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Synthesis and characterization of a novel ionic liquid polymer: Poly(1-(3-aminobenzyl)-3-methylimidazolium chloride)

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Abstract

A new type of polymerizable ionic liquid (IL) 1-(3-aminobenzyl)-3-methylimidazolium chloride (AMIC) was synthesized to obtain a novel polymer salt poly(1-(3-aminobenzyl)-3-methylimidazolium chloride) (PAMIC). The AMIC was structurally characterized by mass spectrometry and Fourier transform infrared spectrometry (FTIR). The structure, morphology and properties of PAMIC were investigated by FTIR, ultraviolet visible absorption spectra (UV-Vis), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), conductivity measurement and thermo-gravimetric analysis (TGA). The PAMIC was spherulitic with an average diameter of about 50 nm and showed high conductivity and excellent thermal stability.

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References

  1. Sheldon, R., Chem. Commun., 2001: 2399

    Google Scholar 

  2. Wilkes, J.S., J. Mol. Catal. A: Chem., 2004, 214: 11

    Article  CAS  Google Scholar 

  3. Dupont, J. and Suarez, P.A.Z., Chem. Phys., 2006, 8: 2441

    CAS  Google Scholar 

  4. Mehdi Taghavi, M.G., Hassanzadeh, M. and Nasab, S.M.A., Chinese J. Polym. Sci., 2013, 31(4): 679

    Article  Google Scholar 

  5. Mansoori, S.S.S.Y., Atghia, S.V., Zamanloo, M.R. and Imanzadeh, G.h., Chinese J. Polym. Sci., 2011, 29(6): 699

    Article  CAS  Google Scholar 

  6. Zhao, H., Xia, S. and Ma, P., J. Chem. Technol. Biotechno., 2005, 80: 1089

    Article  CAS  Google Scholar 

  7. Dietz, M.L. and Stepinski, D.C., Green Chem., 2005, 7: 747

    Article  CAS  Google Scholar 

  8. Pârvulescu, V.I. and Hardacre, C., Chem. Rev., 2007, 107: 2615

    Article  Google Scholar 

  9. Rantwijk, F. and Sheldon, R.A., ChemInform, 2007, 38: 42

    Google Scholar 

  10. Zhang, H., Hong, K. and Mays, J.W., Macromolecules, 2002, 35: 5738

    Article  CAS  Google Scholar 

  11. Perrier, S., Davis, T.P., Carmichael, A.J. and Haddleton, D.M., Chem. Commun., 2002: 2226

  12. Biedroń, T. and Kubisa, P., Polym. Int., 2003, 52: 1584

    Article  Google Scholar 

  13. Yoshizawa, M., Hirao, M., Ito, K. and Ohno, H., J. Mater. Chem., 2001, 11: 1057

    Article  CAS  Google Scholar 

  14. Lu, J., Yan, F. and Texter, J., Prog. Polym. Sci., 2009, 34: 431

    Article  CAS  Google Scholar 

  15. Lewandowski, A. and Świderska, A., Solid State Ionics, 2003, 161: 243

    Article  CAS  Google Scholar 

  16. Yoshizawa, M., Ogihara, W. and Ohno, H., Polym. Adv. Technol., 2002, 13: 589

    Article  CAS  Google Scholar 

  17. Ogihara, W., Washiro, S., Nakajima H. and Ohno, H., Electrochim. Acta, 2006, 51: 2614

    Article  CAS  Google Scholar 

  18. Nakajima, H. and Ohno, H., Polymer, 2005, 46: 11499

    Article  CAS  Google Scholar 

  19. Ohno, H., Macromol. Symp., 2007, 249: 551

    Article  Google Scholar 

  20. Mu, X., Evans D.G. and Kou, Y., Catal. Lett., 2004, 97: 151

    Article  CAS  Google Scholar 

  21. Fukushima, T., Kosaka, A., Ishimura, Y., Yamamoto, T., Takigawa, T., Ishii, N. and Aida, T., Science, 2003, 300: 2072

    Article  CAS  Google Scholar 

  22. Erdemi, H., Akbey, Ü. and Meyer, W.H., Solid State Ionics, 2010, 181: 1586

    Article  CAS  Google Scholar 

  23. He, D.L., Guo, Y.N., Zhou, Z., Xia, S.B., Xie, X. and Yang, R.H., Electrochem. Commun., 2009, 11: 1671

    Article  CAS  Google Scholar 

  24. Ping, Z., J. Chem. Soc. Faraday Trans., 1996, 92: 3063

    Article  CAS  Google Scholar 

  25. Bhadra, S., Singha, N.K. and Khastgir, D., J. Appl. Polym. Sci., 2008, 107: 2486

    Article  CAS  Google Scholar 

  26. Sinha, S., Bhadra, S. and Khastgir, D., J. Appl. Polym. Sci., 2009, 112: 3135

    Article  CAS  Google Scholar 

  27. Pahal, S., Deepa, M., Bhandari, S., Sood, K. and Srivastava, A., Sol. Energy Mater. Sol. Cells., 2010, 94: 1064

    Article  CAS  Google Scholar 

  28. Zhou, Z., He, D.L., Li, X., Wang, S. and Li, G.X., Polym. Sci. Ser. B., 2008, 50: 209

    Article  Google Scholar 

  29. Zhou, Z., He, D.L., Yang, R.H., Guo, Y.N., Zhong, J.F, and Li, G.X., J. Appl. Electrochem., 2008, 38: 1757

    Article  CAS  Google Scholar 

  30. Zhou, Z., He, D.L., Li, X., Zhang, L. and Li, G.X., Acta Polymerica Sinica (in Chinese), 2007, 8: 757

    Google Scholar 

  31. Qiu, H., Qi, S., Wang, D., Wang, J. and Wu, X., Synthetic Met., 2010, 160: 1179

    Article  CAS  Google Scholar 

  32. Rahy, A. and Yang, D., J. Mater. Lett., 2008, 62: 4311

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China

    De-liang He  (何德良), Fei Li, San-bao Xia, Fu-rong Liu & Ying Xiong

  2. College of Civil Engineering, Hunan University, Changsha, 410082, China

    Quan Zhang  (张泉)

Authors
  1. De-liang He  (何德良)
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  2. Fei Li
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  3. San-bao Xia
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  4. Fu-rong Liu
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  5. Ying Xiong
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  6. Quan Zhang  (张泉)
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Corresponding authors

Correspondence to De-liang He  (何德良) or Quan Zhang  (张泉).

Additional information

This work was financially supported by the Hunan Provincial Natural Science Foundation of China (Nos. 11JJ3015 and 11JJ1009).

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He, Dl., Li, F., Xia, Sb. et al. Synthesis and characterization of a novel ionic liquid polymer: Poly(1-(3-aminobenzyl)-3-methylimidazolium chloride). Chin J Polym Sci 32, 163–168 (2014). https://doi.org/10.1007/s10118-014-1385-1

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  • DOI: https://doi.org/10.1007/s10118-014-1385-1

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