Skip to main content
SpringerLink
Log in

Diffusive problem of Stephan and its solution for processes of electrodissolution of semispherical nuclei of the deposit

  • Review
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

We modeled the processes of growth and dissolution of small amounts of deposit on the solid electrode. Quasi-stationary diffusion method solved the basic problem of growth and dissolution of the semi-spherical nuclei deposit. Equations are obtained for current–voltage curves and chronoamperogram for reversible and irreversible electrode processes of electrodissolution of deposit nuclei. We have derived relations for the peak current and peak potentials of the current–voltage curve.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Brainina KhZ, Zaharchuk NF, Sokolov Z.A. (1974) Factory laboratory, 40:252-255

  2. Grygar T, Marken F, Schroder U, Scholz F (2002) Collect Czech Chem Commun 67:163–208

    Article  CAS  Google Scholar 

  3. Brainina KhZ (1974) Stripping voltammetry in chemical analysis. Wiley, New York

    Google Scholar 

  4. Brainina KhZ, Neumann E (1982) Solid state reactions in electroanalytical chemistry. Chemistry, Moscow (in Russian). 264 p

    Google Scholar 

  5. Jones S, Chevallier F, Paddon C, Compton RG (2007) Anal Chem 79:4110–4119

    Article  Google Scholar 

  6. Menshykau D, Compton R (2009) J Phys Chem C 113:15602–15620

    Article  CAS  Google Scholar 

  7. Zaharov M, Guntsov A, Chemezova X (2001) Electrochemical stripping methods for anions. TyumGNGU, Tyumen

    Google Scholar 

  8. Modern crystallography, v.3. Formation of crystals. Under B.K. Weinstein’s general edition, etc. M: the Science, 1980. 407p

  9. Parker R (1970) Crystals growth mechanisms: energetics, kinetics and transport. In: Seitz F (ed) Solid state physics: advances in research and applications, vol. 25. Academic, London, pp 152–301

    Google Scholar 

  10. Guntsov A (2001) Foundations of the theory of stripping voltammetry. Electrodissolution of nucleus deposit. TyumGNGU, Tyumen (in Russian). 122 p

  11. Milchev A (2002) Electrocrystallization. Fundamentals of nucleation and growth. Kluwer Academic, New York

    Google Scholar 

  12. Budevski E, Staikov G, Lorenz W (1996) Electrochemical phase formation—an introduction to the initial stages of metal deposition. VCH, Weiheim

    Google Scholar 

  13. Gamburg Y, Zangari G (2011) Theory and practice of metal electrodeposition. Springer, New York

    Book  Google Scholar 

  14. Isaev V (2007) Electrochemical phase formation. Ekaterinburg (in Russian). 123 p

  15. Fletcher S (1982) J Chem Soc Faraday Trans 79:467–479

    Google Scholar 

  16. Fletcher S (1983) J Cryst Growth 62:505–512

    Article  CAS  Google Scholar 

  17. Guntsov AV (1982) Electrochemistry 18:521–522

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tyumen State Oil and Gas University, 38, Volodarskogo St., Tyumen, Russia, 625000

    A. V. Guntsov

Authors
  1. A. V. Guntsov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Guntsov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guntsov, A.V. Diffusive problem of Stephan and its solution for processes of electrodissolution of semispherical nuclei of the deposit. J Solid State Electrochem 16, 2309–2314 (2012). https://doi.org/10.1007/s10008-012-1706-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-012-1706-7

Keywords

Search

Navigation