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Enhancing the photoelectrochemical performance of BiVO4 by decorating only its (040) facet with self-assembled Ag@AgCl QDs

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Abstract

Decorating a host semiconductor with quantum dots (QDs) is an important strategy for optimizing the separation efficiency and transfer of photogenerated charge carriers. In this work, we designed a heterojunction photoelectrocatalyst in which the (040) facet of BiVO4 was decorated with self-assembled Ag@AgCl QDs (“Ag@AgCl/040BiVO4”). In this photocatalyst, photogenerated charge carriers are efficiently separated using a Z-scheme approach. A facile oil-in-water self-assembly method was employed to generate the composite photocatalyst, which was then characterized via XRD, XPS, SEM, TEM, etc. The results of this characterization indicated that the Ag@AgCl QDs were approximately 5 nm in size and were well dispersed across the (040) crystal facet of BiVO4. PEC measurements indicated that the efficiency of electron–hole separation was enhanced when the BiVO4 was decorated with Ag@AgCl QDs on just one of its facets (040) rather than across all of its surface. An attempt was also made to elucidate the mechanism of interfacial charge transfer in the Ag@AgCl/040BiVO4 system. Decorating a specific crystal facet (040) of BiVO4 with Ag@AgCl QDs was found to facilitate the spatial separation of photogenerated charge carriers and to enhance the redox ability of the system.

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References

  1. Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38

    Article  CAS  PubMed  Google Scholar 

  2. Wang D, Zhang XT, Sun PP, Lu S, Wang LL, Wei YA, Liu YC (2014) Enhanced photoelectrochemical water splitting on hematite thin film with layer-by-layer deposited ultrathin TiO2 under layer. Int J Hydrog Energy 39:16212–16219

  3. Seabold JA, Choi KS (2011) Effect of a cobalt-based oxygen evolution catalyst on the stability and the selectivity of photo-oxidation reactions of a WO3 photoanode. Chem Mater 23:1105–1112

  4. Zhang J, Ma HP, Liu ZF (2017) Highly efficient photocatalyst based on all oxides WO3/Cu2O heterojunction for photoelectrochemical water splitting. Appl Catal B 201:84–91

  5. Kudo A, Ueda K, Kato H, Mikami I (1998) Photocatalytic O2 evolution under visible light irradiation on BiVO4 in aqueous AgNO3 solution. Catal Lett 53:229–230

  6. He Z, Shi Y, Gao C, Wen L, Chen J, Song S (2014) BiOCl/BiVO4 pen heterojunction with enhanced photocatalytic activity under visible-light irradiation. J Phys Chem C 118:389–398

    Article  CAS  Google Scholar 

  7. Kim TW, Choi KS (2014) Nanoporous BiVO4 photoanodes with dual-layer oxygen evolution catalysts for solar water splitting. Science 343:990–994

    Article  CAS  PubMed  Google Scholar 

  8. Pilli SK, Janarthanan R, Deutsch TG, Furtak TE, Brown LD, Turner JA, Herring AM (2013) Efficient photoelectrochemical water oxidation over cobalt-phosphate (Co-Pi) catalyst modified BiVO4/1D-WO3 heterojunction electrodes. Phys Chem Chem Phys 15:14723–14728

  9. Luo W, Wang J, Zhao X, Zhao Z, Li Z, Zou Z (2013) Formation energy and photoelectrochemical properties of BiVO4 after doping at Bi3+ or V5+ sites with higher valence metal ions. Phys Chem Chem Phys 15:1006–1013

    Article  PubMed  Google Scholar 

  10. He H, Berglund SP, Rettie AJE, Chemelewski WD, Xiao P, Zhang Y, Mullins CB (2014) Synthesis of BiVO4 nanoflake array films for photoelectrochemical water oxidation. J Mater Chem A 2:9371–9379

    Article  CAS  Google Scholar 

  11. Li RG, Zhang FX, Wang DG, Yang JX, Li MR, Zhu J, Zhou X (2013) Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4. Nat Commun 4:1432–1438

    Article  CAS  PubMed  Google Scholar 

  12. Wang P, Zheng JY, Zhang D, Kang YS (2015) Selective construction of junctions on different facets of BiVO4 for enhancing photo-activity. New J Chem 39:9918–9925

    Article  CAS  Google Scholar 

  13. Su J, Guo L, Bao N, Grimes CA (2011) Nanostructured WO3/BiVO4 heterojunction films for efficient photoelectrochemical water splitting. Nano Lett 11:1928–1933

    Article  CAS  PubMed  Google Scholar 

  14. Yue DT, Qian XF, Kan M, Ren M, Zhu Y, Jiang LL, Zhao YX (2017) Sulfurated [NiFe]-based layered double hydroxides nanoparticles as efficient co-catalysts for photocatalytic hydrogen evolution using CdTe/CdS quantum dots. Appl Catal B 209:155–160

  15. Gao XF, Li HB, Sun WT, Chen Q, Tang FQ, Peng LM (2009) CdTe quantum dots-sensitized TiO2 nanotube array photoelectrodes. J Phys Chem C 18:7531–7535

    Article  CAS  Google Scholar 

  16. Liang Y, Lin S, Li L, Hu J, Cui W (2015) Oil-in-water self-assembled Ag@AgCl QDs sensitized Bi2WO6: enhanced photocatalytic degradation under visible light irradiation. Appl Catal B 164:192–203

  17. Li H, Sun Y, Cai B, Gana SY, Hana DX, Niua L, Wu TS (2015) Hierarchically Z-scheme photocatalyst of Ag@AgCl decorated on BiVO4 (040) with enhancing photoelectrochemical and photocatalytic performance. Appl Catal B 170-171:206–214

  18. Zhu JL, Liu SM, Yang Q, Xu PP, Ge JH, Guo XT (2016) Fabrication of flower-like Ag@AgCl/Bi2WO6 photocatalyst and its mechanism of photocatalytic degradation. Colloid Surface A 489:275–281

  19. Li JQ, Zhou J, Hao HJ, Zhu ZF (2016) Silver-modified specific (040) facet of BiVO4 with enhanced photoelectrochemical performance. Mater Lett 170:163–166

    Article  CAS  Google Scholar 

  20. Lin S, Li L, Hu J, Liang Y, Cui W (2015) Nano Ag@AgBr surface-sensitized Bi2WO6 photocatalyst: oil-in-water synthesis and enhanced photocatalytic degradation. Appl Surf Sci 324:20–29

  21. Li G, Wong KH, Zhang X, Hu C, Yu JC, Chan RCY, Wong PK (2009) Degradation of acid orange 7 using magnetic AgBr under visible light: the roles of oxidizing species. Chemosphere 76:1185–1191

  22. Yuan Q, Chen L, Xiong M, He J, Luo SL, Au CT, Yin SF (2014) Cu2O/BiVO4 heterostructures: synthesis and application in simultaneous photocatalytic oxidation of organic dyes and reduction of Cr(VI) under visible light. Chem Eng J 255:394–402

    Article  CAS  Google Scholar 

  23. Yu J, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–2169

    Article  CAS  Google Scholar 

  24. And AK, Kamat PV (2007) Interactions of single wall carbon nanotubes with methyl viologen radicals. Quantitative estimation of stored electrons. J Phys Chem C 111:9012–9015

    Article  CAS  Google Scholar 

  25. Wang D, Jiang H, Zong X, Xu Q, Ma Y, Li G, Li C (2011) Crystal facet dependence of water oxidation on BiVO4 sheets under visible light irradiation. Chem Eur J 17:1275–1282

    Article  CAS  PubMed  Google Scholar 

  26. Qiu YF, Chen PL, Liu MH (2010) Evolution of various porphyrin nanostructures via an oil/aqueous medium: controlled self-assembly, further organization, and supramolecular chirality. J Am Chem Soc 132:9644–9652

    Article  CAS  PubMed  Google Scholar 

  27. Jiang J, Zhang X, Sun PB, Zhang LZ (2011) ZnO/BiOI heterostructures: photoinduced charge-transfer property and enhanced visible-light photocatalytic activity. J Phys Chem C 115:20555–20564

    Article  CAS  Google Scholar 

  28. Xiang QJ, Yu JG, Jaroniec M (2011) Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites. J Phys Chem C 115:7355–7363

    Article  CAS  Google Scholar 

  29. Borgohain C, Senapati KK, Sarma KC, Phukan P (2012) A facile synthesis of nanocrystalline CoFe2O4 embedded one-dimensional ZnO hetero-structure and its use in photocatalysis. J Mol Catal A 363-364:495–500

  30. Chen H, Chen S, Quan X, Yu HT, Zhao HM, Zhang YB (2008) Fabrication of TiO2-Pt coaxial nanotube array Schottky structures for enhanced photocatalytic degradation of phenol in aqueous solution. J Phys Chem C 112:9285–9290

  31. Li G, Wu L, Li F, Xu P, Zhang D, Li H (2013) Photoelectrocatalytic degradation of organic pollutants via a CdS quantum dots enhanced TiO2 nanotube array electrode under visible light irradiation. Nano 5:2118–2125

    CAS  Google Scholar 

  32. Wu YM, Zhang JL, Xiao L, Chen F (2009) Preparation and characterization of TiO2 photocatalysts by Fe3+ doping together with Au deposition for the degradation of organic pollutants. Appl Catal B 88:525–532

  33. Xie H, Li YZ, Jin SF, Han JJ, Zhao XJ (2010) Facile fabrication of 3D-ordered macroporous nanocrystalline iron oxide films with highly efficient visible light induced photocatalytic activity. J Phys Chem C 114:9706–9712

    Article  CAS  Google Scholar 

  34. Matsumoto YJ (1996) Energy positions of oxide semiconductors and photocatalysis with iron complex oxides. J Solid State Chem 126:227–234

    Article  CAS  Google Scholar 

  35. Chen D, Li T, Chen Q, Gao J, Fan B, Li J, Li X, Zhang R, Sun J, Gao L (2012) Hierarchically plasmonic photocatalysts of Ag/AgCl nanocrystals coupled with single-crystalline WO3 nanoplates. Nano 4:5431–5439

    CAS  Google Scholar 

  36. Fukahori SJ, Fujiwara T (2014) Modeling of sulfonamide antibiotic removal by TiO2/ high-silica zeolite HSZ-385 composite. J Hazard Mater 272:1–9

    Article  CAS  PubMed  Google Scholar 

  37. Naghizadeh-Alamdari S, Habibi-Yangje HA (2015) One-pot ultrasonic-assisted method for preparation of Ag/AgCl sensitized ZnO nanostructures as visible-light-driven photocatalysts. Solid State Sci 40:111–120

  38. Yao XX, Liu XH, Zhu D (2015) Synthesis of cube-like Ag/AgCl plasmonic photocatalyst with enhanced visible light photocatalytic activity. Catal Commun 59:151–155

  39. McEvoy JG, Zhang ZS (2014) Synthesis and characterization of magnetically separable Ag/AgCl–magnetic activated carbon composites for visible light induced photocatalytic detoxification and disinfection. Appl Catal B 160-161:267–278

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Acknowledgements

This work was financially supported by the Natural Science Foundation of Shaanxi (2015JM5213) and the Postgraduate Innovation Fund of Shaanxi University of Science and Technology.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, People’s Republic of China

    Junqi Li, Liu Guo, Jian Zhou, Qianqian Song & Zheng Liang

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  1. Junqi Li
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  2. Liu Guo
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  3. Jian Zhou
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  4. Qianqian Song
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  5. Zheng Liang
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Correspondence to Junqi Li.

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Li, J., Guo, L., Zhou, J. et al. Enhancing the photoelectrochemical performance of BiVO4 by decorating only its (040) facet with self-assembled Ag@AgCl QDs. J Solid State Electrochem 22, 2425–2434 (2018). https://doi.org/10.1007/s10008-018-3945-8

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  • DOI: https://doi.org/10.1007/s10008-018-3945-8

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