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Analysis of delamination in thin film electrodes under galvanostatic and potentiostatic operations with Li-ion diffusion from edge

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Abstract

Progressive delamination driven by Li-ion diffusion in elastic disk-like thin film electrodes of Li-ion batteries is modeled based on the cohesive model. Axisymmetric diffusion model is considered under both galvanostatic and potentiostatic operations. The effect of edge diffusion on the delamination process is evaluated. It is found that the diffusion from edge leads to an earlier delamination initiation. The edge effect is significant for active disks with a small aspect ratio, but negligible for the case of large aspect ratio. The edge diffusion is weaker in the potentiostatic operation than in the galvanostatic operation.

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References

  1. Marom, R., Amalraj, S. F., Leifer, N., et al.: A review of advanced and practical lithium battery materials. J. Mater. Chem. 21, 9938–9954 (2011)

    Article  Google Scholar 

  2. Dahn, J. R., Zheng, T., Liu, Y., et al.: Mechanisms for lithium insertion in carbonaceous materials. Science 270, 590–593 (1995)

    Article  Google Scholar 

  3. Boukamp, B.A., Lesh, G.C., Huggins, R.A.: All-solid lithium electrodes with mixed-conductor matrix. J. Electrochem. Soc. 128, 725–729 (1981)

    Article  Google Scholar 

  4. Kasavajjula, U., Wang, C., Appleby, A. J.: Nano- and bulksilicon-based insertion anodes for lithium-ion secondary cell. J. Power Sources 163, 1003–1039 (2007)

    Article  Google Scholar 

  5. Baggetto, L., Niessen, R. A. H., Roozeboom, F., et al.: High energy density all-solid-state batteries: A challenging concept towards 3D integration. Adv. Funct. Mater., 18, 1057–1066 (2008)

    Article  Google Scholar 

  6. Chan, C. K., Peng, H., Liu, G., et al.: High-performance lithium battery anodes using silicon nanowires. Nat. Nanotechnol. 3, 31–35 (2008)

    Article  Google Scholar 

  7. Souquet, J. L., Duclot, M.: Thin film lithium batteries. Solid State Ionics 148, 375–379 (2002).

    Article  Google Scholar 

  8. Li, J., Dozier, A. K., Li, Y., et al.: Crack pattern formation in thin film lithium-ion battery electrodes. J. Electrochem. Soc. 158, A689–A694 (2011)

    Article  Google Scholar 

  9. Xiao, X., Liu, P., Verbrugge, M. W., et al.: Improved cycling stability of silicon thin film electrodes through patterning for high energy density lithium batteries. J. Power Sources 196, 1409–1416 (2011)

    Article  Google Scholar 

  10. Haftbaradaran, H., Xiao, X., Verbrugge, M. W., et al.: Method to deduce the critical size for interfacial delamination of patterned electrode structures and application to lithiation of thin-film silicon islands. J. Power Sources, 206, 357–366 (2012)

    Article  Google Scholar 

  11. Cheng, Y. T., Verbrugge, M. W.: Evolution of stress within a spherical insertion electrode particle under potentiostatic and galvanostatic operation. J. Power Sources 190, 453–460 (2009)

    Article  Google Scholar 

  12. Zhang, J., Lu, B., Song, Y., et al.: Diffusion induced stress in layered Li-ion battery electrode plates. J. Power Sources 209, 220–227 (2012)

    Article  Google Scholar 

  13. Brownson, D. A. C., Kampouris, D. K., Banks, C. E.: Graphene electrochemistry: fundamental concepts through to prominent applications. Chem. Soc. Rev. 41, 6944–6976 (2012)

    Article  Google Scholar 

  14. Lu, B., Song, Y., Guo, Z., et al.: Modeling of progressive delamination in a thin film driven by diffusion-induced stresses. Int. J. Solids Struct. 50, 2495–2507 (2013)

    Article  Google Scholar 

  15. Crank, J.: The Mathematics of Diffusion. Oxford: Oxford University Press (1979)

    MATH  Google Scholar 

  16. Camacho, G. T., Ortiz, M.: Computational modeling of impact damage in brittle materials. Int. J. Solids Struct. 33, 2899–2938 (1996)

    Article  MATH  Google Scholar 

  17. Shao, Y., Zhao, H. P., Feng, X. Q., et al.: Discontinuous crackbridging model for fracture toughness analysis of nacre. J. Mech. Phys. Solids, 60, 1400–1419 (2012)

    Article  MathSciNet  Google Scholar 

  18. Mastrojannis, E. N., Keer, L. M., Mura, T.: Thin circular plate under temperature loading in adhesive contact with an elastic half-space. J. Therm. Stresses 10, 71–81 (1987)

    Article  Google Scholar 

  19. He, Y., Yu, X., Li, G., et al.: Shape evolution of patterned amorphous and polycrystalline silicon microarray thin film electrodes caused by lithium insertion and extraction. J. Power Sources 216, 131–138 (2012)

    Article  Google Scholar 

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Authors and Affiliations

  1. Shanghai Institute of Applied Mathematics and Mechanics, Shanghai University, 200072, Shanghai, China

    Bo Lu & Zhan-Sheng Guo

  2. Department of Mechanics, Shanghai University, 200444, Shanghai, China

    Yi-Cheng Song & Jun-Qian Zhang

  3. Shanghai Key Laboratory of Mechanics in Energy Engineering, Shanghai University, 200072, Shanghai, China

    Yi-Cheng Song, Zhan-Sheng Guo & Jun-Qian Zhang

Authors
  1. Bo Lu
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  2. Yi-Cheng Song
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  3. Zhan-Sheng Guo
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  4. Jun-Qian Zhang
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Corresponding author

Correspondence to Jun-Qian Zhang.

Additional information

The project was supported by the National Science Foundation of China (11102103 and 11172159), the Shanghai Municipal Education Commission, China (13ZZ070), the Graduate School of Shanghai University (SHUCX120123), as well as the Science and Technology Commission of Shanghai Municipality, China (12ZR1410200).

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Lu, B., Song, YC., Guo, ZS. et al. Analysis of delamination in thin film electrodes under galvanostatic and potentiostatic operations with Li-ion diffusion from edge. Acta Mech Sin 29, 348–356 (2013). https://doi.org/10.1007/s10409-013-0038-x

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  • DOI: https://doi.org/10.1007/s10409-013-0038-x

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