Journal of Material Cycles and Waste Management

, Volume 20, Issue 1, pp 489–495 | Cite as

Synthesis and characterization of zeolites NaA and NaX from coal gangue

  • Jianlong Chen
  • Xinwei Lu


Zeolites NaA and NaX were synthesized from initial coal gangue (milled sample) and pretreated coal gangue (calcinated and acid immersed sample) by an alkali fusion method prior to hydrothermal treatment, which started by mixing NaOH with coal gangue at an optimal weight ratio of nearly 1.2:1. Results show that zeolite NaA was successfully synthesized by alkali fusion at 650 and 950 °C from initial coal gangue, while zeolite NaX was synthesized by alkali fusion at 600 °C from pretreated coal gangue. Zeolites NaX with different specific surface area, external surface area, surface area of micropore and crystallinity were synthesized when the molar ratio of SiO2/Al2O3 in raw materials ranges from 3.46 to 10.0.


Zeolite NaA Zeolite NaX Coal gangue Synthesis Characterization 



The research was supported by the National Natural Science Foundation of China through Grant 41271510, the Research and Development Project of Science and Technology of Shaanxi Province through Grant 2014K15-01-05, and the Fundamental Research Funds for the Central University through Grants GK201601009. We acknowledge Fuqiang Zhao, Mengmeng Zhang, Xue Xu, and Ni Zhao for their help in samples’ collection and preparation.


  1. 1.
    Mandal A, Sengupta D (2003) Radioelemental study of Kolaghat, thermal power plant, West Bengal, India: possible environmental hazards. Environ Geol 44:180–186Google Scholar
  2. 2.
    Bhuiyan MAH, Parvez L, Islam MA, Dampare SB, Suzuki S (2010) Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. J Hazard Mater 173:384–392CrossRefGoogle Scholar
  3. 3.
    Lu X, Jia X, Wang L (2006) Natural radioactivity of coal and its by-productions in the Baoji coal-fired power plant, China. Currt Sci 91:1508–1511Google Scholar
  4. 4.
    Cao J, Liu Y, Guo G (2004) The current situation in comprehensive utilization of gangue. Tech Equi Environ Pollut Contr 5(1):19–22 (in Chinese) Google Scholar
  5. 5.
    Liang A, Kuang S, Ding H (2004) The discussion of comprehensive utilization of coal gangue. Chine Resour Compre Utiliz 2:11–14 (in Chinese) Google Scholar
  6. 6.
    Xu H, Song W, Cao W, Shao G, Lu H, Yang D, Chen D, Zhang R (2016) Utilization of coal gangue for the production of brick. J Mater Cycles Waste Manag. doi: 10.1007/s10163-016-0521-0 Google Scholar
  7. 7.
    Li D, Song X, Gong C, Pan Z (2006) Research on cementitious behavior and mechanism of pozzolanic cement with coal gangue. Cem Concr Res 36:1752–1759CrossRefGoogle Scholar
  8. 8.
    Jameson CJ, Jameson AK, Lim HM (1997) Competitive adsorption of xenon and krypton in zeolite NaA: 129Xe nuclear magnetic resonance studies and grand canonical Monte Carlo simulations. J Chem Phys 107:4364–4372CrossRefGoogle Scholar
  9. 9.
    Darkrim F, Aoufi A, Malbrunot P, Levesque D (2000) Hydrogen adsorption in the NaA zeolite: a comparison between numerical simulations and experiments. J Chem Phys 112:5991–5999CrossRefGoogle Scholar
  10. 10.
    Huang Y, Wang K, Dong D, Li D, Hill MR, Hill AJ, Wang H (2010) Synthesis of hierarchical porous zeolite NaY particles with controllable particle sizes. Micropor Mesopor Mater 127:167–175CrossRefGoogle Scholar
  11. 11.
    Ojha K, Pradhan NC, Samanta AN (2004) Zeolite from fly ash: synthesis and characterization. Bull Mater Sci 27:555–564CrossRefGoogle Scholar
  12. 12.
    Chandrasekhar S, Pramada PN (1999) Investigation on the synthesis of zeolite NaX from Kerala kaolin. J Poro Mater 6:283–297CrossRefGoogle Scholar
  13. 13.
    Zhan BZ, White MA, Lumsden M, Mueller-Neuhaus J, Robertson KN, Cameron TS, Gharghouri M (2002) Control of particle size and surface properties of crystals of NaX zeolite. Chem Mater 14:3636–3642CrossRefGoogle Scholar
  14. 14.
    Ghorai PK, Sluiter M, Yashonath S, Kawazoe Y (2006) Intermolecular potential for methane in zeolite A and Y: adsorption isotherm and related properties. Solid State Sci 8:248–258CrossRefGoogle Scholar
  15. 15.
    Nibou D, Mekatel H, Amokrane S, Barkat M, Trari M (2010) Adsorption of Zn2+ ions onto NaA and NaX zeolites: kinetic, equilibrium and thermodynamic studies. J Hazard Mater 173:637–646CrossRefGoogle Scholar
  16. 16.
    Zhao Y, Zhang B, Zhang X, Wang J, Liu J, Chen R (2010) Preparation of highly ordered cubic NaA zeolite from halloysite mineral for adsorption of ammonium ions. J Hazard Mater 178:658–664CrossRefGoogle Scholar
  17. 17.
    Bouizi Y, Paillaud JL, Simon L, Valtchev V (2007) Seeded synthesis of very high silica zeolite A. Chem Mater 19:652–654CrossRefGoogle Scholar
  18. 18.
    Sasaki H, Oumi Y, Sadakane M, Sano T (2010) Synthesis of single phase Ca-α-SiAlON using Y-type zeolite. J Eur Ceram Soc 30:1537–1541CrossRefGoogle Scholar
  19. 19.
    Braschi I, Blasioli S, Gigli L, Gessa CE, Alberti A, Martucci A (2010) Removal of sulfonamide antibiotics from water: evidence of adsorption into an organophilic zeolite Y by its structural modifications. J Hazard Mater 178:218–225CrossRefGoogle Scholar
  20. 20.
    Inada M, Eguchi Y, Enomoto N, Hojo J (2005) Synthesis of zeolite from coal fly ash with different silica-alumina composition. Fuel 84:299–304CrossRefGoogle Scholar
  21. 21.
    Tanaka H, Furusawa S, Hino R (2002) Synthesis, characterization, and formation process of NaX zeolite from coal fly ash. J Mater Synth Proc 10:143–148CrossRefGoogle Scholar
  22. 22.
    Tanaka H, Miyagawa A, Eguchi H, Hino R (2004) Synthesis of a single-phase Na-A zeolite from coal fly ash by dialysis. Ind Eng Chem Res 43:6090–6094CrossRefGoogle Scholar
  23. 23.
    Zhang X, Tang D, Zhang M, Yang R (2013) Synthesis of NaX zeolite: Influence of crystallization time, temperature and batch molar ratio SiO2/Al2O3 on the particulate properties of zeolite crystals. Pow Tech 235:322–328CrossRefGoogle Scholar
  24. 24.
    Fotovat F, Kazemian H, Kazemeini M (2009) Synthesis of Na-A and faujasitic zeolites from high silicon fly ash. Mater Res Bull 44:913–917CrossRefGoogle Scholar
  25. 25.
    Wang MR, Jia DC, He PG, Zhou Y (2010) Influence of calcination temperature of kaolin on the structure and properties of final geopolymer. Mater Lett 64:2551–2554CrossRefGoogle Scholar
  26. 26.
    Hollman GG, Steenbruggen G, Janssen JM (1999) A two-step process for the synthesis of zeolites from coal fly ash. Fuel 78:1225–1230CrossRefGoogle Scholar
  27. 27.
    Shigemoto N, Hayashi H, Miyaura K (1993) Selective formation of Na-X zeolite from coal fly ash by fusion with sodium hydroxide prior to hydrothermal reaction. J Mater Sci 28:4781–4786CrossRefGoogle Scholar
  28. 28.
    Tan WC, Yap SY, Matsumoto A, Othman R, Yeoh FY (2011) Synthesis and characterization of zeolites NaA and NaY from rice husk ash. Adsorption 17:863–868CrossRefGoogle Scholar
  29. 29.
    Szostak R (1997) Molecular sieves: principles of synthesis and identification. Springer, New YorkGoogle Scholar
  30. 30.
    Ríos CA, Williams CD, Fullen MA (2009) Nucleation and growth history of zeolite LTA synthesized from kaolinite by two different methods. Appl Clay Sci 42:446–454CrossRefGoogle Scholar
  31. 31.
    Belver C, Bañares Muñoz MA, Vicente MA (2002) Chemical activation of a kaolinite under acid and alkaline conditions. Chem Mater 14:2033–2043CrossRefGoogle Scholar
  32. 32.
    Qiu L, Laws PA, Zhan BZ, White MA (2006) Thermodynamic investigations of zeolites NaX and NaY. Can J Chem 84:134–139CrossRefGoogle Scholar

Copyright information

© Springer Japan 2017

Authors and Affiliations

  1. 1.School of Tourism and EnvironmentShaanxi Normal UniversityXi’anPeople’s Republic of China

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