Journal of Solid State Electrochemistry

, Volume 22, Issue 5, pp 1315–1319 | Cite as

Synthesis of Na2Ti3O7 nanoparticles by sonochemical method for solid state electrolyte applications

  • Y. Leyet
  • F. Guerrero
  • J. Anglada-Rivera
  • R. F. B. de Souza
  • W. R. Brito
  • L. Aguilera
  • L. A. Pocrifka
  • R. Peña-Garcia
  • E. Padrón-Hernández
  • J. de la Cruz Pérez
Original Paper


Na2Ti3O7 ceramic materials have been widely used in sodium-ion battery applications with relative good results; however, there are still several studies that might be carried out in the improvement of the Na2Ti3O7 properties and the overall batteries’ performance. In this direction, we used sonochemical method following a thermal treatment in order to synthetized pure phase Na2Ti3O7 nanopowders. X-ray diffraction characterization revealed that Na2Ti3O7 is the primary phase in nanopowders and ceramic sample; although, a high level of amorphization was observed in the sonicated nanopowder without heat treatment process. Nanopowder-prepared ceramic sample showed a crystallite size of 50 nm after sintering at 900 °C for 1 h. The specific surface area, pore volume, and pore size were obtained from the B.E.T. measurements, being 51 m2 g−1, 0.07 cm3 g−1, and 55 Å, respectively. The capacitance values of the nanopowder-prepared ceramic sample were in the order of microfarad. The total energy of the system was used to determine relaxation time of the sample (τ 0 = 31 ms).


Na2Ti3O7 Sonochemical method Electrical response Solid state electrolyte 



This work has been supported by the Brazilian Agencies CNPq, FINEP, FACEPE, FAPEAM, MCTI and CAPES (99999.008454/2014-00).


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Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  • Y. Leyet
    • 1
    • 2
  • F. Guerrero
    • 2
  • J. Anglada-Rivera
    • 3
  • R. F. B. de Souza
    • 4
  • W. R. Brito
    • 4
  • L. Aguilera
    • 4
  • L. A. Pocrifka
    • 4
  • R. Peña-Garcia
    • 5
  • E. Padrón-Hernández
    • 5
    • 6
  • J. de la Cruz Pérez
    • 7
  1. 1.Departamento de Engenharia de MateriaisUniversidade Federal do AmazonasManausBrazil
  2. 2.Departamento de FísicaUniversidade Federal do AmazonasManausBrazil
  3. 3.Instituto Federal de Educação Ciência e Tecnologia do AmazonasManausBrazil
  4. 4.Departamento de QuímicaUniversidade Federal do AmazonasManausBrazil
  5. 5.Departamento de FísicaUniversidade Federal de PernambucoRecifeBrazil
  6. 6.Programa de Pós Graduação em Ciência de MateriaisUniversidade Federal De PernambucoRecifeBrazil
  7. 7.ISQ- Instituto de Soldadura e QualidadePorto SalvoPortugal

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