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MOF-derived binary mixed carbon/metal oxide porous materials for constructing simultaneous determination of hydroquinone and catechol sensor

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Abstract

It is a top priority to simultaneously and accurately detect hydroquinone (HQ) and catechol (CC). Here, a new strategy for constructing simultaneous determination of HQ and CC sensor was proposed by one-step pyrolysis of MIL series metal-organic frameworks materials (MIL-125 (Ti), MIL-101 (Cr), and MIL-101 (Fe)) to obtain uniform-mixed carbon/metal oxide porous materials (TiO2/C900, Cr2O3/C900, and Fe2O3/C900, respectively). And, cyclic voltammetry (CV) was utilized to investigate the electrochemical behavior of the composite materials. It was found that the simultaneous detection of catechol (CC) and hydroquinone (HQ) could be achieved by the sensor consisted of TiO2/C900 with the superior BET-specific surface area and micro-mesoporous characteristics. And, the linear range and detection limit of HQ and CC for the TiO2/C900 sensor were further studied. In addition, it was also found that the pyrolysis temperature and metal centers would affect the internal structures and component of the materials, thus affecting the properties of materials. The experiment provides a new idea for optimizing the simultaneous detection of the dihydroxybenzene isomers.

A new feasible strategy was proposed by introducing the binary uniform-mixed carbon/metal oxide porous materials, by which the calcination temperature and the metal centers of MOFs would be considered to construct the sensor for simultaneous determination of catechol (CC) and hydroquinone (HQ).

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Acknowledgments

The authors gratefully acknowledge the financial supports of the National Natural Science Foundation of China (21207018, 21673039, and 21573042), Natural Science Foundation of Fujian Province (2015J01039, 2018J07001), and Environment and Land Resources Bureau of Pingtan Comprehensive Experimentation Area (DH-1374).

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Authors and Affiliations

  1. Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou, 350007, People’s Republic of China

    Ziyan Wang, Meishan Li, Yingxiang Ye, Yisi Yang, Yaqi Lu, Xiuling Ma, Zhangjing Zhang & Shengchang Xiang

Authors
  1. Ziyan Wang
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  2. Meishan Li
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  3. Yingxiang Ye
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  4. Yisi Yang
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  5. Yaqi Lu
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  6. Xiuling Ma
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  7. Zhangjing Zhang
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  8. Shengchang Xiang
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Corresponding authors

Correspondence to Xiuling Ma or Shengchang Xiang.

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Highlight

1. Binary uniform-mixed carbon/metal oxide porous materials by one-step pyrolysis of MOFs were firstly used to construct the electrochemistry sensor.

2. The electrocatalysis performance of materials can be regulated by adjusting the calcination temperature and the metal centers of MOFs.

3. A promising sensor for the simultaneous determination of dihydroxybenzene isomer has been developed.

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Wang, Z., Li, M., Ye, Y. et al. MOF-derived binary mixed carbon/metal oxide porous materials for constructing simultaneous determination of hydroquinone and catechol sensor. J Solid State Electrochem 23, 81–89 (2019). https://doi.org/10.1007/s10008-018-4111-z

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  • DOI: https://doi.org/10.1007/s10008-018-4111-z

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