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Journal of Material Cycles and Waste Management

, Volume 20, Issue 1, pp 431–438 | Cite as

Evaluation by year of the valuable/hazardous material content of lithium-ion secondary battery cells and other components of notebook computer battery packs

  • Shunsuke Kuzuhara
  • Yuta Akimoto
  • Kazu Shibata
  • Masahiro Oguchi
  • Atsushi Terazono
ORIGINAL ARTICLE
  • 176 Downloads

Abstract

Our objective was to provide the information necessary to efficiently recover metals from end-of-life lithium-ion secondary batteries by assessing the metal content by year of production. In addition, we analyzed the concentrations of Sn and the toxic metals Pb, Cr, and Cd in battery pack components, including printed circuit boards and cables. Li and Co were the only active substances in the cathode materials of lithium-ion secondary batteries produced from 1997 to 2005. Ni and Mn also were used in cathode materials of batteries produced from 2007 to 2011. However, Ni became the main constituent in 2012, and Mn was not detected in batteries from that year. For printed circuit boards and cables, Pb concentrations from 1997 to 2004 ranged from 6451 to 12,107 mg/kg, but from 2005 onward maximum concentrations were 513 mg/kg, clearly showing that substitution for Pb had been completed a year before the EU Restriction on Hazardous Substances (RoHS) Directive came into effect.

Keywords

Li-ion battery Rare metal Recovery WEEE RoHS 

Notes

Acknowledgements

The authors acknowledge research funding provided by the Environment Research and Technology Development Fund from the Ministry of the Environment of Japan (3K143010). The authors also thank FIT FRONTIER, Ltd. (Mr. Mitsuhiro SENDA and Mr. Masahiro KUSAKA) for providing the samples and the helpful discussions.

Supplementary material

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Supplementary material 1 (PPTX 66 KB)
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Supplementary material 2 (PPTX 65 KB)
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Supplementary material 3 (PPTX 53 KB)

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Copyright information

© Springer Japan 2017

Authors and Affiliations

  1. 1.National Institute of TechnologySendai CollegeNatoriJapan
  2. 2.Institute of Multidisciplinary Research for Advanced MaterialsTohoku UniversitySendaiJapan
  3. 3.TOYOCOLOR Co., Ltd.TokyoJapan
  4. 4.Center for Material Cycles and Waste Management ResearchNational Institute for Environmental StudiesTsukubaJapan

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