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Applied Magnetic Resonance

, Volume 49, Issue 4, pp 357–367 | Cite as

Translational Mobility of Components and Structure of Water–Ethanol Solutions

  • V. A. Sevryugin
  • N. M. Azancheev
  • G. N. Kosova
Original Paper
  • 98 Downloads

Abstract

The concentration dependences of self-diffusion coefficients of water and ethanol molecules in water–ethanol solutions are obtained by the method of nuclear magnetic resonance spectroscopy with the pulse magnetic field gradient. On the basis of the ideas of hydration of ethanol molecules, the obtained dependences are interpreted and assumptions are made about the structural organization of water–ethanol solutions in the region of diluted and concentrated solutions.

References

  1. 1.
    F. Franks, D.J.G. Ives, Quart. Rev. Chem. Soc. 20, 1–44 (1966)CrossRefGoogle Scholar
  2. 2.
    T. Sato, A. Chiba, R. Nozaki, J. Mol. Liquid 96–97, 327–339 (2002)CrossRefGoogle Scholar
  3. 3.
    R. Li, C. D’Agostino, J. McGregor, M.D. Mantle, J.A. Zeitler, L.F. Gladden, J. Phys. Chem. B 118, 10156–10166 (2014)CrossRefGoogle Scholar
  4. 4.
    A. Coccia, P.L. Indovina, F. Podo, V. Viti, Chem. Phys. 7, 30–40 (1975)ADSCrossRefGoogle Scholar
  5. 5.
    N. Hu, D. Wu, K.J. Cross, D.W. Schaefer, Appl. Spectrosc. 64, 337–342 (2010)ADSCrossRefGoogle Scholar
  6. 6.
    K. Yoshida, A. Kitajo, T. Yamaguchi, J. Mol. Liquids 125, 158–163 (2006)CrossRefGoogle Scholar
  7. 7.
    E.O. Stejskal, J.E. Tanner, J. Chem. Phys. 42(1), 288–292 (1965)ADSCrossRefGoogle Scholar
  8. 8.
    V.A. Sevriugin, V.D. Skirda, Zh Fiz, Khim. 73(5), 853–856 (1999)Google Scholar
  9. 9.
    V.A. Sevriugin, IYu. Aslanyan, V.D. Skirda, Zh Fiz, Khim. 74(12), 2167–2172 (2000)Google Scholar
  10. 10.
    V.A. Sevriugin, V.V. Loskutov, N.E. Zhuravlyova, Appl. Magn. Reson. 29, 523–530 (2005)CrossRefGoogle Scholar
  11. 11.
    J. Teixeira, M.-C. Bellissent-Funel, S.H. Chen, A.J. Dianoux, Phys. Rev. A 31(3), 1913 (1985)ADSCrossRefGoogle Scholar
  12. 12.
    Y. Ishihara, S. Okouchi, H. Uedaira, J. Chem. Soc., Faraday Trans. 93, 3337 (1997)CrossRefGoogle Scholar
  13. 13.
    H. Ohtaki, T. Radnai, Chem. Rev. 93, 1157 (1993)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2018

Authors and Affiliations

  • V. A. Sevryugin
    • 1
  • N. M. Azancheev
    • 1
  • G. N. Kosova
    • 2
  1. 1.Kazan Federal UniversityKazanRussia
  2. 2.Volga-Region Technological UniversityYoshkar-OlaRussia

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