysis Elsevier Science B.V. San Diego 305–313

    Google Scholar 

  11. G. Leofanti M. Padovan M. Garilli et al. (2000) J. Catal. 189 105

    Google Scholar 

  12. E. Finocchio N. Rossi G. Busca et al. (1998) J. Catal. 179 606

    Google Scholar 

  13. D. Carmello E. Finocchio A. Marsella et al. (2000) J. Catal. 191 354

    Google Scholar 

  14. G. Leofanti M. Padovan M. Garilli et al. (2000) J. Catal. 189 91

    Google Scholar 

  15. Handbook of Chem. Phys. 1981–1982 ed. Published by Chemical Rubber Company

  16. V.K. Kaushik (1989) Spectrochim. Acta 44B 581

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Tiexin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xueju, L., Jie, L., Guangdong, Z. et al. “Ethane oxychlorination” over γ-Al2O3 supported CuCl2–KCl–LaCl3. Catal Lett 100, 153–159 (2005). https://doi.org/10.1007/s10562-004-3448-3

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-004-3448-3

Keywords:

Navigation