Abstract
Fusion pretreatment is introduced to the microwave-assisted hydrothermal process to improve the zeolite fabrication from municipal solid waste incineration (MSWI) fly ash. The fusion-pretreated microwave-assisted hydrothermal method (FMHM) and microwave-assisted hydrothermal method are conducted and systematically compared. With fusion pretreatment, the quartz is transformed into amorphous form, which is easier to dissolve into a hydrothermal solution and thus accelerates the zeolite fabrication process. The scanning electron microscope, X-ray diffraction, Fourier transform infrared measurement and thermal gravimetric analysis are performed, whose results suggest the formation of zeolite materials in the FMHM product, such as needle-like tobermorite and rose-like sodalite. The thermal gravimetric analysis indicates water adsorption of the FMHM product is improved. The cation exchange capacity of the FMHM product is 1.172 meq g−1, more than twofold larger than that of the MHM product. Additionally, the toxicity test indicates that the leakage of heavy metal ions from the FMHM product is dramatically reduced. The improved safety makes the zeolitic product synthesized from MSWI fly ash promising for further applications. FMHM significantly facilitates the disposal and reuse of the MSWI fly ash.
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Hu Y, Zhang P, Li J, Chen D (2015) Stabilization and separation of heavy metals in incineration fly ash during the hydrothermal treatment process. J Hazard Mater 299:149–157. https://doi.org/10.1016/j.jhazmat.2015.06.002
Xue Y, Hou H, Zhu S, Zha J (2009) Utilization of municipal solid waste incineration ash in stone mastic asphalt mixture: pavement performance and environmental impact. Constr Build Mater 23:989–996. https://doi.org/10.1016/j.conbuildmat.2008.05.009
Pan Y, Yang L, Zhou J, Liu J, Qian G, Ohtsuka N et al (2013) Characteristics of dioxins content in fly ash from municipal solid waste incinerators in China. Chemosphere 92:765–771. https://doi.org/10.1016/j.chemosphere.2013.04.003
Anastasiadou K, Christopoulos K, Mousios E, Gidarakos E (2012) Solidification/stabilization of fly and bottom ash from medical waste incineration facility. J Hazard Mater 207:165–170. https://doi.org/10.1016/j.jhazmat.2011.05.027
China's National Bureau of Statistics (2019) China statistical yearbook. China Statistics Press, Beijing
Cyr M, Idir R, Escadeillas G (2012) Use of metakaolin to stabilize sewage sludge ash and municipal solid waste incineration fly ash in cement-based materials. J Hazard Mater 243:193–203. https://doi.org/10.1016/j.jhazmat.2012.10.019
Tang Q, Liu Y, Gu F, Zhou T (2016) Solidification/stabilization of fly ash from a municipal solid waste incineration facility using portland cement. Adv Mater Sci Eng 2016:1–10. https://doi.org/10.1155/2016/7101243
Li X-G, Lv Y, Ma B-G, Chen Q-B, Yin X-B, Jian S-W (2012) Utilization of municipal solid waste incineration bottom ash in blended cement. J Clean Prod 32:96–100. https://doi.org/10.1016/j.jclepro.2012.03.038
Lin KL, Wang KS, Tzeng BY, Lin CY (2003) The reuse of municipal solid waste incinerator fly ash slag as a cement substitute. Resour Conserv Recyl 39:315–324. https://doi.org/10.1016/S0921-3449(02)00172-6
Mangialardi T, Paolini AE, Polettini A, Sirini P (1999) Optimization of the solidification/stabilization process of MSW fly ash in cementitious matrices. J Hazard Mater 70:53–70. https://doi.org/10.1016/S0304-3894(99)00132-6
Wang F-H, Zhang F, Chen Y-J, Gao J, Zhao B (2015) A comparative study on the heavy metal solidification/stabilization performance of four chemical solidifying agents in municipal solid waste incineration fly ash. J Hazard Mater 300:451–458. https://doi.org/10.1016/j.jhazmat.2015.07.037
Liu S-J, Guo Y-P, Yang H-Y, Wang S, Ding H, Qi Y (2016) Synthesis of a water-soluble thiourea-formaldehyde (WTF) resin and its application to immobilize the heavy metal in MSWI fly ash. J Environ Manag 182:328–334. https://doi.org/10.1016/j.jenvman.2016.07.086
Mallampati SR, Mitoma Y, Simion C, Lee BH (2015) Immobilization and volume reduction of heavy metals in municipal solid waste fly ash using nano-size calcium and iron-dispersed reagent. J Air Waste Manag 65:1247–1255. https://doi.org/10.1080/10962247.2015.1077175
Weckhuysen BM, Yu J (2015) Recent advances in zeolite chemistry and catalysis. Chem Soc Rev 44:7022–7024. https://doi.org/10.1039/c5cs90100f
Abdullahi T, Harun Z, Othman MHD (2017) A review on sustainable synthesis of zeolite from kaolinite resources via hydrothermal process. Adv Powder Technol 28:1827–1840. https://doi.org/10.1016/j.apt.2017.04.028
Yang T, Han C, Liu H, Yang L, Liu D, Tang J et al (2019) Synthesis of Na-X zeolite from low aluminum coal fly ash: characterization and high efficient As(V) removal. Adv Powder Technol 30:199–206. https://doi.org/10.1016/j.apt.2018.10.023
Bayuseno AP, Schmahl WW, Muellejans T (2009) Hydrothermal processing of MSWI fly ash-towards new stable minerals and fixation of heavy metals. J Hazard Mater 167:250–259. https://doi.org/10.1016/j.jhazmat.2008.12.119
Qiu Q, Jiang X, Lu S, Ni M (2016) Effects of microwave-assisted hydrothermal treatment on the major heavy metals of municipal solid waste incineration fly ash in a circulating fluidized bed. Energy Fuel 30:5945–5952. https://doi.org/10.1021/acs.energyfuels.6b00547
Qiu Q, Jiang X, Lv G, Lu S, Ni M (2016) Stabilization of heavy metals in municipal solid waste incineration fly ash in circulating fluidized bed by microwave-assisted hydrothermal treatment with additives. Energy Fuel 30:7588–7595. https://doi.org/10.1021/acs.energyfuels.6b01431
Qiu Q, Jiang X, Chen Z, Lu S, Ni M (2017) Microwave-assisted hydrothermal treatment with soluble phosphate added for heavy metals solidification in MSWI fly ash. Energy Fuel 31:5222–5232. https://doi.org/10.1021/acs.energyfuels.6b02516
Qiu Q, Jiang X, Lv G, Chen Z, Lu S, Ni M et al (2018) Adsorption of heavy metal ions using zeolite materials of municipal solid waste incineration fly ash modified by microwave-assisted hydrothermal treatment. Powder Technol 335:156–163. https://doi.org/10.1016/j.powtec.2018.05.003
Ojha K, Pradhan NC, Samanta AN (2004) Zeolite from fly ash: synthesis and characterization. Bull Mater Sci 27:555–564. https://doi.org/10.1007/BF02707285
USA EPA (1986) Cation-exchange capacity of soils (Sodium acetate). Washington DC
Ministry of Ecology and Environment of the People's Republic of China (2007) Solid waste-extraction procedure for leaching toxicity-acetic acid buffer solution method, HJ/T300-2007. China Environmental Standards Press, Beijing
Guo X, Song M (2018) Micro-nanostructures of tobermorite hydrothermal-synthesized from fly ash and municipal solid waste incineration fly ash. Constr Build Mater 191:431–439. https://doi.org/10.1016/j.conbuildmat.2018.10.030
Belviso C (2018) Ultrasonic vs hydrothermal method: different approaches to convert fly ash into zeolite. How they affect the stability of synthetic products over time? Ultrason Sonochem 43:9–14. https://doi.org/10.1816/j.ultsonch.2017.12.050
Kazemian H, Naghdali Z, Kashani TG, Farhadi F (2010) Conversion of high silicon fly ash to Na-P1 zeolite: alkaline fusion followed by hydrothermal crystallization. Adv Powder Technol 21:279–283. https://doi.org/10.1016/j.apt.2009.12.005
Hu H, Luo G, Liu H, Qiao Y, Xu M, Yao H (2013) Fate of chromium during thermal treatment of municipal solid waste incineration (MSWI) fly ash. Proc Combust Inst 34:2795–2801. https://doi.org/10.1016/j.proci.2012.06.181
Wang KS, Sun CJ, Liu CY (2001) Effects of the type of sintering atmosphere on the chromium leachability of thermal-treated municipal solid waste incinerator fly ash. Waste Manag 21:85–91. https://doi.org/10.1016/S0956-053X(00)00041-6
Perry RH, Green DW (2007) Perry's chemical engineers' handbook. McGraw-Hill, New York
Yang L, Qian X, Yuan P, Bai H, Miki T, Men F et al (2019) Green synthesis of zeolite 4A using fly ash fused with synergism of NaOH and Na2CO3. J Clean Prod 212:250–260. https://doi.org/10.1016/j.jclepro.2018.11.259
Ślósarczyk A, Paszkiewicz Z, Paluszkiewicz C (2005) FTIR and XRD evaluation of carbonated hydroxyapatite powders synthesized by wet methods. J Mol Struct 744–747:657–661. https://doi.org/10.1016/j.molstruc.2004.11.078
Sivalingam S, Sen S (2019) Valorization of coal fly ash into nanozeolite by sonication-assisted hydrothermal method. J Environ Manag 235:145–151. https://doi.org/10.1016/j.jenvman.2019.01.042
Liu Y, Yan C, Zhao J, Zhang Z, Wang H, Zhou S et al (2018) Synthesis of zeolite P1 from fly ash under solvent-free conditions for ammonium removal from water. J Clean Prod 202:11–22. https://doi.org/10.1016/j.jclepro.2018.08.128
Li Q, Xu H, Li F, Li P, Shen L, Zhai J (2012) Synthesis of geopolymer composites from blends of CFBC fly and bottom ashes. Fuel 97:366–372. https://doi.org/10.1016/j.fuel.2012.02.059
Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S (2008) Adsorption of reactive dyes from aqueous solutions by fly ash: kinetic and equilibrium studies. J Hazard Mater 150:737–746. https://doi.org/10.1016/j.jhazmat.2007.05.027
Henao-Sierra W, Romero-Sáez M, Gracia F, Cacua K, Buitrago-Sierra R (2018) Water vapor adsorption performance of Ag and Ni modified 5A zeolite. Microporous Mesoporous Mater 265:250–257. https://doi.org/10.1016/j.micromeso.2018.02.036
Li DX, Chen YM, Shen JL, Su JH, Wu XQ (2000) The influence of alkalinity on activation and microstructure of fly ash. Cement Concr Res 30:881–886. https://doi.org/10.1016/S0008-8846(00)00252-0
Kim MS, Jun Y, Lee C, Oh JE (2013) Use of CaO as an activator for producing a price-competitive non-cement structural binder using ground granulated blast furnace slag. Cement Concr Res 54:208–214. https://doi.org/10.1016/j.cemconres.2013.09.011
Sato H, Grutzeck M (1991) Effect of starting materials on the synthesis of tobermorite. Mater Res Soc Symp Proc 245:235. https://doi.org/10.1557/PROC-245-235
Huang S, Chang F, Lo S, Lee M, Wang C, Lin J (2007) Production of lightweight aggregates from mining residues, heavy metal sludge, and incinerator fly ash. J Hazard Mater 144:52–58. https://doi.org/10.1016/j.jhazmat.2006.09.094
Alver E, Metin AU (2012) Anionic dye removal from aqueous solutions using modified zeolite: adsorption kinetics and isotherm studies. Chem Eng J 200:59–67. https://doi.org/10.1016/j.cej.2012.06.038
Querol X, Moreno N, Umana JC, Juan R, Hernandez S, Fernandez-Pereira C et al (2002) Application of zeolitic material synthesised from fly ash to the decontamination of waste water and flue gas. J Chem Technol Biot 77:292–298. https://doi.org/10.1002/jctb.597
Querol X, Moreno N, Umana JC, Alastuey A, Hernandez E, Lopez-Soler A et al (2002) Synthesis of zeolites from coal fly ash: an overview. Int J Coal Geol 50:413–423. https://doi.org/10.1016/S0166-5162(02)00124-6
Zhao Y (2016) Review of the natural, modified, and synthetic zeolites for heavy metals removal from wastewater. Environ Eng Sci 33:443–454. https://doi.org/10.1089/ees.2015.0166
Baldermann A, Landler A, Mittermayr F, Letofsky-Papst I, Steindl F, Galan I (2019) Removal of heavy metals (Co, Cr, and Zn) during calcium-aluminium-silicate-hydrate and trioctahedral smectite formation. J Mater Sci 54:9331–9351. https://doi.org/10.1007/s10853-019-03541-5
Tran HV, Gowripalan N (2018) Mechanisms of heavy metal immobilisation using geopolymerisation techniques—a review. J Adv Concr Technol 16:124–135. https://doi.org/10.3151/jact.16.124
Gattullo CE, D'Alessandro C, Allegretta I, Porfido C, Spagnuolo M, Terzano R (2018) Alkaline hydrothermal stabilization of Cr(VI) in soil using glass and aluminum from recycled municipal solid wastes. J Hazard Mater 344:381–389. https://doi.org/10.1016/j.jhazmat.2017.10.035
Zhou X, Zhou M, Wu X, Han Y, Geng J, Wang T et al (2017) Reductive solidification/stabilization of chromate in municipal solid waste incineration fly ash by ascorbic acid and blast furnace slag. Chemosphere 182:76–84. https://doi.org/10.1016/j.chemosphere.2017.04.072
Lindberg D, Molin C, Hupa M (2015) Thermal treatment of solid residues from WtE units: a review. Waste Manag 37:82–94. https://doi.org/10.1016/j.wasman.2014.12.009
Acknowledgements
This study is supported by the National Key Research and Development Program of China (Grant Nos. 2018YFF0215001, 2018YFC1901302, 2017YFC0703100), the Innovative Research Groups of the National Natural Science Foundation of China (Grant No. 51621005), the National Nature Science Foundation of China (Grant No. 51676172), and the Fundamental Research Funds for the Central Universities (Grant No. 2018FZA4010), Funds for Science and Technology projects of Power Construction Group Corporation of China, LTD.
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Chen, Q., Long, L., Liu, X. et al. Low-toxic zeolite fabricated from municipal solid waste incineration fly ash via microwave-assisted hydrothermal process with fusion pretreatment. J Mater Cycles Waste Manag 22, 1196–1207 (2020). https://doi.org/10.1007/s10163-020-01020-7
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DOI: https://doi.org/10.1007/s10163-020-01020-7