The Influence of Ruthenium Nanoparticle Size on the Activity of Benzene Hydrogenation Catalysts

Ruthenium nanoparticles of varying sizes were synthesized under microwave radiation and deposited on natural aluminosilicate nanotubes. The catalytic properties of the materials obtained in the hydrogenation reaction of benzene were studied, and the influence of ruthenium nanoparticle size effect on the activity of the synthesized catalysts was determined. Conversions, activation energies, turn-over frequency, and rate constants of reactions were defined.

This is a preview of subscription content, log in to check access.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. 1.

    Technical Regulation of the Customs Union TR TS 013/2011 “On Requirements for Automobile and Aviation Gasoline, Diesel and Marine Fuel, Jet Fuel and Fuel Oil”. Adopted by the decision of the Commission of the Customs Union No. 826 of 10/18/2011 [in Russian].

  2. 2.

    TIM. Kapustin, Problems and Prospects for the Development of Russian Oil Refining [in Russian], Workshop “Oil Refining: World and Russia” of the Forum “Oil and Gas Dialogue” IMEMO RAS Moscow, March 22, 2011 (http://www.imemo.ru/en/conf/2011/22032011/2203_kPdf).

  3. 3.

    M. Peyrovi, N. Parsafard, and Z. Mohammadian, Chin. J. Chem. Eng., 26, 521-528 (2018).

  4. 4.

    Z. Mohammadian, M. Peyrovi, and N. Parsafard, Chem. Phys. Lett., 715, 367-374 (2019).

  5. 5.

    J. Bart and S. Cavallaro, Ind. Eng. Chem. Res., 54, 1-46 (2015).

  6. 6.

    Information and Technical Handbook of the Best Available Technologies [in Russian], Russian BAT Bureau, (2017).

  7. 7.

    Z. Mohammadian, Al. Peyrovi, and N. Parsafard, Chem. Set, 4, 11116 (2019).

  8. 8.

    H. Zhang, V. Meng, G. Song et at, Synth. React. Inorg. M., 46, 940-944 (2016).

  9. 9.

    H. Liu, R. Fang, Z. Li et al., Chem. Eng. Sci., 122, 350-359 (2015).

  10. 10.

    A. Glotov, A. Stavitskaya, Y. Chudakov et al., Bull. Chem. Soc. Japan, 92, 61-69 (2019).

  11. 11.

    V Vinokurov, A. Glotov, Y. Chudakov et at, Ind. Eng. Chem. Res., 56, 14043-14052 (2017).

  12. 12.

    G. Zhou, L. Jiang, and D. He, J. Catal., 369, 352-362 (2019).

  13. 13.

    L. Zhu, H. Sun, H. Fu et at, Appl. Catal. A: General, 499, 124-132 (2015).

  14. 14.

    X. Fu, Z. Ding, X Zhang et al., Nanosc. Res. Lett., 9, 282 (2014).

  15. 15.

    K. Murugesan, T Senthamarai, M. Sohail et at, Chem. Sci., 9, 8553-8560 (2018).

  16. 16.

    M. Peyrovi, N. Parsafard, and M. Hajiabadi, Int. J. Chem. Kinet., 49, 283-292 (2017).

  17. 17.

    A.P. Glotov, A.V. Stavitskaya, Y.A. Chudakov et al., Petrol. Chem., 58, No. 14, 1221-1226 (2018).

  18. 18.

    Y Lvov, W. Wang, L. Zhang et al., Adv. Mat., 28, 1227 (2016).

  19. 19.

    V Vinokurov, A. Stavitskaya, A. Glotov et al., J. Solid. St. Chem., 268, 182-189 (2018).

  20. 20.

    V.V. Nedolivko, GO. Zasypalov, Y.A. Chudakov et al., Russ. Chem. Bull., 69, 260-264 (2020).

  21. 21.

    L. Wang, J. Chen, L. Ge et al., J. Phys. Chem. C, 117, 4141 (2013).

  22. 22.

    Q. Wang, Y Wang, Y Zhao et al., Crystengcomm, 17, 3110 (2015).

  23. 23.

    Y Ouyang, B. Guo, L. Fu et al., Mater. and Des., 110, 169 (2016).

Download references

The study was supported by a RFBR grant, project No. 1833-00925 mol_a and carried out as part of a State Assignment, project No. 0768-2020-0007.

Author information

Affiliations

Authors

Corresponding author

Correspondence to Ya.A. Chudakov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 2, pp. 7 – 11, March – April, 2020.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Chudakov, Y., Stytsenko, V., Zasypalov, G. et al. The Influence of Ruthenium Nanoparticle Size on the Activity of Benzene Hydrogenation Catalysts. Chem Technol Fuels Oils (2020). https://doi.org/10.1007/s10553-020-01121-x

Download citation

Keywords

  • halloysite
  • benzene hydrogenation
  • ruthenium
  • nanoparticles