Abstract
Composite films composed of uncured natural rubber (NR) combined with coal fly ash (CFA) and CFA treated by acid washing (CFAT), both acting as fillers, were developed. The goal was to add value to the CFA (which is an industrial waste) while improving the mechanical properties of the NR. These NR–CFA and NR–CFAT composites were fabricated using the latex aqueous microdispersion method to ensure suitable dispersion of the filler. The mechanical properties of both composites, including tensile strength, elongation at break and Young’s modulus, were improved considerably at a filler content of 20 phr compared to the original NR. Adding CFA and CFAT increased these values to 10.5 MPa, 222% and 126 and 7.7 MPa, 315% and 21.4 MPa, respectively. NR–CFA and NR–CFAT composites also exhibited substantially higher structural stability in water with only minimal swelling, as well as better resistance to toluene. The NR–CFA composite film containing CFA at 20 phr was found to have the best structural stability, mechanical properties and resistance to solvents among the specimens tested.
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Petchseechoung W (2106) Thailand industry outlook 2016–2018, rubber industry. https://www.krungsri.com/bank/getmedia/1d1b8758-8da1-44e3-af42-962b0b9f7506/IO_Rubber_2016_EN.aspx. Accessed 5 Jan 2018
Phinyocheep P (2014) Chemical modification of natural rubber (NR) for improved performance. In: Kohjiya S, Ikeda Y (eds) Chemistry, manufacture and applications of natural rubber. Woodhead Publishing Ltd, Oxford, pp 68–118. https://doi.org/10.1533/9780857096913.1.68
Intiya W, Thepsuwan U, Sirisinha C, Sae-Oui P (2017) Possible use of sludge ash as filler in natural rubber. J Mater Cycles Waste Manag 19:774–781. https://doi.org/10.1007/s10163-016-0480-5
Sae-oui P, Sirisinha C, Thaptong P (2009) Utilization of limestone dust waste as filler in natural rubber. J Mater Cycles Waste Manag 11:166–171. https://doi.org/10.1007/s10163-008-0230-4
Igwe IO, Ejim AA (2011) Studies on mechanical and end-use properties of natural rubber filled with snail shell powder. Mater Sci Appl 02:801–810. https://doi.org/10.4236/msa.2011.27109
Cokca E, Yilmaz Z (2004) Use of rubber and bentonite added fly ash as a liner material. Waste Manag 24:153–164. https://doi.org/10.1016/j.wasman.2003.10.004
Peng Z, Kong LX, Li S-D, Chen Y, Huang MF (2007) Self-assembled natural rubber/silica nanocomposites: Its preparation and characterization. Compos Sci Technol 67:3130–3139. https://doi.org/10.1016/j.compscitech.2007.04.016
Hasegawa M, Furukawa S, Asana M (2007) Utilization of the coal ash as filler of plastics and rubber products. In: Proceedings of international symposium on EcoTopia science (ISETS07). pp 842–845
Rattanasom N, Saowapark T, Deeprasertkul C (2007) Reinforcement of natural rubber with silica/carbon black hybrid filler. Polym Test 26:369–377. https://doi.org/10.1016/j.polymertesting.2006.12.003
Ooi ZX, Ismail H, Abu Bakar A (2013) Synergistic effect of oil palm ash filled natural rubber compound at low filler loading. Polym Test 32:38–44. https://doi.org/10.1016/j.polymertesting.2012.09.007
Rajisha KR, Maria HJ, Pothan LA, Ahmad Z, Thomas S (2014) Preparation and characterization of potato starch nanocrystal reinforced natural rubber nanocomposites. Int J Biol Macromol 67:147–153. https://doi.org/10.1016/j.ijbiomac.2014.03.013
Mariano M, El Kissi N, Dufresne A (2016) Cellulose nanocrystal reinforced oxidized natural rubber nanocomposites. Carbohydr Polym 137:174–183. https://doi.org/10.1016/j.carbpol.2015.10.027
Barrera CS, Cornish K (2015) Novel mineral and organic materials from agro-industrial residues as fillers for natural rubber. J Polym Environ 23:437–448. https://doi.org/10.1007/s10924-015-0737-4
Barrera CS, Cornish K (2016) High performance waste-derived filler/carbon black reinforced guayule natural rubber composites rubber. Ind Crops Prod 86:132–142. https://doi.org/10.1016/j.indcrop.2016.03.021
Energy Policy and Planning Office (2015) Thailand power development plan (PDP: 2015–2036). Ministry of Energy. http://www2.eppo.go.th/power/PDP2015/PDP2015.pdf. Accessed 5 Jan 2018
Nyale SM, Babajide OO, Birch GD, Böke N, Petrik LF (2013) Synthesis and characterization of coal fly ash-based foamed geopolymer. Proc Environ Sci 18:722–730. https://doi.org/10.1016/j.proenv.2013.04.098
Yao ZT, Ji XS, Sarker PK, Tang JH, Ge LQ, Xia MS, Xi YQ (2015) A comprehensive review on the applications of coal fly ash. Earth Sci Rev 141:105–121. https://doi.org/10.1016/j.earscirev.2014.11.016
Wang L, Sun H, Sun Z, Ma E (2015) New technology and application of brick making with coal fly ash. J Mater Cycles Waste Manag 18:763–770. https://doi.org/10.1007/s10163-015-0368-9
Kaur R, Goyal D (2014) Mineralogical comparison of coal fly ash with soil for use in agriculture. J Mater Cycles Waste Manag 18:186–200. https://doi.org/10.1007/s10163-014-0323-1
Lee K-M, Jo Y-M (2010) Synthesis of zeolite from waste fly ash for adsorption of CO2. J Mater Cycles Waste Manag 12:212–219. https://doi.org/10.1007/s10163-010-0290-0
Ruen-ngam D, Rungsuk D, Apiratikul R, Pavasant P (2009) Zeolite formation from coal fly ash and its adsorption potential. J Air Waste Manag Assoc 59:1140–1147. https://doi.org/10.3155/1047-3289.59.10.1140
Koshy N, Singh DN (2016) Fly ash zeolites for water treatment applications. J Environ Chem Eng 4:1460–1472. https://doi.org/10.1016/j.jece.2016.02.002
Panitchakarn P, Laosiripojana N, Viriya-umpikul N, Pavasant P (2014) Synthesis of high-purity Na-A and Na-X zeolite from coal fly ash. J Air Waste Manag Assoc 64:586–596. https://doi.org/10.1080/10962247.2013.859184
Molina A, Poole C (2004) A comparative study using two methods to produce zeolites from fly ash. Miner Eng 17:167–173. https://doi.org/10.1016/j.mineng.2003.10.025
Barrera CS, Cornish K (2017) Processing and mechanical properties of natural rubber/waste-derived nano filler composites compared to macro and micro filler composites. Ind Crops Prod 107:217–231. https://doi.org/10.1016/j.indcrop.2017.05.045 2017.
Shivpuri KK, Kulkarni BL, Dikshit DA AK (2012) Metal leaching potential in coal fly ash. Am J Environ Eng 1:21–27. https://doi.org/10.5923/j.ajee.20110101.04
Wajima T, Munakata K (2011) Material conversion from paper sludge ash in NaOH solution to synthesize adsorbent for removal of Pb2+, NH4 + and PO4 3– from aqueous solution. J Environ Sci 23:718–724. https://doi.org/10.1016/s1001-0742(10)60467-6
Phomrak S, Phisalaphong M (2017) Reinforcement of natural rubber with bacterial cellulose via a latex aqueous microdispersion process. J Nanomater 2017:1–9. https://doi.org/10.1155/2017/4739793
Dai Z, Liu S, Ju H, Chen H (2004) Direct electron transfer and enzymatic activity of hemoglobin in a hexagonal mesoporous silica matrix. Biosens Bioelectron 19:861–867. https://doi.org/10.1016/j.bios.2003.08.024
Dzhurkov V, Nesheva D, Scepanovic M, Nedev N, Kaschieva S, Dmitriev SN, Popovic Z (2014) Spectroscopic studies of SiOx films irradiated with high energy electrons. J Phys Conf Ser 558(012045). https://doi.org/10.1088/1742-6596/558/1/012045
Battisha IK, Beyally AE, Mongy SAE, Nahrawi AM (2007) Development of the FTIR properties of nano-structure silica gel doped with different rare earth elements, prepared by sol–gel route. J Sol Gel Sci Technol 41:129–137. https://doi.org/10.1007/s10971-006-0520-z
Saikia BJ, Gopalakrishnarao Parthasarathy G (2010) Fourier transform infrared spectroscopic characterization of kaolinite from Assam and Meghalaya, Northeastern India. J Mod Phys 1:206–210. https://doi.org/10.4236/jmp.2010.14031
Poompradub S, Thirakulrati M, Prasassarakich P (2014) In situ generated silica in natural rubber latex via the sol–gel technique and properties of the silica rubber composites. Mater Chem Phys 144:122–131. https://doi.org/10.1016/j.matchemphys.2013.12.030
Maan A, Niyogi UK, Singh AK, Mehra DS, Rattan S (2014) Development and characterization of fly ash reinforced natural rubber composite. J Polym Mater 31:397–408. https://doi.org/10.14233/ajchem.2016.19539
Obasi HC, Ogbobe O, Igwe IO (2009) Diffusion characteristics of toluene into natural rubber/linear low density polyethylene blends. Int J Polym Sci 2009:1–6. https://doi.org/10.1155/2009/140682
Acknowledgements
The authors are grateful for the financial support from the Ratchadaphiseksomphot Endowment Fund of Chulalongkorn University for Postdoctoral Fellowship and the kind support of CFA from the pulping process in Prachinburi province of Thailand. We thank Michael D. Judge, MSc. from Edanz Group (http://www.Edanzediting.com/ac) for editing a draft of the manuscript.
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Panitchakarn, P., Wikranvanich, J. & Phisalaphong, M. Synthesis and characterization of natural rubber/coal fly ash composites via latex aqueous microdispersion. J Mater Cycles Waste Manag 21, 134–144 (2019). https://doi.org/10.1007/s10163-018-0774-x
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DOI: https://doi.org/10.1007/s10163-018-0774-x