Skip to main content
Log in

Removal techniques for heavy metals from fly ash

  • REVIEW
  • Published:
Journal of Material Cycles and Waste Management Aims and scope Submit manuscript

Abstract

This study reviews different technologies for extraction of heavy metals from fly ash. With this perspective processes like bioleaching using microbes, carrier in pulp method, chemical extraction via acids, alkaline leachates and chelating agents, chloride evaporation process, electrodialytic and thermal treatments were studied thoroughly. A comprehensive comparison of all the techniques is also done by studying in detail their reaction conditions, metals leached and percentage extraction achieved. The study concluded that depending on the type of fly ash and metal under consideration determines the suitability of the process adopted for detoxification of fly ash. In addition to these, factors like cost, time and energy also define the final selection process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Vassilev SV, Vassileva CG (2007) A new approach for the classification of coal fly ashes based on their origin, composition, properties, and behaviour. Fuel 86(10):1490–1512

    Article  Google Scholar 

  2. Page AL, Elseewi A, Straughan IR (1979) Physical and chemical properties of fly ash from coal-fired power plants with reference to environmental impacts. In: Gunther F, Gunther J (eds) Residue reviews. Springer, New York, pp 83–120

    Chapter  Google Scholar 

  3. Ghio AJ, Silbajoris R, Carson JL, Samet JM (2002) Biological effects of oil fly ash. Environ Health Perspect 110(Suppl 1):89

    Article  Google Scholar 

  4. Iyer R (2002) The surface chemistry of leaching coal fly ash. J Hazard Mater 93(3):321–329

    Article  Google Scholar 

  5. Cereda E, Braga Marcazzan GM, Pedretti M, Grime GW, Baldacci A (1995) The microscopic nature of coal fly ash particles investigated by means of nuclear microscopy. Atmos Environ 29(17):2323–2329

    Article  Google Scholar 

  6. Bumrongjaroen W, Muller I, Livingston RA, Davis J (2011) A performance-based fly ash classification system using glassy particle chemical composition data. In: 2011 World of Coal Ash (WOCA) Conference. Denver, CO, USA

  7. Wang S, Wu H (2006) Environmental-benign utilisation of fly ash as low-cost adsorbents. J Hazard Mater 136(3):482–501

    Article  MathSciNet  Google Scholar 

  8. Fisher GL, Prentice BA, Silberman D, Ondov JM, Biermann AH, Ragaini RC et al (1978) Physical and morphological studies of size-classified coal fly ash. Environ Sci Technol 12(4):447–451. doi:10.1021/es60140a008

    Article  Google Scholar 

  9. Nriagu JO (1988) A silent epidemic of environmental metal poisoning? Environ Pollut 50(1):139–161

    Article  Google Scholar 

  10. Que Hee SS, Finelli VN, Fricke FL, Wolnik KA (1982) Metal content of stack emissions, coal and fly ash from some eastern and western power plants in the USA as obtained by ICP-AES. Int J Environ Anal Chem 13(1):1–18

    Article  Google Scholar 

  11. Lam CH, Ip AW, Barford JP, McKay G (2010) Use of incineration MSW ash: a review. Sustainability 2(7):1943–1968

    Article  Google Scholar 

  12. Wu H-Y, Ting Y-P (2006) Metal extraction from municipal solid waste (MSW) incinerator fly ash—Chemical leaching and fungal bioleaching. Enzyme Microb Technol 38(6):839–847

    Article  MathSciNet  Google Scholar 

  13. Keppert M, Pavlik Z, Pavlikova M, Fort J, Trnik A, Žumar J et al (2013) Municipal solid waste incineration fly ash as supplementary cementitious material. In: Central Europe towards Sustainable Building 26-28 Jun 2013. Prague

  14. Wan X, Wang W, Ye T, Guo Y, Gao X (2006) A study on the chemical and mineralogical characterization of MSWI fly ash using a sequential extraction procedure. J Hazard Mater 134(1–3):197–201. doi:10.1016/j.jhazmat.2005.10.048

    Article  Google Scholar 

  15. Ward CR, French D (2006) Determination of glass content and estimation of glass composition in fly ash using quantitative X-ray diffractometry. Fuel 85(16):2268–2277

    Article  Google Scholar 

  16. Goodarzi F (2006) Characteristics and composition of fly ash from Canadian coal-fired power plants. Fuel 85(10–11):1418–1427

    Article  Google Scholar 

  17. Koukouzas N, Hämäläinen J, Papanikolaou D, Tourunen A, Jäntti T (2007) Mineralogical and elemental composition of fly ash from pilot scale fluidised bed combustion of lignite, bituminous coal, wood chips and their blends. Fuel 86(14):2186–2193

    Article  Google Scholar 

  18. Kutchko BG, Kim AG (2006) Fly ash characterization by SEM–EDS. Fuel 85(17–18):2537–2544

    Article  Google Scholar 

  19. Tang Z, Ma S, Ding J, Wang Y, Zheng S, Zhai G (2013) Current status and prospects of fly ash utilization in China. In: 2013 World of Coal Ash (WOCA) Conference. Lexington, pp 1–7

  20. Fytianos K, Tsaniklidi B, Voudrias E (1998) Leachability of heavy metals in Greek fly ash from coal combustion. Environ Int 24(4):477–486

    Article  Google Scholar 

  21. Williams PT (2013) Waste treatment and disposal, 2nd edn. Jonh Wiley & Sons Ltd., England

    Google Scholar 

  22. Querol X, Moreno N, Umana J, Alastuey A, Hernández E, López-Soler A et al (2002) Synthesis of zeolites from coal fly ash: an overview. Int J Coal Geol 50(1):413–423

    Article  Google Scholar 

  23. Bada SO, Potgieter-Vermaak S (2008) Evaluation and treatment of coal fly ash for adsorption application. Leonardo Electon J Pract Technol 12:37–48

    Google Scholar 

  24. Ferreira C, Ribeiro A, Ottosen L (2003) Possible applications for municipal solid waste fly ash. J Hazard Mater 96(2):201–216

    Article  Google Scholar 

  25. Iyer R, Scott J (2001) Power station fly ash—a review of value-added utilization outside of the construction industry. Resour Conserv Recycl 31(3):217–228

    Article  Google Scholar 

  26. Ferraiolo G, Zilli M, Converti A (1990) Fly ash disposal and utilization. J Chem Technol Biotechnol 47(4):281–305. doi:10.1002/jctb.280470402

    Article  Google Scholar 

  27. Fishbein L (1984) Overview of analysis of carcinogenic and/or mutagenic metals in biological and environmental samples I. Arsenic, beryllium, cadmium, chromium and selenium. Int J Environ Anal Chem 17(2):113–170

    Article  Google Scholar 

  28. Adriano D, Page A, Elseewi A, Chang A, Straughan I (1980) Utilization and disposal of fly ash and other coal residues in terrestrial ecosystems: a review. J Environ Qual 9(3):333–344

    Article  Google Scholar 

  29. Hui K, Chao C, Kot S (2005) Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash. J Hazard Mater 127(1):89–101

    Article  Google Scholar 

  30. Kersch C, Van Roosmalen M, Woerlee G, Witkamp G (2000) Extraction of heavy metals from fly ash and sand with ligands and supercritical carbon dioxide. Ind Eng Chem Res 39(12):4670–4672

    Article  Google Scholar 

  31. Jakob A, Stucki S, Kuhn P (1995) Evaporation of heavy metals during the heat treatment of municipal solid waste incinerator fly ash. Environ Sci Technol 29(9):2429–2436. doi:10.1021/es00009a040

    Article  Google Scholar 

  32. Kirkelund GM, Jensen PE, Ottosen LM, editors (2013) Electrodialytic extraction of heavy metals from Greenlandic MSWI fly ash as a function of remediation time and L/S ratio. In: 10th international symposium on cold regions development, Anchorage, Alaska

  33. Konishi Y, Matsui M, Fujiwara H, Nomura T, Nakahara K (2003) Zinc leaching from fly ash in municipal waste incineration by thermophilic archaean Acidianus brierleyi growing on elemental sulfur. Sep Sci Technol 38(16):4117–4130

    Article  Google Scholar 

  34. Tateda M, Ike M, Fujita M (1998) Comparative evaluation of processes for heavy metal removal from municipal solid waste incineration fly ash. J Environ Sci 10(4):458–465

    Google Scholar 

  35. Krebs W, Brombacher C, Bosshard PP, Bachofen R, Brandl H (1997) Microbial recovery of metals from solids. FEMS Microbiol Rev 20(3–4), 605–617

    Article  Google Scholar 

  36. Brandl H (2008) Microbial leaching of metals. In: Biotechnology. Wiley-VCH Verlag GmbH, pp 191–224

  37. Brandl H (ed) (2001) Heterotrophic leaching. British mycological society symposium series, vol 23. Electronic reproduction. Cambridge University Press, UK

  38. Bosecker K (1997) Bioleaching: metal solubilization by microorganisms. FEMS Microbiol Rev 20(3–4):591–604

    Article  Google Scholar 

  39. Wang Q, Yang J, Wang Q, Wu T (2009) Effects of water-washing pretreatment on bioleaching of heavy metals from municipal solid waste incinerator fly ash. J Hazard Mater 162(2–3):812–818

    Article  Google Scholar 

  40. Bosshard PP, Bachofen R, Brandl H (1996) Metal leaching of fly ash from municipal waste incineration by Aspergillus niger. Environ Sci Technol 30(10):3066–3070

    Article  Google Scholar 

  41. Mishra D, Rhee Y-H (2010) Current research trends of microbiological leaching for metal recovery from industrial wastes. Curr Res Technol Educ Topics Appl Microbiol Microb Biotechnol 2:1289–1292

    Google Scholar 

  42. Zimmermann J, Dott W (2009) Sequenced bioleaching and bioaccumulation of phosphorus from sludge combustion—a new way of resource reclaiming. Adv Mater Res 71:625–628

    Article  Google Scholar 

  43. Brandl H, Faramarzi MA (2006) Microbe-metal-interactions for the biotechnological treatment of metal-containing solid waste. China Particuol 04(02):93–97. doi:10.1142/S1672251506000212

    Article  Google Scholar 

  44. Krebs W, Bachofen R, Brandl H (2001) Growth stimulation of sulfur oxidizing bacteria for optimization of metal leaching efficiency of fly ash from municipal solid waste incineration. Hydrometallurgy 59(2–3):283–290

    Article  Google Scholar 

  45. Brombacher C, Bachofen R, Brandl H (1998) Development of a laboratory-scale leaching plant for metal extraction from fly ash by Thiobacillus strains. Appl Environ Microbiol 64(4):1237–1241

    Google Scholar 

  46. Xu T-J, Ting Y-P (2004) Optimisation on bioleaching of incinerator fly ash by Aspergillus niger—use of central composite design. Enzyme Microb Technol 35(5):444–454

    Article  MathSciNet  Google Scholar 

  47. Yang J, Wang Q, Wang Q, Wu T (2008) Comparisons of one-step and two-step bioleaching for heavy metals removed from municipal solid waste incineration fly ash. Environ Eng Sci 25(5):783–789

    Article  Google Scholar 

  48. Jadhav U, Hocheng H (2015) Analysis of metal bioleaching from thermal power plant fly ash by Aspergillus niger 34770 culture supernatant and reduction of phytotoxicity during the process. Appl Biochem Biotechnol 175(2):870–881. doi:10.1007/s12010-014-1323-2

    Article  Google Scholar 

  49. Yang J, Wang Q, Luo Q, Wang Q, Wu T (2009) Biosorption behavior of heavy metals in bioleaching process of MSWI fly ash by Aspergillus niger. Biochem Eng J 46(3):294–299

    Article  Google Scholar 

  50. Yang J, Wang Q, Wang Q, Wu T (2009) Heavy metals extraction from municipal solid waste incineration fly ash using adapted metal tolerant Aspergillus niger. Bioresour Technol 100(1):254–260

    Article  Google Scholar 

  51. Xu T-J, Ting Y-P (2009) Fungal bioleaching of incineration fly ash: metal extraction and modeling growth kinetics. Enzyme Microb Technol 44(5):323–328

    Article  Google Scholar 

  52. Tiwari S, Singh S, Garg S (2012) Stimulated phytoextraction of metals from fly ash by microbial interventions. Environ Technol 33(21):2405–2413

    Article  Google Scholar 

  53. Ishigaki T, Nakanishi A, Tateda M, Ike M, Fujita M (2005) Bioleaching of metal from municipal waste incineration fly ash using a mixed culture of sulfur-oxidizing and iron-oxidizing bacteria. Chemosphere 60(8):1087–1094

    Article  Google Scholar 

  54. Seidel A, Zimmels Y, Armon R (2001) Mechanism of bioleaching of coal fly ash by Thiobacillus thiooxidans. Chem Eng J 83(2):123–130

    Article  Google Scholar 

  55. Gadd GM (2000) Bioremedial potential of microbial mechanisms of metal mobilization and immobilization. Curr Opin Biotechnol 11(3):271–279

    Article  Google Scholar 

  56. Burgstaller W, Schinner F (1993) Leaching of metals with fungi. J Biotechnol 27(2):91–116

    Article  Google Scholar 

  57. Alorro RD, Hiroyoshi N, Ito M, Tsunekawa M (2009) Recovery of heavy metals from MSW molten fly ash by CIP method. Hydrometallurgy 97(1):8–14

    Article  Google Scholar 

  58. Alorro RD, Mitani S, Hiroyoshi N, Ito M, Tsunekawa M (2008) Recovery of heavy metals from MSW molten fly ash by carrier-in-pulp method: Fe powder as carrier. Miner Eng 21(15):1094–1101

    Article  Google Scholar 

  59. Wei C, Liu Q, Gu J (2014) Kinetic behaviour of zinc in fly ash melting separation process. Asian J Chem 26(1):251

    Google Scholar 

  60. Fang Z, Gesser H (1996) Recovery of gallium from coal fly ash. Hydrometallurgy 41(2):187–200

    Article  Google Scholar 

  61. Matjie R, Bunt J, Van Heerden J (2005) Extraction of alumina from coal fly ash generated from a selected low rank bituminous South African coal. Miner Eng 18(3):299–310

    Article  Google Scholar 

  62. Navarro R, Guzman J, Saucedo I, Revilla J, Guibal E (2007) Vanadium recovery from oil fly ash by leaching, precipitation and solvent extraction processes. Waste Manag 27(3):425–438

    Article  Google Scholar 

  63. Nagib S, Inoue K (2000) Recovery of lead and zinc from fly ash generated from municipal incineration plants by means of acid and/or alkaline leaching. Hydrometallurgy 56(3):269–292

    Article  Google Scholar 

  64. Sreenivasarao K, Warren G, McKinley M, Gao G (1997) Hydrometallurgical treatment of municipal solid waste fly ash for simultaneous detoxification and metal recovery. J Environ Sci Health Part A 32(4):1225–1245

    Google Scholar 

  65. Wang K-S, Chiang K-Y, Lin K-L, Sun C-J (2001) Effects of a water-extraction process on heavy metal behavior in municipal solid waste incinerator fly ash. Hydrometallurgy 62(2):73–81

    Article  Google Scholar 

  66. Mizutani S, Yoshida T, Sakai S-I, Takatsuki H (1996) Release of metals from MSW I fly ash and availability in alkali condition. Waste Manag 16(5):537–544

    Article  Google Scholar 

  67. Tsai S-L, Tsai M-S (1998) A study of the extraction of vanadium and nickel in oil-fired fly ash. Resour Conserv Recycl 22(3):163–176

    Article  Google Scholar 

  68. Okada T, Tojo Y, Tanaka N, Matsuto T (2007) Recovery of zinc and lead from fly ash from ash-melting and gasification-melting processes of MSW—comparison and applicability of chemical leaching methods. Waste Manag 27(1):69–80

    Article  Google Scholar 

  69. Van der Bruggen B, Vogels G, Van Herck P, Vandecasteele C (1998) Simulation of acid washing of municipal solid waste incineration fly ashes in order to remove heavy metals. J Hazard Mater 57(1):127–144

    Article  Google Scholar 

  70. Fedje KK, Ekberg C, Skarnemark G, Steenari B-M (2010) Removal of hazardous metals from MSW fly ash—an evaluation of ash leaching methods. J Hazard Mater 173(1):310–317

    Article  Google Scholar 

  71. Querol X, Umaña JC, Alastuey A, Ayora C, Lopez-Soler A, Plana F (2001) Extraction of soluble major and trace elements from fly ash in open and closed leaching systems. Fuel 80(6):801–813

    Article  Google Scholar 

  72. Hosseini T, Selomulya C, Zhang L (2013) Comparison of magnesium oxide extraction from Victorian brown coal fly ash and steel making slag using regenerative ammonium chloride. Chemeca 2013 (Brisbane, Australia), vol 41, pp 581–586

  73. Huang K, Inoue K, Harada H, Kawakita H, Keisuke O (2011) Leaching behavior of heavy metals with hydrochloric acid from fly ash generated in municipal waste incineration plants. Trans Nonferrous Met Soc China 21(6):1422–1427

    Article  Google Scholar 

  74. Huang K, Inoue K, Harada H, Kawakita H, Ohto K (2011) Leaching of heavy metals by citric acid from fly ash generated in municipal waste incineration plants. J Mater Cycles Waste Manag 13(2):118–126

    Article  Google Scholar 

  75. Ugurlu A (2004) Leaching characteristics of fly ash. Environ Geol 46(6–7):890–895

    Article  Google Scholar 

  76. Kalembkiewicz J, Sitarz-Palczak E (2015) Efficiency of leaching tests in the context of the influence of the fly ash on the environment. J Ecol Eng 16(1):67–80

    Article  Google Scholar 

  77. Nugteren HW, Janssen-Jurkovícová M, Scarlett B (2002) Removal of heavy metals from fly ash and the impact on its quality. J Chem Technol Biotechnol 77(3):389–395

    Article  Google Scholar 

  78. Baba A, Kaya A (2004) Leaching characteristics of fly ash from thermal power plants of Soma and Tunçbilek, Turkey. Environ Monit Assess 91(1–3):171–181

    Article  Google Scholar 

  79. Bo D, Zhang F-S, Zhao L (2009) Influence of supercritical water treatment on heavy metals in medical waste incinerator fly ash. J Hazard Mater 170(1):66–71

    Article  Google Scholar 

  80. Katsuura H, Inoue T, Hiraoka M, Sakai S (1996) Full-scale plant study on fly ash treatment by the acid extraction process. Waste Manag 16(5–6):491–499

    Article  Google Scholar 

  81. Seidel A, Zimmels Y (1998) Mechanism and kinetics of aluminum and iron leaching from coal fly ash by sulfuric acid. Chem Eng Sci 53(22):3835–3852

    Article  Google Scholar 

  82. Kazonich G, Kim AG, Dahlberg MD, editors (2003) Comparison of leaching results for three high mercury fly ash samples. In: Proceedings of the Air Quality IV: Mercury, Trace Elements, and Particulate Matter Conference

  83. Nayak N, Panda CR (2010) Aluminium extraction and leaching characteristics of Talcher Thermal Power Station fly ash with sulphuric acid. Fuel 89(1):53–58

    Article  Google Scholar 

  84. Wu C-y Yu, H-f Zhang H-f (2012) Extraction of aluminum by pressure acid-leaching method from coal fly ash. Trans Nonferrous Met Soc China 22(9):2282–2288

    Article  Google Scholar 

  85. Li L-s Wu, Y-s Liu Y-y, Y-c Zhai (2011) Extraction of alumina from coal fly ash with sulfuric acid leaching method. Chin J Process Eng 11(2):254–258

    Google Scholar 

  86. Xu YH, Nakajima T, Ohki A (2001) Leaching of arsenic from coal fly ashes 1. Leaching behavior of arsenic and mechanism study. Toxicol Environ Chem 81(1–2):55–68

    Article  Google Scholar 

  87. Nazari E, Rashchi F, Saba M, Mirazimi S (2014) Simultaneous recovery of vanadium and nickel from power plant fly-ash: optimization of parameters using response surface methodology. Waste Manag 34(12):2687–2696

    Article  Google Scholar 

  88. McNally D, Crowley-Parmentier J, Whitman B (2012) Trace metal leaching and bioavailability of coal-generated fly ash. Int Res J Environ Sci 1(5):76–80

    Google Scholar 

  89. Yang GC, Tsai C-M (1998) A study on heavy metal extractability and subsequent recovery by electrolysis for a municipal incinerator fly ash. J Hazard Mater 58(1):103–120

    Article  Google Scholar 

  90. Seidel A, Sluszny A, Shelef G, Zimmels Y (1999) Self inhibition of aluminum leaching from coal fly ash by sulfuric acid. Ceram Int 72(3):195–207

    Google Scholar 

  91. Xue J, Wang W, Wang Q (2008) Traditional and microwave acid extraction of heavy metals from MSWI fly ash and their redistribution of fractions. Huan Jing Ke Xue (Ch) 29(2):535–539

    Google Scholar 

  92. Pangayao D, Gallardo S, editors (2014) Leaching of chromium from coal ash using citric acid, oxalic acid and gluconic acid by batch leaching procedure. In: IEEE 2014 International Conference on Humanoid, Nanotechnology, Information Technology, Communication and Control, Environment and Management (HNICEM)

  93. Torma AE, Singh AK (1993) Acidolysis of coal fly ash by Aspergillus niger. Fuel 72(12):1625–1630

    Article  Google Scholar 

  94. Miravet R, López-Sánchez JF, Rubio R (2006) Leachability and analytical speciation of antimony in coal fly ash. Anal Chim Acta 576(2):200–206

    Article  Google Scholar 

  95. Ettler V, Vrtišková R, Mihaljevič M, Šebek O, Grygar T, Drahota P (2009) Cadmium, lead and zinc leaching from smelter fly ash in simple organic acids—simulators of rhizospheric soil solutions. J Hazard Mater 170(2):1264–1268

    Article  Google Scholar 

  96. Parvizi R, Khaki J, Moayed M, Ardani M (2012) Hydrometallurgical extraction of vanadium from mechanically milled oil-fired fly ash: analytical process optimization by using Taguchi design method. Metall Mater Trans B 43(6):1269–1276. doi:10.1007/s11663-012-9709-4

    Article  Google Scholar 

  97. Wang J, Ban H, Teng X, Wang H, Ladwig K (2006) Impacts of pH and ammonia on the leaching of Cu(II) and Cd(II) from coal fly ash. Chemosphere 64(11):1892–1898

    Article  Google Scholar 

  98. Hong K-J, Tokunaga S, Kajiuchi T (2000) Extraction of heavy metals from MSW incinerator fly ashes by chelating agents. J Hazard Mater 75(1):57–73

    Article  Google Scholar 

  99. Hong KJ, Tokunaga S, Ishigami Y, Kajiuchi T (2000) Extraction of heavy metals from MSW incinerator fly ash using saponins. Chemosphere 41(3):345–352

    Article  Google Scholar 

  100. Janoš P, Wildnerová M, Loučka T (2002) Leaching of metals from fly ashes in the presence of complexing agents. Waste Manag 22(7):783–789

    Article  Google Scholar 

  101. Harris WR, Silberman D (1983) Time-dependent leaching of coal fly ash by chelating agents. Environ Sci Technol 17(3):139–145

    Article  Google Scholar 

  102. Arroyo F, Fernández-Pereira C, Coca P (2010) Precipitation of germanium from coal fly ash leachates. Coal Combust Gasif Prod 2:28–34

    Google Scholar 

  103. Seggiani M, Vitolo S, D’Antone S (2006) Recovery of nickel from Orimulsion fly ash by iminodiacetic acid chelating resin. Hydrometallurgy 81(1):9–14

    Article  Google Scholar 

  104. Yu C, Ying X, Yueyang F (2014) Optimizing extraction process of heavy metals in fly ash using saponins by response surface methodology. CIESC J 65(2):701–710

    Google Scholar 

  105. Bipp H-P, Wunsch P, Fischer K, Bieniek D, Kettrup A (1998) Heavy metal leaching of fly ash from waste incineration with gluconic acid and a molasses hydrolysate. Chemosphere 36(11):2523–2533

    Article  Google Scholar 

  106. Harris WR, Silberman D (1988) Leaching of metal ions from fly ash by canine serum. Environ Sci Technol 22(1):109–112

    Article  Google Scholar 

  107. Rahaman MA, Gafur MA, Kurny ASW (2013) Kinetics of recovery of alumina from coal fly ash through fusion with sodium hydroxide. Am J Mater Eng Technol 1(3):54–58

    Google Scholar 

  108. Zhu P, Dai H, Han L, Xu X, Cheng L, Wang Q et al (2015) Aluminum extraction from coal ash by a two-step acid leaching method. J Zhejiang Univ Sci A 16(2):161–169

    Article  Google Scholar 

  109. Tsuboi I, Kasai S, Kunugita E, Komasawa I (1991) Recovery of gallium and vanadium from coal fly ash. J Chem Eng Jpn 24(1):15–20

    Article  Google Scholar 

  110. Nurmesniemi H, Pöykiö R, Kuokkanen T, Rämö J (2008) Chemical sequential extraction of heavy metals and sulphur in bottom ash and in fly ash from a pulp and paper mill complex. Waste Manag Res 26(4):389–399

    Article  Google Scholar 

  111. Fernandez-Turiel J, De Carvalho W, Cabañas M, Querol X, Lopez-Soler A (1994) Mobility of heavy metals from coal fly ash. Environ Geol 23(4):264–270

    Article  Google Scholar 

  112. Ariese F, Swart K, Morabito R, Brunori C, Balzamo S, Slobodnik J et al (2002) Leaching studies of inorganic and organic compounds from fly ash. Int J Environ Anal Chem 82(11–12):751–770

    Article  Google Scholar 

  113. Xue J, Wang W, Wang Q, Liu S, Yang J, Wui T (2010) Removal of heavy metals from municipal solid waste incineration (MSWI) fly ash by traditional and microwave acid extraction. J Chem Technol Biotechnol 85(9):1268–1277

    Article  Google Scholar 

  114. Levasseur B, Chartier M, Blais J-F, Mercier G (2006) Metals removal from municipal waste incinerator fly ashes and reuse of treated leachates. J Environ Eng 132(5):497–505

    Article  Google Scholar 

  115. Jegadeesan G, Al-Abed SR, Pinto P (2008) Influence of trace metal distribution on its leachability from coal fly ash. Fuel 87(10):1887–1893

    Article  Google Scholar 

  116. Ferreira C, Jensen P, Ottosen L, Ribeiro A (2005) Removal of selected heavy metals from MSW fly ash by the electrodialytic process. Eng Geol 77(3):339–347

    Article  Google Scholar 

  117. Pedersen AJ (2002) Evaluation of assisting agents for electrodialytic removal of Cd, Pb, Zn, Cu and Cr from MSWI fly ash. J Hazard Mater 95(1):185–198

    Article  Google Scholar 

  118. Kirkelund GM, Damoe AJ, Ottosen LM (2013) Electrodialytic removal of Cd from biomass combustion fly ash suspensions. J Hazard Mater 250:212–219

    Article  Google Scholar 

  119. Pazos M, Kirkelund GM, Ottosen LM (2010) Electrodialytic treatment for metal removal from sewage sludge ash from fluidized bed combustion. J Hazard Mater 176(1):1073–1078

    Article  Google Scholar 

  120. Hansen HK, Ottosen LM, Villumsen A (2004) Electrodialytic removal of cadmium from straw combustion fly ash. J Chem Technol Biotechnol 79(7):789–794

    Article  Google Scholar 

  121. Pedersen AJ, Ottosen LM, Villumsen A (2005) Electrodialytic removal of heavy metals from municipal solid waste incineration fly ash using ammonium citrate as assisting agent. J Hazard Mater 122(1):103–109

    Article  Google Scholar 

  122. Lima A, Ottosen LM, Ribeiro AB (2012) Assessing fly ash treatment: remediation and stabilization of heavy metals. J Environ Manag 95:S110–S115

    Google Scholar 

  123. Y-L Zhang, Kasai E (2004) Effect of chlorine on the vaporization behavior of zinc and lead during high temperature treatment of dust and fly ash. ISIJ Int 44(9):1457–1468

    Article  Google Scholar 

  124. Jakob A, Stucki S, Struis RPWJ (1996) Complete heavy metal removal from fly ash by heat treatment: influence of chlorides on evaporation rates. Environ Sci Technol 30(11):3275–3283

    Article  Google Scholar 

  125. Nowak B, Rocha SF, Aschenbrenner P, Rechberger H, Winter F (2012) Heavy metal removal from MSW fly ash by means of chlorination and thermal treatment: influence of the chloride type. Chem Eng J 179:178–185

    Article  Google Scholar 

  126. Kirk DW, Chan CC, Marsh H (2002) Chromium behavior during thermal treatment of MSW fly ash. J Hazard Mater 90(1):39–49

    Article  Google Scholar 

  127. Nowak B, Pessl A, Aschenbrenner P, Szentannai P, Mattenberger H, Rechberger H et al (2010) Heavy metal removal from municipal solid waste fly ash by chlorination and thermal treatment. J Hazard Mater 179(1):323–331

    Article  Google Scholar 

  128. Nowak B, Aschenbrenner P, Winter F (2013) Heavy metal removal from sewage sludge ash and municipal solid waste fly ash—a comparison. Fuel Process Technol 105:195–201

    Article  Google Scholar 

  129. Nowak B, Pessl A, Aschenbrenner P, Mattenberger H, Friebert A, Rechberger H et al. editors (2009) Thermal processing for heavy metal removal of municipal solid waste fly ash. In: Proceedings of the European Combustion Meeting 2009. Vienna, Austria

  130. Matsuno M, Tomoda K, Nakamura T (2003) Volatilization mechanism of Pb from fly ash in municipal waste incinerator. Mater Trans 44(12):2481–2488

    Article  Google Scholar 

  131. Rio S, Verwilghen C, Ramaroson J, Nzihou A, Sharrock P (2007) Heavy metal vaporization and abatement during thermal treatment of modified wastes. J Hazard Mater 148(3):521–528

    Article  Google Scholar 

  132. Wang K-S, Sun C-J, Liu C-Y (2001) Effects of the type of sintering atmosphere on the chromium leachability of thermal-treated municipal solid waste incinerator fly ash. Waste Manag 21(1):85–91

    Article  Google Scholar 

  133. Hu H, Luo G, Liu H, Qiao Y, Xu M, Yao H (2013) Fate of chromium during thermal treatment of municipal solid waste incineration (MSWI) fly ash. Proc Combust Inst 34(2):2795–2801

    Article  Google Scholar 

  134. Bai G, Qiao Y, Shen B, Chen S (2011) Thermal decomposition of coal fly ash by concentrated sulfuric acid and alumina extraction process based on it. Fuel Process Technol 92(6):1213–1219

    Article  Google Scholar 

  135. Stucki S, Jakob A (1998) Thermal treatment of incinerator fly ash: factors influencing the evaporation of ZnCl2. Waste Manag 17(4):231–236

    Article  Google Scholar 

  136. Chan CC, Kirk DW (1999) Behaviour of metals under the conditions of roasting MSW incinerator fly ash with chlorinating agents. J Hazard Mater 64(1):75–89

    Article  Google Scholar 

  137. Liu Y, Zheng L, Li X, Xie S (2009) SEM/EDS and XRD characterization of raw and washed MSWI fly ash sintered at different temperatures. J Hazard Mater 162(1):161–173

    Article  Google Scholar 

  138. Chan CCY, Kirk DW, Marsh H (2000) The behaviour of Al in MSW incinerator fly ash during thermal treatment. J Hazard Mater 76(1):103–111

    Article  Google Scholar 

  139. Struis RP, Ludwig C, Lutz H, Scheidegger AM (2004) Speciation of zinc in municipal solid waste incineration fly ash after heat treatment: an X-ray absorption spectroscopy study. Environ Sci Technol 38(13):3760–3767

    Article  Google Scholar 

  140. Zhu J, Zhao L, Chen M, Zhang F-S (2011) Removal of heavy metals from hazardous waste incinerator fly ash by vacuum-aided heat treatment. Environ Eng Sci 28(10):743–748

    Article  Google Scholar 

  141. Xie Y, Zhu J (2012) The detoxification of medical waste incineration fly ash using self-propagating reaction. Proc Environ Sci 16:222–228

    Article  Google Scholar 

  142. Schlumberger S, Schuster M, Ringmann S, Koralewska R (2007) Recovery of high purity zinc from filter ash produced during the thermal treatment of waste and inerting of residual materials. Waste Manag Res 25(6):547–555

    Article  Google Scholar 

  143. Iretskaya S, Nzihou A, Zahraoui C, Sharrock P (1999) Metal leaching from MSW fly ash before and after chemical and thermal treatments. Environ Prog 18(2):144–148

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rabia Nazir.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Meer, I., Nazir, R. Removal techniques for heavy metals from fly ash. J Mater Cycles Waste Manag 20, 703–722 (2018). https://doi.org/10.1007/s10163-017-0651-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10163-017-0651-z

Keywords

Navigation