Abstract
Activated carbon sorbents impregnated with KOH, Fe(NO3)3, Cu(NO3)2, Zn(NO3)2 or Co(NO3)2 and their applications in catalytic oxidation reaction of COS were investigated. The results showed that the activated carbon modified with 10 % (mass percentage) KOH enhanced the adsorption ability significantly. And it was also found that the oxygen content and temperature were the two most important factors in the COS adsorption. Further investigation on the pore structures of the samples with X-ray photoelectron spectroscopy indicated that an adsorption/oxidation process happened in the KOH modified activated carbon in which the major existing forms of sulfur were SO4 2− and S species. The oxidation of COS suggested that KOH in the micropores may play a catalytic role during the adsorption. On the other hand, we found that the desorption activation energy from KOHW was higher than that from AC by the CO2-TPD spectra, which indicated the adsorption of CO2 on KOH impregnated activated carbon was stronger. The strong adsorption could be attributed to the basic groups on the activated carbon surface. In conclusion, the activated carbon impregnated with KOH promises a good candidate for COS adsorbent.
Similar content being viewed by others
References
Cui, H., Turn, S.Q.: Adsorption/desorption of dimethylsulfide on activated carbon modified with iron chloride. Appl. Catal. B 88(1–2,29), 25–31 (2009)
Donohue, M.D., Aranovich, G.L.: Classification of Gibbs adsorption isotherms. Adv. Colloid Interface Sci. 76–77(1), 137–152 (1998)
Huang, H.M., Young, N., Williams, B.P., Taylor, S.H., Hutchings, G.: COS hydrolysis using zinc-promoted alumina catalysts. Catal. Lett. 104(1–2), 17–21 (2005)
Huang, H.M., Young, N., Williams, B.P., Taylor, S.H., Hutchings, G.: High temperature COS hydrolysis catalysed by γ-Al2O3. Catal. Lett. 110(3), 243–246 (2006a)
Huang, C.C., Chen, C.H., Chu, S.M.: Effect of moisture on H2S adsorption by copper impregnated activated carbon. J. Hazard. Mater. 136(3), 866–873 (2006b)
Jackson, S.D., Leeming, P., Webb, G.: Supported metal catalysts: preparation, characterisation, and function IV. Study of hydrogen sulphide and carbonyl sulphide adsorption on platinum catalysts. J. Catal. 160(2), 235–243 (1996)
Lee, Y.W., Kim, H.J., Park, J.W., Choi, B.U., Choi, D.K., Park, J.W.: Adsorption and reaction behavior for the simultaneous adsorption of NO–NO2 and SO2 on activated carbon impregnated with KOH. Carbon 41(10), 1881–1888 (2003)
Li, J., Li, Z., Liu, B., Xia, Q.B., Xi, H.X.: Effect of relative humidity on adsorption of formaldehyde on modified activated carbons. Chin. J. Chem. Eng. 16(6), 871–875 (2008)
Liu, Y.C., He, H., Mu, Y.J.: Heterogeneous reactivity of carbonyl sulfide on α-Al2O3 and γ-Al2O3. Atmos. Environ. 42(5), 960–969 (2008)
Lάszlό, K., Tombάcz, E., Josepovits, K.: Effect of activation on the surface chemistry of carbons from polymer precursors. Carbon 39(8), 1217–1228 (2001)
Ning, P., Yu, L.L., Yi, H.H., Tang, X.L., Li, H., Wang, H.Y., Yang, L.N.: Effect of Fe/Cu/Ce loading on the coal-based activated carbons for hydrolysis of carbonyl sulfide.J. Rare Earths 28(2), 205–210 (2010)
Ning, P., Wang, X.Y., Bart, H.J., Tian, S.L., Zhang, Y., Wang, X.Q.: Removal of phosphorus and sulfur from yellow phosphorus off-gas by metal-modified activated carbon. J. Clean. Prod. 19(13), 1547–1552 (2011)
Oliver, T.M., Jugoslav, K., Aleksandar, P., Nikola, D.: Synthetic activated carbons for the removal of hydrogen cyanide from air. Chem. Eng. Process. 44(11), 1181–1187 (2005)
Rhodes, C., Riddel, S.A., West J., Williams, B.P., Hutchings, G.J.: The low-temperature hydrolysis of carbonyl sulfide and carbon disulfide: a review. Catal. Today 59(3–4), 443–464 (2000)
Sakanishi, K.,Wu, Z.H., Matsumura, A., Saito, I., Hanaoka, T., Minowa, T., Tada, M., Iwasaki. T.: Simultaneous removal of H2S and COS using activated carbons and their supported catalysts. Catal. Today 104(1), 94–100 (2005)
Sattler, M.L., Garrepalli, D.R., Nawal, C.S.: Carbonyl sulfide removal with compost and wood chip biofilters, and in the presence of hydrogen sulfide. J. Air Waste Manag. Assoc. 59(12), 1458–1467 (2009)
Sattler, M.L., Rosenberk, R.S.: Removal of carbonyl sulfide using activated carbon adsorption. J. Air Waste Manag. Assoc. 56(2), 219–224 (2006)
Serrano, D.P., Calleja, G., Botas, J.A., Gutierrez, F.J.: Characterization of adsorptive and hydrophobic properties of silicalite-1, ZSM-5, TS-1 and Beta zeolites by TPD techniques. Sep. Purif. Technol. 54(1,15), 1–9 (2007)
Svoronos, P.D.N., Bruno, T.J.: Carbonyl sulfide: a review of its chemistry and properties. Ind. Eng. Chem. Res. 41(22), 5321–5336 (2002)
Sparks, D.E., Morgan, T., Patterson, P.M., Tackett, S.A., Morris, E., Crocker, M.: New sulfur adsorbents derived from layered double hydroxides I: synthesis and COS adsorption. Appl. Catal. B 82(3–4), 190–198 (2008)
Thomas, B., Williams, B.P., Young, N., Rhodes, C., Hutchings, G.J.: Ambient temperature hydrolysis of carbonyl sulfide using γ-alumina catalysts: effect of calcination temperature and alkali doping. Catal. Today 86(4), 201–205 (2003)
Tian, S.L., Mo, H., Zhang, R.F., Ning. P., Zhou, T.H.: Enhanced removal of hydrogen sulfide from a gas stream by 3-aminopropyltriethoxysilane-surface-functionalized activated carbon. Adsorption 15(5–6), 477–484 (2009)
Toops, T.J., Crocker, M.: New sulfur adsorbents derived from layered double hydroxides II. DRIFTS study of COS and H2S adsorption. Appl. Catal. B 82(3–4), 199–207 (2008)
Wang, H.Y., Yi, H.H., Ning, P., Tang, X.L., Yu, L.L., He, D., Zhao, S.: Calcined hydrotalcite-like compounds as catalysts for hydrolysis carbonyl sulfide at low temperature. Chem. Eng. J. 166(1), 99–104 (2011)
Wang, L., Wang, S.D., Yuan, Q., Lu, G.Z.: COS hydrolysis in the presence of oxygen: Experiment and modeling. J. Nat. Gas Chem. 17(1), 93–97 (2008)
Wang, X.Q., Ning, P., Shi, Y., Jiang, M.: Adsorption of low concentration phosphine in yellow phosphorus off-gas by impregnated activated carbon. J. Hazard. Mater. 171(1–3), 588–593 (2009)
Wang, X.Q., Qiu, J., Ning, P., Ren, X.G., Li, Z.Y., Yin, Z.F., Chen, W., Liu, W.: Adsorption/desorption of low concentration of carbonyl sulfide by impregnated activated carbon under micro-oxygen conditions. J. Hazard. Mater. 229–230, 128–136 (2012)
West, J., Williams, B.P., Young. N., Rhodes. C., Hutchings, G.J.: Ni- and Zn-promotion of γ-Al2O3 for the hydrolysis of COS under mild conditions. Catal. Commun. 2(3–4), 135–138 (2001)
Williams, B.P., Young, N.C., West, J., Rhodes, C., Hutchings, G.J.: Carbonyl sulphide hydrolysis using alumina catalysts. Catal. Today. 49(1–3), 99–104 (1999)
Xiao, Y.H., Wang, S.D., Wu, D.Y., Yuan, Q.: Catalytic oxidation of hydrogen sulfide over unmodified and impregnated activated carbon. Sep. Purif. Technol. 59(3,1), 326–332 (2008)
Yi, H.H., Yu, Q.F., Tang, X.L., Ning, P., Yang, L.P., Ye, Z.Q., Song, J.H.: Phosphine adsorption removal from yellow phosphorus tail gas over CuO–ZnO–La2O3/activated carbon. Ind. Eng. Chem. Res. 50(7), 3960–3965 (2011)
Yu, M.X., Li, Z., Xia, Q.B., Xi, H.X., Wang, S.W.: Desorption activation energy of dibenzothiophene on the activated carbons modified by different metal salt solutions. Chem. Eng. J. 132(1–3), 233–239 (2007)
Zhang, Y.Q., Xiao, Z.B., Ma, J.X.: Hydrolysis of carbonyl sulfide over rare earth oxysulfides. Appl. Catal. 48(1,8), 57–63 (2004)
Zhao, S.Z., Yi, H.H., Tang, X.L., Ning, P., Wang, H.Y., He, D.: Effect of Ce-doping on catalysts derived from hydrotalcite-like precursors for COS hydrolysis. J. Rare Earths 28(1), 329–333 (2010)
Acknowledgments
This work was supported by the National Natural Science Foundation of China (No. 51268021, U1137603, 51368026), 863 National High-tech Development Plan Foundation (No. 2012AA062504) and by Applied Basic Research Program of Yunnan (No. 2011FB027, 2011FA010).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, X., Ma, Y., Ning, P. et al. Adsorption of carbonyl sulfide on modified activated carbon under low-oxygen content conditions. Adsorption 20, 623–630 (2014). https://doi.org/10.1007/s10450-014-9607-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10450-014-9607-y