Skip to main content
Log in

Superhydrophobic polymer composite coating on glass via spin coating technique

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

In this work, a superhydrophobic coating on glass surface has been prepared by using polymethylmethacrylate, SiO2 nanoparticles, and hexadecyltrimethoxysilane via spin coating technique. Coating was characterized by using contact angle measurement technique, scanning electron microscopy, and Fourier-transform infrared spectroscopy. Coating shows the superhydrophobic nature with water contact angle of 165 ± 5° and tilt angle of 7 ± 1°. Thermal, chemical, and mechanical stability of coating was also examined, and it is found excellent wetting stability of coating under harsh conditions. Droplet dynamics behavior of water droplets on coating was also studied and bouncing, pinning, and splashing of water droplets are observed at different impact velocities. Coating also exhibits the excellent self-cleaning nature. Prepared coating shows its several industrial applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Guo Z, Liu W (2007) Biomimic from the superhydrophobic plant leaves in nature: binary structure and unitary structure. Plant Sci 172:1103–1112

    Article  CAS  Google Scholar 

  2. Bhushan B (2018) Biomimetic: bioinspired hierarchical-structured surfaces for green science and technologythird edn. Springer International, Cham

    Book  Google Scholar 

  3. Lai Y, Tang Y, Gong J, Gong D, Chi L, Lin C, Chen Z (2012) Transparent superhydrophobic/ super hydrophilic TiO2-based coatings for self-cleaning and anti-fogging. J Mater Chem 22:7420–7426

    Article  CAS  Google Scholar 

  4. Huang K, Yeh S, Huang C (2015) Surface modification for superhydrophilicity and underwater superoleophobicity: applications in antifog, underwater self- cleaning, and oil-water separation. ACS Appl Mater Interfaces 7:21021–21029

    Article  CAS  Google Scholar 

  5. Mishchenko L, Hatton B, Bahadur V, Taylor JA, Krupenkin T, Aizenberg J (2010) Design of ice-free nanostructured surfaces based on repulsion of impacting water droplets. ACS Nano 4:7699–7707

    Article  CAS  Google Scholar 

  6. Cao L, Jones AK, Sikka VK, Wu J, Gao D (2009) Anti-icing superhydrophobic coatings. Langmuir 25:12444–12448

    Article  CAS  Google Scholar 

  7. Rao AV, Latthe SS, Mahadik SA, Kappenstein C (2011) Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate. Appl Surf Sci 257:5772–5776

    Article  CAS  Google Scholar 

  8. Verma LK, Sakhuja M, Son J, Danner AJ, Yang H, Zheng HC, Bhatia CS (2011) Self-cleaning and antireflective packaging glass for solar modules. Renew Energy 36:2489–2493

    Article  CAS  Google Scholar 

  9. Qiu W, Xu D, Liu B, Shen L, Guo Q (2015) Fabrication of superhydrophobic surfaces by smoke deposition and application in oil −water separation. RSC Adv 5:71329–71335

    Article  CAS  Google Scholar 

  10. Mahadik SA, Parale V, Vhatkara RS, Mahadik DB, Kavale MS, Wagh PB, Gupta S, Gurav J (2013) Superhydrophobic silica coating by dip coating method. Appl Surf Sci 277:67–72

    Article  CAS  Google Scholar 

  11. Wang S, Li M, Lu Q (2010) Filter paper with selective absorption and separation of liquids that differ in surface tension. ACS Appl Mater Interfaces 2:677–683

    Article  CAS  Google Scholar 

  12. Wang J, Chen X, Kang Y, Yang G, Yu L, Zhang P (2010) Preparation of superhydrophobic poly (methyl methacrylate)-silicon dioxide nanocomposite films. Appl Surf Sci 257:1473–1477

    Article  CAS  Google Scholar 

  13. Manoudis PN, Karapanagiotis I, Tsakalof A, Zuburtikudis I, Panayiotou C (2008) Superhydrophobic composite films produced on various substrates. Langmuir 24:11225–11232

    Article  CAS  Google Scholar 

  14. Kumar AM, Latthe SS, Sudhagar P, Obot IB, Gasem ZM (2015) In-situ synthesis of hydrophobic SiO2-PMMA composite for surface protective coatings: experimental and quantum chemical analysis. J Polymer 77:79–86

    Article  Google Scholar 

  15. Kinoshita H, Ogasahara A, Fukuda Y, Ohmae N (2010) Superhydrophobic/superhydrophilic micropatterning on a carbon nanotube film using a laser plasma-type hyper thermal atom beam facility. Carbon 48:4403–4408

    Article  CAS  Google Scholar 

  16. Hwang HS, Lee SB, Park I (2010) Fabrication of raspberry-like superhydrophobic hollow silica particles. Mater Lett 64:2159–2162

    Article  CAS  Google Scholar 

  17. Ma M, Mao Y, Gupta M, Gleason KK, Rutledge GC (2005) Superhydrophobic fabrics produced by electrospinning and chemical vapor deposition. Macromolecules 38:9742–9748

    Article  CAS  Google Scholar 

  18. Zhang X, Zhao J, Mo J, Suna R, Li Z, Guo Z (2019) Fabrication of superhydrophobic aluminum surface by droplet etching and chemical modification. J Colloids Surf A567:205–212

    Article  Google Scholar 

  19. Shi Y, yang W, Feng X, Wang Y, Yue G (2015) Fabrication of superhydrophobic ZnO nano rod surface with corrosion resistance via combining thermal oxidation and surface modification. J Mater Lett 151:24–27

    Article  CAS  Google Scholar 

  20. Gurav AB, Xu Q, Latthe SS, Vhatkar RS, Liu S, Yoon H, Yoon SS (2015) Superhydrophobic coatings prepared from methyl-modified silica particles using simple dip-coating method. Ceram Int 41:3017–3023

    Article  CAS  Google Scholar 

  21. Gao Q, Zhu Q, Guo Y (2009) Formation of highly hydrophobic surfaces on cotton and polyester fabrics using silica sol nanoparticles and non fluorinatedalkylsilane. Ind Eng Chem Res 48:9797–9803

    Article  CAS  Google Scholar 

  22. Forooshani HM, Aliofkhazraei M, Rouhaghdam AS (2017) Superhydrophobic aluminum surfaces by mechanical/chemical combined method and its corrosion behavior. J Taiwan Inst Chem Eng 72:220–235

    Article  CAS  Google Scholar 

  23. Latthe SS, Demirel AL (2013) Polystyrene/octadecyltrichlorosilane superhydrophobic coatings with hierarchical morphology. Polym Chem 4:246–249

    Article  CAS  Google Scholar 

  24. Costa ROR, Freitas RFS (2002) Phase behavior of poly (N-isopropylacrylamide) in binary aqueous solutions. Polymer 43:5879–5885

    Article  CAS  Google Scholar 

  25. Ebert D, Bhushan B (2012) Transparent, superhydrophobic, and wear-resistant coatings on glass and polymer substrates using SiO2, ZnO, and ITO nanoparticles. Langmuir 28:11391–11399

    Article  CAS  Google Scholar 

  26. Ge M, Cao C, Huang J, Zhang X, Tang Y, Zhou X, Zhang K, Chen Z, Lai Y (2018) Rational design of materials interface at nanoscale towards intelligent oil–water separation. Nanoscale Horiz 3:235–260

    Article  CAS  Google Scholar 

  27. Yilgor E, Soz CK, Yilgör I (2018) Wetting behavior of superhydrophobic poly(methyl methacrylate). Prog Org Coat 125:530–536

    Article  CAS  Google Scholar 

  28. Guo D, Chen J, Hou K, Xu S, Cheng J, Wen X, Wang S, Huangb C, Pia P (2018) A facile preparation of superhydrophobic hallo site-based meshes for efficient oil–water separation. J Appl Clay Sci 156:195–201

    Article  CAS  Google Scholar 

  29. Nanda D, Varshney P, Satapathy M, Mohapatra SS, Bhushan B, Kumar A (2017) Single-step method to fabricate durable superliquiphobic coating on aluminum surface with self-cleaning and anti-fogging properties. J Colloid Interface Sci 507:397–409

    Article  CAS  Google Scholar 

  30. Zhang J, CAI J, Li M (2016) Grafting of PMMA brushes layer on Cu surface to create a stable superhydrophobic surface. J Appl Surf Sci 386:309–318

    Article  CAS  Google Scholar 

  31. Cassie ABD, Baxter S (1944) Wettability of porous surfaces. Trans Faraday Soc 40:546–551

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Aditya Kumar.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Meena, M.K., Sinhamahapatra, A. & Kumar, A. Superhydrophobic polymer composite coating on glass via spin coating technique. Colloid Polym Sci 297, 1499–1505 (2019). https://doi.org/10.1007/s00396-019-04560-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-019-04560-z

Keywords

Navigation