The characteristics of the granular polymer material plasticization process in a plasticizer shear flow are studied. A mathematical model of the process, which fully conforms to the modern concepts of the plasticization mechanism and allows determination of the key process parameters, particularly the plasticization time, under intense shear impact on the polymer granules, is proposed. This model provides the possibility of performing technological calculations even at the stage of designing mixing equipment for preparation of highly viscous polymer solutions.
Similar content being viewed by others
References
A. A. Tager, Physical Chemistry of Polymers [in Russian], 4th Revised and Enlarged Edition, Nauchnyi Mir, Moscow (2007).
S. P. Papkov, P hysicochemical Principles of Polymer Solutions Treatment [in Russian], Khimiya, Moscow (1971).
Yu. P. Gupalo, A. D. Polyanin, and Yu. S. Ryazantsev, Mass and Heat Exchange of Reacting Particles with a Flow [in Russian], Nauka, Moscow (1985).
D. W. van Krevelen, Properties and Chemical Structure of Polymers [Russian translation from English], Khimiya, Moscow (1976).
G. A. Akselrud and A. D. Molchanov, Dissolution of Solid Substances [in Russian], Khimiya, Moscow (1977), p. 272.
M. V. Lebedev and O. V. Tin’kov, “Special features of dispersed solid materials dissolution process in shear flow of a viscous liquid,” Khim. Neftegaz. Mashinostr., No. 1, 3–6 (2018).
A. A. Askadskii, M. N. Popova, and A. E. Volodina, “Analysis of dependencies of plasticized polymer fluidity temperature on chemical structure and concentration of polymer and plasticizer,” Vestn. MGSU, No. 10, 147–153 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, Vol. 54, Nos. 5–6, pp. 3–7, June, 2018.
Rights and permissions
About this article
Cite this article
Lebedev, M.V., Tin’kov, O.V. & Generalov, M.B. Calculation of Parameters of Granular Polymer Material Plasticization Process Under Intense Shear Impact. Chem Petrol Eng 54, 371–378 (2018). https://doi.org/10.1007/s10556-018-0489-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10556-018-0489-9