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Food Science and Biotechnology

, Volume 27, Issue 2, pp 343–352 | Cite as

An investigation on the physicochemical characterization of interesterified blends of fully hydrogenated palm olein and soybean oil

  • Raheleh Mahjoob
  • Abdorreza Mohammadi Nafchi
  • Elahe Omidbakhsh Amiri
  • Jamshid Farmani
Article
  • 68 Downloads

Abstract

In this study, the effect of interesterification (using sodium methoxide) on physicochemical characteristics of fully hydrogenated palm olein (FHPO)/soybean oil blends (10 ratios) was investigated. Interesterification changed free fatty acid content, decreased oil stability index, solid fat content (SFC) and slip melting point (SMP), and does not affected the peroxide value. With the increase of FHPO ratio, oil stability index, SFC and SMP increased in both the interesterified and non-interesterified blends. Fats with higher FHPO ratio had narrower plastic range, as well. Compared to the initial blends, interesterified fats had wider plastic ranges at lower temperatures. Both the non-interesterified and interesterified blends showed monotectic behavior. The Gompertz function could describe SFC curve (as a function of temperature, saturated fatty acid (SFA) content or both) and SMP (as a function of SFA) of the interesterified fats with high R2 and low mean absolute error.

Keywords

Interesterification Fully hydrogenated palm olein Soybean oil Physicochemical characterization Gompertz function 

Notes

Acknowledgments

Authors are thankful to the managers of Parto Daneh Khazar (Behshahr, Iran) for their assistances.

Compliance with ethical standards

Conflict of interest

Authors declare no conflict of interest.

References

  1. 1.
    Khatoon S, Reddy S, Reddy Y. Plastic fats with zero trans fatty acids by interesterification of mango, mahua and palm oils. Eur. J. Lipid Sci. Technol. 107: 786–791 (2005)CrossRefGoogle Scholar
  2. 2.
    Wang FC, Gravelle AJ, Blake A, Marangoni AG. Novel trans-fat replacement strategies. Curr. Opin. Food Sci. 7: 27–34 (2016)CrossRefGoogle Scholar
  3. 3.
    Rousseau D, Marangoni AG. Chemical interesterification of food lipids: theory and practice. pp. 267–298. In: Food Lipids, Chemistry, Nutrition, and Biotechnology. Akoh CC, Min DB Food Lipids (eds). CRC Press, Inc., Boca Raton, FL, USA (2008)Google Scholar
  4. 4.
    Petrauskaite V, De Greyt W, Kellens M, Huyghebaert A. Physical and chemical properties of trans-free fats produced by chemical interesterification of vegetable oil blends. J. Am. Oil Chem. Soc. 75: 489–493 (1998)CrossRefGoogle Scholar
  5. 5.
    Oliveira PD, Rodrigues AMC, Bezerra CV, Silva LHM. Chemical interesterification of blends with palm stearin and patawa oil. Food Chem. 215: 369–376 (2017)CrossRefGoogle Scholar
  6. 6.
    Ornla-ied P, Sonwai S, Lertthirasuntorn S. Trans-free margarine fat produced using enzymatic interesterification of rice bran oil and hard palm stearin. Food Sci. Biotechnol. 25: 673–680 (2016)CrossRefGoogle Scholar
  7. 7.
    Biswas N, Cheow YL, Tan CP, Kanagaratnam S, Siow LF. Cocoa butter substitute (CBS) produced from palm mid-fraction/palm kernel oil/palm stearin for confectionery fillings. J. Am. Oil Chem. Soc. 1–11 (2017)Google Scholar
  8. 8.
    Ebrahimi L, Farmani J, Bahmaei M. Physicochemical and rheological characterization of lipase-interesterified trans-free blends of fully hydrogenated palm olein and soybean oil. Adv. Food Sci. 37: 111–118 (2015)Google Scholar
  9. 9.
    Masuchi M, Gandra K, Marangoni A, de Sa´Perenha C, Chiu M, Grimaldi R. Fats from chemically interesterified high-oleic sunflower oil and fully hydrogenated palm oil. J. Am. Oil Chem. Soc. 91: 859–866 (2014)CrossRefGoogle Scholar
  10. 10.
    Farmani J, Hamedi M, Safari M, Madadlou A. Trans-free Iranian vanaspati through enzymatic and chemical transesterification of triple blends of fully hydrogenated soybean, rapeseed and sunflower oils. Food Chem. 102: 827–833 (2007)CrossRefGoogle Scholar
  11. 11.
    Farmani J, Hamedi M, Safari M. Production of zero trans Iranian vanaspati using chemical transesterification and blending techniques from palm olein, rapeseed and sunflower oil. Int. J. Food Sci. Technol. 43, 393–399 (2008).CrossRefGoogle Scholar
  12. 12.
    Farmani J, Safari M, Hamedi M. Trans-free fats through interesterification of canola oil/palm olein or fully hydrogenated soybean oil blends. Eur. J. Lipid Sci. Technol. 111: 1212–1220 (2009)CrossRefGoogle Scholar
  13. 13.
    Naeli MH, Farmani J, Zargaran A. Rheological and physicochemical modification of trans-free blends of palm stearin and soybean oil by chemical interesterification. J. Food Process Eng. 1–12 (2016)Google Scholar
  14. 14.
    Farmani J. Modeling of solid fat content of chemically interesterified fully hydrogenated soybean oil and canola oil blends as a function of temperature and saturated fatty acids. Food Measure. 9: 281–289 (2015)CrossRefGoogle Scholar
  15. 15.
    Ebrahimi L, Farmani J, Bahmaei M. Description of melting curves of enzymatically interesterified blends of fully hydrogenated palm olein and soybean oil by sigmoidal functions. Food Biosci. 17: 29–34 (2017)CrossRefGoogle Scholar
  16. 16.
    AOCS. Official methods and recommended practices of American oil chemists’ society.4th ed. Champaign, American Oil Chemists’ Society Press (1996)Google Scholar
  17. 17.
    Jeyarani T, Reddy SY. Preparation of plastic fats with zero trans FA from palm oil. J. Am. Oil Chem. Soc. 80: 1107–1113 (2003)CrossRefGoogle Scholar
  18. 18.
    Karabulut I, Turan S, Ergin G. Effects of chemical interesterification on solid fat content and slip melting point of fat/oil blends. Eur. Food Res. Technol. 218: 224–229 (2004)CrossRefGoogle Scholar
  19. 19.
    Kellens M. Oil modification processes. pp. 153–195. In: Edible Oil Processing. Hamm W, Hamilton RJ, Calliauw G (eds.). Wiley-blackwell. UK (2013)Google Scholar
  20. 20.
    Ledochowska E, Wilczynska E. Comparison of the oxidative stability of chemically and enzymatically interesterified fats. Fett/Lipid. 100: 343–348 (1998)CrossRefGoogle Scholar
  21. 21.
    Kowalski B, Tarnowska K, Gruczynska E, Bekas W. Chemical and enzymatic interesterification of tallow and rapeseed oil equal-weight blend. Eur. J. Lipid Sci. Technol. 106: 655– 664 (2004)CrossRefGoogle Scholar
  22. 22.
    Lee JH, Akoh CC, Lee KT. Physical properties of trans free bakery shortening produced by lipase-catalyzed interesterification. J. Am. Oil Chem. Soc.85: 1–11 (2008)CrossRefGoogle Scholar
  23. 23.
    Ribeiro A, Gioielli L, Gonçalves A, Grimaldi, R. Zero trans fats from soybean oil and fully hydrogenated soybean oil: Physico-chemical properties and food applications. Food Res. Int.42: 401–410 (2009)CrossRefGoogle Scholar
  24. 24.
    Norizzah AR, Chong CL, Cheow CS, Zaliha O. Effects of chemical interesterification on physicochemical properties of palm stearin and palm kernel olein blends. Food Chem. 86: 229– 235 (2004)CrossRefGoogle Scholar
  25. 25.
    Guedes AMM, Ming CC, Ribeiro APB, Da Silva RC, Gioielli LA, Gonçalves LAG. Physicochemical properties of interesterified blends of fully hydrogenated Crambe abyssinica Oil and soybean Oil. J. Am. Oil Chem. Soc. 91:111–123 (2014)CrossRefGoogle Scholar
  26. 26.
    Fauzi SHM, Rashid NA, Omar Z. Effects of chemical interesterification on the physicochemical, microstructural and thermal properties of palm stearin, palm kernel oil and soybean oil blends. Food Chem. 137: 8–17 (2013)CrossRefGoogle Scholar
  27. 27.
    Kadivar S, De Clercq N, Mokbul M, Dewettinck K. Influence of enzymatically produced sunflower oil based cocoa butter equivalents on the phase behavior of cocoa butter and quality of dark chocolate. LWT-Food Sci. Technol. 66: 48-55 (2016)CrossRefGoogle Scholar
  28. 28.
    Augusto PED, Soares BMC, Chiu MC, Goncalves LAG. Modeling the effect of temperature on lipid solid fat content (SFC). Food Res. Int. 45: 132–135 (2012)CrossRefGoogle Scholar
  29. 29.
    Marangoni AG, Rousseau D. Engineering triacylglycerols: the role of interesterification. Trends Food Sci. Technol. 6:329–335 (1995)CrossRefGoogle Scholar
  30. 30.
    Naeli M. H, Farmani J, Zargaran A. Modeling of slip melting point of chemically interesterified fats as a function of fatty acid composition. Iran. J. Nutr. Sci. Food Technol.1175–76 (2016). [In Persian]Google Scholar

Copyright information

© The Korean Society of Food Science and Technology and Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  1. 1.Department of Food Science and Technology, Faculty of Agriculture, Damghan BranchIslamic Azad UniversityDamghanIran
  2. 2.Department of Food Science and Technology, Faculty of Agricultural EngineeringSari Agricultural Sciences and Natural Resources UniversitySariIran

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