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A semi-analytical solution for electric double layers near an elliptical cylinder

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Abstract

A theoretical analysis on the electric double layer formed near the surface of an infinite cylinder with an elliptical cross section and a prescribed electric potential in an ionic conductor was performed using the linearized Gouy–Chapman theory. A semi-analytical solution in terms of the Mathieu functions was obtained. The distributions of the electric potential, cations, anions, and electric field were calculated. The effects of various physical and geometric parameters were examined. The fields vary rapidly near the elliptical boundary and are nearly uniform at far field. Electric field concentrations were found at the ends of the semi-major and semi-minor axes of the ellipse. These concentrations are sensitive to the physical and geometric parameters.

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References

  1. Masliyah, J.H., Bhattacharjee, S.: Electrokinetic and Colloid Transport Phenomena, Chap. 5. Wiley, New York (2006)

    Book  Google Scholar 

  2. Kornyshev, A.A.: Double-layer in ionic liquids: paradigm change? J. Phys. Chem. B 111, 5545–5557 (2007)

    Article  Google Scholar 

  3. Sampath, S., Choudhury, N.A., Shukla, A.K.: Hydrogel membrane electrolyte for electrochemical capacitors. J. Chem. Sci. 121, 727–734 (2009)

    Article  Google Scholar 

  4. Kalupson, J., Ma, D., Randall, C.A., et al.: Ultrahigh-power flexible electrochemical capacitors using binder-free single-walled carbon nanotube electrodes and hydrogel membranes. J. Phys. Chem. C 118, 2943–2952 (2014)

    Article  Google Scholar 

  5. Syahidah, S.N., Majid, S.R.: Ionic liquid-based polymer gel electrolytes for symmetrical solid-state electrical double layer capacitor operated at different operating voltages. Electrochim. Acta 175, 184–192 (2015)

    Article  Google Scholar 

  6. Bazant, M.Z., Thornton, K., Ajdari, A.: Diffuse-charge dynamics in electrochemical systems. Phys. Rev. E 70, 02150 (2004)

    Article  Google Scholar 

  7. Lockett, V., Horne, M., Sedev, R., et al.: Differential capacitance of double layer at the electrode/ionic liquids interface. Phys. Chem. Chem. Phys. 12, 12499–12512 (2010)

    Article  Google Scholar 

  8. Golovnev, A., Trimper, S.: Exact solution of the Poisson–Nernst–Planck equations in the linear regime. J. Chem. Phys. 131, 114903 (2009)

    Article  Google Scholar 

  9. Golovnev, A., Trimper, S.: Analytical solution of the Poisson–Nernst–Planck equations in the linear regime at an applied dc-voltage. J. Chem. Phys. 134, 154902 (2011)

    Article  Google Scholar 

  10. Golovnev, A., Trimper, S.: Analytical solution of the PNP equations at AC applied voltage. Phys. Lett. A 376, 1391–1395 (2012)

    Article  Google Scholar 

  11. Brown, M.A., Bossa, G.V., May, S.: Emergence of a Stern layer from the incorporation of hydration interactions into the Gouy–Chapman model of the electrical double layer. Langmuir 31, 11477–11483 (2015)

    Article  Google Scholar 

  12. Trefalt, G., Behrens, S.H., Borkovec, M.: Charge regulation in the electrical double layer: ion adsorption and surface interactions. Langmuir 32, 380–400 (2016)

    Article  Google Scholar 

  13. Goel, T., Patra, C.N.: Structure of spherical electric double layers: a density functional approach. J. Chem. Phys. 127, 034502 (2007)

    Article  Google Scholar 

  14. López-García, J.J., Aranda-Rascón, M.J., Horno, J.: Electrical double layer around a spherical colloid particle: the excluded volume effect. J. Colloid Interface Sci. 316, 196–201 (2007)

    Article  Google Scholar 

  15. Tseng, S., Jiang, J.M., Hsu, J.P.: Electrical potential in a cylindrical double layer: a functional theory approach. J. Colloid Interface Sci. 273, 218–223 (2004)

    Article  Google Scholar 

  16. Goel, T., Patra, C.N., Ghosh, S.K., et al.: Structure of cylindrical electric double layers: a systematic study by Monte Carlo simulations and density functional theory. J. Chem. Phys. 129, 154906 (2008)

    Article  Google Scholar 

  17. Halle, B.: Orientation-dependent electrical double-layer interactions: I. Rodlike macroions of finite length. J. Chem. Phys. 102, 7238–7250 (1995)

    Article  Google Scholar 

  18. Iozzo, D.A.B., Tong, M., Wu, G., et al.: Numerical analysis of electric double layer capacitors with mesoporous electrodes: effects of electrode and electrolyte properties. J. Phys. Chem. C 119, 25235–25242 (2015)

    Article  Google Scholar 

  19. Singh, M.B., Kant, R.: Theory of anomalous dynamics of electric double layer at heterogeneous and rough electrodes. J. Phys. Chem. C 118, 5122–5133 (2014)

    Article  Google Scholar 

  20. Xie, J., Agarwal, R., Liu, Y., et al.: A three-axis SOI accelerometer sensing with both in-plane and vertical comb electrodes. Microsyst. Technol. 18, 325–332 (2012)

    Article  Google Scholar 

  21. Surapaneni, R., Guo, Q., Xie, Y., et al.: A three-axis high-resolution capacitive tactile imager system based on floating comb electrodes. J. Micromech. Microeng. 23, 075004 (2013)

    Article  Google Scholar 

  22. Molina-Lopez, F., Briand, D., Rooij, N.F.D.: Decreasing the size of printed comb electrodes by the introduction of a dielectric interlayer for capacitive gas sensors on polymeric foil: modeling and fabrication. Sensors Actuat. B Chem. 189, 89–96 (2013)

    Article  Google Scholar 

  23. Ngo, T.T., Shirzadfar, H., Bourjilat, A., et al.: A method to determine the parameters of the double layer of a planar interdigital sensor. In: Proceedings of the 8th International Conference on Sensing Technology, Liverpool, 348–351 (2014)

  24. McLachlan, N.W.: Theory and Application of Mathieu Functions. Oxford Press, Oxford (1951)

    MATH  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grants 11502108 and 11232007), the Program for New Century Excellent Talents in Universities (Grant NCET-12-0625), the Natural Science Foundation of Jiangsu Province (Grant BK20140037), the Fundamental Research Funds for Central Universities (Grant NE2013101), and a project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Correspondence to Zhenghua Qian or Jiashi Yang.

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Dai, X., Qian, Z. & Yang, J. A semi-analytical solution for electric double layers near an elliptical cylinder. Acta Mech. Sin. 34, 62–67 (2018). https://doi.org/10.1007/s10409-017-0680-9

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