Enhanced electrochemical performance of MoS2 anode material with novel composite binder

Abstract

A simple and green approach for creating a highly capacitive molybdenum disulphide (MoS2) anode material for lithium-ion batteries is proposed. The electrode composition consists of MoS2 and conductive water-based binder PEDOT:PSS/CMC (poly(3,4-ethylenedioxythiophene)/poly(styrenesulphonate)/carboxymethyl cellulose). The electrochemical performance of modified electrodes is markedly superior to those with conventional PVDF (polyvinylidene fluoride) and carbon black composition. The electrode provides initial capacity of 1090 mA h g−1 at 0.1 mA g−1, maintains 410 mA h g−1 at 2 mA g−1 and retains 78% of initial capacity after 100 charge-discharge cycles.

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Data availability

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors would like to thank the Centres for X-ray Diffraction Studies, Nanotechnology, and Physical Methods of Surface Investigation of the Research park of Saint Petersburg State University for XRD, SEM, and XPS studies.

Funding

The financial support was from Saint Petersburg State University (grant no. 26455158).

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Correspondence to Veniamin V. Kondratiev.

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Volkov, A.I., Eliseeva, S.N., Tolstopjatova, E.G. et al. Enhanced electrochemical performance of MoS2 anode material with novel composite binder. J Solid State Electrochem 24, 1607–1614 (2020). https://doi.org/10.1007/s10008-020-04701-3

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Keywords

  • Composites
  • PEDOT:PSS
  • Molybdenum disulphide
  • Energy storage
  • Lithium-ion batteries