Biodegradable, flame retardant wood-plastic combination via in situ ring-opening polymerization of lactide monomers
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A wood-plastic combination (WPC) was created via in situ polymerization of the l-lactide monomer (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione. Commercial poplar boards (Liriodendron tulipifera) were impregnated with the flame retardant chemical resorcinol bis(diphenyl phosphate)(RDP). These samples were then soaked in a solution of the monomer and deionized water with sulfuric acid 5% wt/wood as a catalyst for polymerization. The wood and solution were placed in a vacuum oven for impregnation and polymerization of the monomers. The wood RDP combination was not flame retardant and had an Izod impact strength that was slightly smaller than neat wood sample. Addition of lactide monomer tripled the Izod impact strength relative to wood, and scanning electron microscope (SEM) images indicated that a polymerized coating had formed which reinforced the porous wood structure. Addition of all three components produced a synergy. The Izod impact strength of the material was nearly 14 times greater and the WPC was flame retardant surpassing the stringent UL-94-V0 requirement.
KeywordsWood Plastic Biodegradable Flame retardant
We would like to thank the NSF-INSPIRE program (Grant #1344267). We would also like to thank the Advanced Energy Center for access to the ThINC facility.
Compliance with ethical standards
Conflict of interest
The authors declare that they have no conflict of interest.
This article does not contain any studies with human participants or animals performed by any of the authors.
- 1.Bergman R, Ibach R, Lapasha C, Denig J (2009) Evaluating physical property changes for small-diameter, plantation-grown southern pine after in situ polymerization of an acrylic monomer. For Prod J 59(10):64–71Google Scholar
- 2.Mubarak A, Khan KM, Idriss Ali, Jahan MS (1999) Characterization of wood and wood-plastic composite. Polym-Plast Technol 38(4):753–765Google Scholar
- 5.Li Y (2011) Wood-polymer composites. In: Tesinova P (ed) Advances in composite materials—analysis of natural and man-made materials. ISBN: 978-953-307-449-8 InTech. http://www.intechopen.com/books/advances-in-composite-materials-analysis-of-natural-and-man-madematerials/wood-polymer-composites. Accessed 09 Sep 2011
- 6.Ren J (2010) Biodegradable poly (lactic acid) synthesis, modification, processing and applications. Tsinghua University Press, BeijingGoogle Scholar
- 14.Bao F, Fu F, Choong E, Hse C (2001) Contribution factor of wood properties of three poplar clones to strength of laminated veneer lumber. Wood Fiber Sci 33(3):345–352Google Scholar
- 15.ASTM D256: Standard test methods for determining the Izod pendulum impact resistance of plastics. ASTM International, West Conshohocken, PA, vol 08.01Google Scholar