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Hyperfine Structure in the OD ESR Spectra of Recombining Charge Pairs in Doped Polyethylene Matrices

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Abstract

The hyperfine structure has been resolved in the optically detected electron spin resonance (OD ESR) spectra of radical ion pairs generated by ionizing radiation at a low dopant concentration in a solid polyethylene matrix at room temperature. The different organic molecules that can capture electrons and holes were used as the dopants. The spin-lattice relaxation times T1 for radical ions of dopants were estimated to be tens of microseconds. The temperature dependence of OD ESR signal intensity indicates the diffusion-assisted mechanism of recombination of radical ion pairs in polyethylene.

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Acknowledgements

This work was supported by the Russian Science Foundation (project no. 16-13-10163).

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Authors and Affiliations

  1. Voevodsky Institute of Chemical Kinetics and Combustion, Novosibirsk, Russia

    V. N. Verkhovlyuk, V. I. Borovkov, V. A. Bagryansky, S. B. Zikirin, O. A. Anisimov & Yu. N. Molin

  2. Novosibirsk State University, Novosibirsk, Russia

    V. I. Borovkov & S. B. Zikirin

  3. Novosibirsk Institute of Organic Chemistry, Novosibirsk, Russia

    A. I. Taratayko

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  1. V. N. Verkhovlyuk
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  2. V. I. Borovkov
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  3. V. A. Bagryansky
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  4. S. B. Zikirin
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  5. A. I. Taratayko
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  6. O. A. Anisimov
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Correspondence to V. N. Verkhovlyuk.

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Verkhovlyuk, V.N., Borovkov, V.I., Bagryansky, V.A. et al. Hyperfine Structure in the OD ESR Spectra of Recombining Charge Pairs in Doped Polyethylene Matrices. Appl Magn Reson 49, 345–355 (2018). https://doi.org/10.1007/s00723-018-0978-1

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  • DOI: https://doi.org/10.1007/s00723-018-0978-1

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