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Estimation of the composition of electrolytically prepared intermetallic bismuth–platinum deposits

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Abstract

The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi–Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi–Pt deposit when three intermetallic compounds such as: Pt2Bi3, PtBi2, PtBi, and phase of pure Bi exist simultaneously on the electrode.

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Authors and Affiliations

  1. Tomsk Polytechnic University, 30 Lenina av., Tomsk, 634050, Russia

    Natalya Shekhovtsova, Tatyana Glyzina, Sergey Romanenko & Nina Kolpakova

Authors
  1. Natalya Shekhovtsova
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  2. Tatyana Glyzina
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  3. Sergey Romanenko
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  4. Nina Kolpakova
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Corresponding author

Correspondence to Natalya Shekhovtsova.

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Shekhovtsova, N., Glyzina, T., Romanenko, S. et al. Estimation of the composition of electrolytically prepared intermetallic bismuth–platinum deposits. J Solid State Electrochem 16, 2419–2423 (2012). https://doi.org/10.1007/s10008-012-1730-7

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  • DOI: https://doi.org/10.1007/s10008-012-1730-7

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