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Asymmetric hydrogenation of dehydrodipeptides bearing different protecting groups

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Summary.

 N-[(Z)-N-Benzoyl- or N-boc-(2-fluorophenyl)dehydroalanyl]-(R)- or (S)-phenyl-alanines 1,2,5 and 6 were hydrogenated in the presence of chiral and achiral rhodium complexes. The optical induction is compared to the results obtained using the corresponding esters as substrates.

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Authors and Affiliations

  1. Institut für Organische Katalyseforschung an der Universität Rostock e.V., Rostock, Germany, , , , , , DE

    Chr. Döbler, H.-J. Kreuzfeld, Chr. Fischer & M. Michalik

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  1. Chr. Döbler
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  2. H.-J. Kreuzfeld
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  3. Chr. Fischer
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  4. M. Michalik
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Received November 11, 2001 Accepted January 15, 2002

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Döbler, C., Kreuzfeld, HJ., Fischer, C. et al. Asymmetric hydrogenation of dehydrodipeptides bearing different protecting groups. Amino Acids 22, 325–331 (2002). https://doi.org/10.1007/s007260200018

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  • DOI: https://doi.org/10.1007/s007260200018

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