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Magnetic and optical properties of new (1 − x) Bi0.5Na0.5TiO3 + x BaMnO3−δ solid solution materials

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Abstract

A solid solution of BaMnO3−δ and Bi0.5Na0.5TiO3 was prepared using a sol–gel method. X-ray diffraction analysis of Bi0.5Na0.5TiO3 − x BaMnO3−δ samples indicated a rhombohedral structure of Bi0.5Na0.5TiO3 materials during distortion due to the random distribution of Ba and Mn cations in the host lattice. The substitution of Ba and Mn at A- and B-sites in the perovskite structure of Bi0.5Na0.5TiO3 changed the optical band gap due to local defect and/or promotion of oxygen vacancies. The samples exhibited strong room temperature ferromagnetism, which overcame the weak ferromagnetism and diamagnetism of Bi0.5Na0.5TiO3 materials. Our study provided a flexible approach to integrate the ferromagnetism properties of ferroelectric materials.

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Acknowledgments

This work was financially supported by The Ministry of Science and Technology, Viet Nam, under project number ĐTĐLCN.29/18.

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Authors and Affiliations

  1. Department of General Physics, School of Engineering Physics, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Hanoi, Vietnam

    Dung Duc Dang & Nguyen The Hung

  2. Department of Physics, Faculty of Basic Sciences, Viet Nam Maritime University, 484 Lach Tray road, Le Chan, Haiphong, Vietnam

    Nguyen The Hung

  3. Department of Physics, Incheon National University, Incheon, 22012, Republic of Korea

    Dorj Odkhuu

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  1. Dung Duc Dang
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  2. Nguyen The Hung
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Correspondence to Dung Duc Dang.

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Dang, D.D., Hung, N.T. & Odkhuu, D. Magnetic and optical properties of new (1 − x) Bi0.5Na0.5TiO3 + x BaMnO3−δ solid solution materials. Appl. Phys. A 125, 465 (2019). https://doi.org/10.1007/s00339-019-2571-3

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