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Development of Pressure Calibration Method in High-Pressure THz ESR System

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Abstract

We have developed a pressure calibration method in the high-pressure THz ESR system using induction coils set outside the pressure cell. The pressure is calibrated using alternating current (AC) magnetization measurements of the superconducting transition temperature of tin set inside the pressure cell with an ESR sample. The system fits the developed pressure cell with a wide frequency range of 0.05–0.8 THz. The pressure range was extended to 2.8 GPa. The ESR system was applied to the well-known cobalt Tutton’s salt \(({\text {NH}}_{4})_{2} {\rm {Co}}({\text {SO}}_{4})_{2}\cdot {\rm {6H}}_{2} {\text {O}}\), and its g principal values at 0 GPa were determined as \(g_{1}=6.61\), \(g_{2}=3.05\), and \(g_{3}=2.94\) for the first time. Furthermore, we succeeded in observing the large change in these g values with pressure.

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Acknowledgements

This work was supported by KAKENHI from Japan Society for the Promotion of Science: Grant Numbers 19K03746 (T.S.), and 19K21852 (H.O.). One of the authors (T.S.) would like to thank Dr. Dmytro Kamenskyi for translating the Russian paper.

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Authors and Affiliations

  1. Research Facility Center for Science and Technology, Kobe University, Kobe, 657-8501, Japan

    Takahiro Sakurai

  2. Faculty of Science, Kobe University, Kobe, 657-8501, Japan

    Yoshimasa Yasutani & Hitoshi Sugawara

  3. Molecular Photoscience Research Center, Kobe University, Kobe, 657-8051, Japan

    Susumu Okubo & Hitoshi Ohta

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  1. Takahiro Sakurai
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  2. Yoshimasa Yasutani
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  3. Hitoshi Sugawara
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  4. Susumu Okubo
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  5. Hitoshi Ohta
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Correspondence to Takahiro Sakurai.

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Sakurai, T., Yasutani, Y., Sugawara, H. et al. Development of Pressure Calibration Method in High-Pressure THz ESR System. Appl Magn Reson 53, 763–775 (2022). https://doi.org/10.1007/s00723-021-01395-2

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