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Oligomerization of Propane-Propylene Fraction of Oil Refinery Gases on Pillared Clay Based Superacidic Catalysts

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Chemistry and Technology of Fuels and Oils Aims and scope

Superacidic catalyst systems based on sulfated zirconia, mixed heteropoly acids, and nano-sized nickel powder applied on acid-activated montmorillonite are proposed. The mechanisms of the propane-propylene fraction oligomerization process on superacidic catalysts are studied in a wide range of temperatures, pressures, and volumetric feedstock feed rates. It is shown that catalysts with a degree of montmorillonite modification with 2.5% nano-sized nickel, which exhibit the best activity and propylene trimer selectivity, are the most promising from the viewpoint of introduction of the oligomerization process at oil-processing/refining enterprises.

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References

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The work is carried out within the framework of the project portion of the state task No. 10.2699.2014/K.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, Ufa, Russia

    Yu. A. Khamzin, R. R. Shiriyazdanov, A. R. Davletshin, F. Sh. Vil’danov, E. A. Ipatova, M. N. Rakhimov, E. G. Telyashev, R. R. Abdyushev & L. S. Doinitsyna

Authors
  1. Yu. A. Khamzin
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  2. R. R. Shiriyazdanov
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  3. A. R. Davletshin
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  4. F. Sh. Vil’danov
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  5. E. A. Ipatova
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  6. M. N. Rakhimov
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  7. E. G. Telyashev
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  8. R. R. Abdyushev
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  9. L. S. Doinitsyna
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Corresponding author

Correspondence to Yu. A. Khamzin.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 23 – 25, September – October, 2015.

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Khamzin, Y.A., Shiriyazdanov, R.R., Davletshin, A.R. et al. Oligomerization of Propane-Propylene Fraction of Oil Refinery Gases on Pillared Clay Based Superacidic Catalysts. Chem Technol Fuels Oils 51, 458–463 (2015). https://doi.org/10.1007/s10553-015-0625-6

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  • DOI: https://doi.org/10.1007/s10553-015-0625-6

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