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The Direct Dimension in Pulse EPR

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Abstract

The direct dimension or time following directly after a pulse sequence in pulse EPR is rarely utilized. Many of the reasons for this stem from limitations in the technology available at the time pulse EPR was developed. The underutilization of the direct dimension can limit sensitivity, information content, and accurate analysis of data. Some features of the direct dimension are illustrated using two-pulse ESEEM spectroscopy.

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Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation (grant 14.W03.31.0034).

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  1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    Michael K. Bowman & Alexander G. Maryasov

  2. Department of Chemistry & Biochemistry, The University of Alabama, Tuscaloosa, AL, 35487, USA

    Michael K. Bowman

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Bowman, M.K., Maryasov, A.G. The Direct Dimension in Pulse EPR. Appl Magn Reson 52, 1041–1062 (2021). https://doi.org/10.1007/s00723-021-01362-x

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