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Magnetic properties of the new quaternary Heusler compound NbRhCrAl

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Abstract

In this examination, we utilize the Monte Carlo simulations (MCS), under the Metropolis calculation, to explore the magnetic properties of the quaternary Heusler compound NbRhCrAl. This alloy has not been integrated till now. This material contains three magnetic atoms: Nb, Rh and Cr, displayed by the spin moments S = 1, σ = 5/2 and Q = 3/2, respectively. For non-null temperature values, the behavior of the total and partial magnetizations is presented as a function temperature, exchange coupling interactions, crystal field and the external magnetic field. In fact, we have studied the behavior of the total and partial magnetizations, the susceptibilities, the specific heat and the total energy as a function of temperature. Also, we provide the behavior of the total magnetizations as a function of the crystal field and the exchange coupling interactions. Finally, we illustrate and discuss the hysteresis loops as a function of the external magnetic field for fixed values of the studied physical parameters.

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References

  1. C. Felser, G.H. Fecher, B. Balke, Spintronics: a challenge for materials science and solid-state chemistry. Angew. Chem. Int. Ed. 46, 668 (2007)

    Article  Google Scholar 

  2. S. Idrissi, R. Khalladi, S. Ziti, N. El Mekkaoui, S. Mtougui, H. Labrim, I. El Housni, L. Bahmad, The electronic and magnetic proprieties of the rare earth-based quaternary Heusler compound LuCoVGe. Physica B 562, 116–123 (2019). https://doi.org/10.1016/j.physb.2019.03.018

    Article  ADS  Google Scholar 

  3. K. Inomata, N. Ikeda, N. Tezuka, R. Goto, S. Sugimoto, M. Wojcik, E. Jedryka, Highly spin polarized materials and devices for spintronics. Sci. Technol. Adv. Mater. 9, 014101 (2008)

    Article  Google Scholar 

  4. R.A. de Groot, F.M. Mueller, P.G. van Engen, K.H.J. Buschow, New Class of materials: half-metallic ferromagnets. Phys. Rev. Lett. 50, 2024–2027 (1983)

    Article  ADS  Google Scholar 

  5. S.A. Wolf, D.D. Awschalom, R.A. Buhrman, J.M. Daughton, S. vonMolnár, M.L. Roukes, A.Y. Chtchelkanova, D.M. Treger, Spintronics: a spin-based electronics vision for the future. Science 294, 1488–1495 (2001)

    Article  ADS  Google Scholar 

  6. Z. Szotek, W.M. Temmerman, A. Svane, L. Petit, G.M. Stocks, H. Winter, Half- metallic transition metal oxides. J. Magn. Magn. Mater. 272–276, 1816–1817 (2004)

    Article  ADS  Google Scholar 

  7. W.Y. Song, J. Wang, Z.J. Wu, Half metallic properties of Sr2CuOsO6. Chem. Phys. Lett. 482, 246–248 (2009)

    Article  ADS  Google Scholar 

  8. S.H. Lv, H.P. Li, D.M. Han, Z.J. Wu, X.J. Liu, J. Meng, A better ferrimagnetic half-metal LuCu3Mn4O12: predicted from first-principles investigation. J. Magn. Magn. Mater. 323, 416–421 (2011)

    Article  ADS  Google Scholar 

  9. X.T. Wang, Y.T. Cui, X.F. Liu, G.D. Liu, Electronic structures and magnetism in the Li2AgSb-type Heusler alloys, Zr2CoZ (Z = Al, Ga, In, Si, Ge, Sn, Pb, Sb): a first- principles study. J. Magn. Magn. Mater. 394, 50–59 (2015)

    Article  ADS  Google Scholar 

  10. X.T. Wang, Z.X. Cheng, J.L. Wang, H. Rozale, L.Y. Wang, Z.Y. Yu, J.T. Yang, G.D. Liu, Strain-induced diverse transitions in physical nature in the newly designed inverse Heusler alloy Zr2MnAl. J. Alloys. Compd. 686, 549–555 (2016)

    Article  Google Scholar 

  11. X.T. Wang, Z.X. Cheng, J.L. Wang, G.D. Liu, A full spectrum of spintronic properties demonstrated by a C1b-type Heusler compound Mn2Sn subjected to strain engineering. J. Mater. Chem. C 4, 8535–8544 (2016)

    Article  Google Scholar 

  12. G.D. Liu, X.F. Dai, H.Y. Liu, J.L. Chen, Y.X. Li, G. Xiao, G.H. Wu, Mn2CoZ (Z = Al, Ga, In, Si, Ge, Sn, Sb) compounds: Structural, electronic, and magnetic properties. Phys. Rev. B 77, 014424 (2008)

    Article  ADS  Google Scholar 

  13. L. Zhang, X.T. Wang, H. Rozale, Y.C. Gao, L.Y. Wang, X.B. Chen, Electronic structures, magnetic properties and half-metallicity in Heusler alloys Zr2IrZ (Z = Al, Ga, In). Curr. Appl. Phys. 15, 1117–1123 (2015)

    Article  ADS  Google Scholar 

  14. G.D. Liu, X.F. Dai, S.Y. Yu, Z.Y. Zhu, J.L. Chen, G.H. Wu, H. Zhu, J.Q. Xiao, Physical and electronic structure and magnetism of Mn2NiGa: experiment and density-functional theory calculations. Phys Rev B 74, 054435 (2006)

    Article  ADS  Google Scholar 

  15. X.T. Wang, X.F. Dai, L.Y. Wang, X.F. Liu, W.H. Wang, G.H. Wu, C.C. Tang, G.D. Liu, Electronic structures and magnetism of Rh3Z (Z = Al, Ga, In, Si, Ge, Sn, Pb, Sb) with DO3 structures. J. Magn. Magn. Mater. 378, 16–23 (2015)

    Article  ADS  Google Scholar 

  16. X.T. Wang, Z.X. Cheng, J.L. Wang, L.Y. Wang, Z.Y. Yu, C.S. Fang, J.T. Yang, G.D. Liu, Origin of the half-metallic band-gap in newly designed quaternary Heusler compounds ZrVTiZ (Z = Al, Ga). RSC Adv 6, 57041 (2016)

    Article  Google Scholar 

  17. Y.J. Zhang, Y.J. Liux, G.D. Liu, Magnetic properties and half-metallicity of the CoFeTiZ (Z = Si, Ge, Sn) quaternary Heusler compound, Science paper Online (2013)

  18. Y.J. Zhang, Z.H. Liu, G.T. Li, X.Q. Ma, G.D. Liu, Magnetism, band gap and stability of half-metallic property for the quaternary Heusler alloys CoFeTiZ (Z = Si, Ge, Sn). J Alloys Compd 616, 449–453 (2014)

    Article  Google Scholar 

  19. L. Xiong, L. Yi, G.Y. Gao, Search for half-metallic magnets with large half-metallic gaps in the quaternary Heusler alloys CoFeTiZ and CoFeVZ (Z = Al, Ga, Si, Ge, As, Sb). J. Magn. Magn. Mater. 360, 98–103 (2014)

    Article  ADS  Google Scholar 

  20. G.Y. Gao, L. Hu, K.L. Yao, B. Luo, N. Liu, Large half-metallic gaps in the quaternary Heusler alloys CoFeCrZ (Z = Al, Si, Ga, Ge): a first-principles study. J. Alloys Compd. 551, 539–543 (2013)

    Article  Google Scholar 

  21. G. Gökog˘lu, Abinitio electronic structure of NiCoCrGa half-metallic quaternary Heusler compound. Solid State Sci. 14, 1273–1276 (2012)

    Article  ADS  Google Scholar 

  22. Q. Gao, L. Li, G. Lei, J.B. Deng, X.P. Hu, A first-principle study on the properties of a new series of quaternary Heusler alloys CoFeScZ (Z = P, As, Sb). J. Magn. Magn. Mater. 379, 288–293 (2015)

    Article  ADS  Google Scholar 

  23. M. Khodami, F. Ahmadian, First-principles study of magnetism and half- metallic properties for the quaternary Heusler alloys CoMnTiZ (Z = P, As, and Sb). J. Supercond. Nov. Magn. 28, 3027–3035 (2015)

    Article  Google Scholar 

  24. N. Karimian, F. Ahmadian, Electronic structure and half-metallicity of new quaternary Heusler alloys NiFeTiZ (Z = Si, P, Ge, and As). Solid State Commun. 223, 60–66 (2015)

    Article  ADS  Google Scholar 

  25. M. Singh, H.S. Saini, J. Thakur, A.H. Reshak, M.K. Kashyap, Magnetism and robust half-metallicity of new quaternary Heusler alloy FeCrMnSb. J. Alloys Compd. 580, 201–204 (2013)

    Article  Google Scholar 

  26. M.N. Rasool, A. Hussain, A. Javed, M.A. Khan, Study of the structural, electronic and magnetic properties of ScFeCrT (T = Si, Ge) Heusler alloys by first principles approach. J. Magn. Magn. Mater. 426, 421–428 (2017)

    Article  ADS  Google Scholar 

  27. J.M.K. Al-zyadi, G.Y. Gao, K.L. Yao, Theoretical investigation of the electronic structures and magnetic properties of the bulk and surface (001) of the quaternary Heusler alloy NiCoMnGa. J. Magn. Magn. Mater. 378, 1–6 (2015)

    Article  ADS  Google Scholar 

  28. S. Berri, M. Ibrir, D. Maouche, M. Attallah, First principles study of structural, electronic and magnetic properties of ZrFeTiAl, ZrFeTiSi, ZrFeTiGe and ZrNiTiAl. J. Magn. Magn. Mater. 371, 106–111 (2014)

    Article  ADS  Google Scholar 

  29. M.N. Rasool, A. Hussain, A. Javed, M.A. Khan, F. Iqbal, Structural stability, electronic and magnetic behaviour of spin-polarized YCoVZ (Z = Si, Ge) and YCoTiZ (Z = Si, Ge) Heusler alloys. Mater. Chem. Phys. 183, 524–533 (2016)

    Article  Google Scholar 

  30. R.K. Guo, G.D. Liu, X.T. Wang, H. Rozale, L.Y. Wang, R. Khenata, Z.M. Wu, X.F. Dai, First- principles study on quaternary Heusler compounds ZrFeVZ (Z = Al, Ga, In) with large spin-flip gap. RSC Adv. 6, 109394 (2016)

    Article  Google Scholar 

  31. V. Alijani, K.J. Winterli, G.H. Fecher, S.S. Naghavi, S. Chadov, T. Gruhn, C. Felser, Quaternary Heusler compounds Co2-xRhxMnZ (Z = Ga, Sn, Sb): crystal structure, electronic structure, and magnetic properties. J. Phys.: Condens. Mater. 24, 046001 (2012)

    ADS  Google Scholar 

  32. S. Berri, M. Ibrir, D. Maouche, M. Attallah, Robust half-metallic ferromagnet of quaternary Heusler compounds ZrCoTiZ (Z = Si, Ge, Ga and Al). Comput. Mater. Sci. 1, 26–31 (2014)

    Google Scholar 

  33. H.H. Xie, Q. Gao, L. Li, G. Lei, G.Y. Mao, X.R. Hu, J.B. Deng, First-principles study of four quaternary Heusler alloys ZrMnVZ and ZrCoFeZ (Z = Si, Ge). Comp. Mater. Sci. 103, 52–55 (2015)

    Article  Google Scholar 

  34. S. Berri, M. Ibrir, D. Maouche, M. Attallah, First principles study of structural, electronic and magnetic properties of ZrFeTiAl, ZrFeTiSi, ZrFeTiGe and ZrNiTiAl. J. Magn. Magn. Mater. 371, 106–111 (2014)

    Article  ADS  Google Scholar 

  35. S. Bahramian, F. Ahmadian, Half-metallicity and magnetism of quaternary Heusler compounds CoRuTiZ (Z = Si, Ge, and Sn). J. Magn. Magn. Mater. 424, 122–129 (2017)

    Article  ADS  Google Scholar 

  36. H. Labrim, A. Jabar, A. Belhaj, S. Ziti, L. Bahmad, L. Laânab, A. Benyoussef, J. Alloy. Compd. 641, 37–42 (2015)

    Article  Google Scholar 

  37. S. Idrissi, R. Khalladi, S. Mtougui, S. Ziti, H. Labrim, I. El Housni, N. El Mekkaoui, L. Bahmad, Magnetism and phase diagrams of the doubles perovskite Sr2CrIrO6: Monte Carlo simulations. Physica A (2019). https://doi.org/10.1016/j.physa.2019.03.004

    Article  Google Scholar 

  38. S. Idrissi, H. Labrim, S. Ziti, R. Khalladi, N. El Mekkaoui, I. El Housni, S. Mtougui, L. Bahmad, Magnetic properties of the double perovskite Bi2FeCrO6. Accepted Electr. Mater. J. 15, 85 (2019). https://doi.org/10.1007/s11664-019-07110-z

    Article  Google Scholar 

  39. L. Bahmad, A. Benyoussef, H. Ez-Zahraouy, Order–disorder layering transitions in a variable transverse field. J. Magn. Magn. Mater. 238(1), 115–122 (2002)

    Article  ADS  Google Scholar 

  40. L. Bahmad, A. Benyoussef, H. Ez-Zahraouy, Wetting of a corrugated surface 3D ising model. Physica A 303(3–4), 525–533 (2002)

    Article  ADS  Google Scholar 

  41. Y. Li, G.D. Liu, X.T. Wang, E.K. Liu, X.K. Xi, W.H. Wang, G.H. Wu, L.Y. Wang, X.F. Dai, First-principles study on electronic structure, magnetism and half-metallicity of the NbCoCrAl and NbRhCrAl compounds. Results Phys. 7, 2248–2254 (2017)

    Article  ADS  Google Scholar 

  42. Z. Haque, G.S. Thakur, S. Ghara, L.C. Gupta, A. Sundaresan, A.K. Ganguli, Structural and magnetic properties of a new and ordered quaternary alloy MnNiCuSb (SG: F43 m). J. Magn. Magn. Mater. 397, 315–318 (2016)

    Article  ADS  Google Scholar 

  43. Z. Jia, K. Lin, G. Wu, H. Xingand, H. Wu, Recent progresses of high-temperature microwave-absorbing materials. Nano 13(6), 1830005 (2018)

    Article  Google Scholar 

  44. Wu Hongjing, Qu Shaohua, Kejun Lin, Yuchang Qing, Liuding Wang, Yuancheng Fan, Fu Quanhong, FuliZhang, Enhanced low-frequency microwave absorbing property of SCFs@TiO2 composite. Powder Technol. 333(15), 153–159 (2018)

    Google Scholar 

  45. Di Lan, Ming Qin, Ruisheng Yang, Shuang Chen, Wu Hongjing, Yuancheng Fan, Fu Quanhong, Fuli Zhang, Facile synthesis of hierarchical chrysanthemum-like copper cobaltate-copper oxide composites for enhanced microwave absorption performance. J. Colloid Interface Sci. 533, 481–491 (2019)

    Article  ADS  Google Scholar 

  46. K. Momma, F. Izumi, VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. J. Appl. Crystallogr. 44, 1272–1276 (2011) Ibid (ISSN 0021-8898)

    Article  Google Scholar 

  47. K. Binder, D.W. Heermann, MC Simulations in Statistical Physics (Springer, Germany, 2002)

    MATH  Google Scholar 

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Idrissi, S., Bahmad, L., Ziti, S. et al. Magnetic properties of the new quaternary Heusler compound NbRhCrAl. Appl. Phys. A 125, 306 (2019). https://doi.org/10.1007/s00339-019-2580-2

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