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Applied Physics A

, 124:397 | Cite as

Enhanced performance of ultracapacitors using redox additive-based electrolytes

  • Dharmendra Jain
  • Jitendra Kanungo
  • S. K. Tripathi
Article
  • 174 Downloads

Abstract

Different concentrations of potassium iodide (KI) as redox additive had been added to 1 M sulfuric acid (H2SO4) electrolyte with an aim of enhancing the capacitance and energy density of ultracapacitors via redox reactions at the interfaces of electrode–electrolyte. Ultracapacitors were fabricated using chemically treated activated carbon as electrode with H2SO4 and H2SO4–KI as an electrolyte. The electrochemical performances of fabricated supercapacitors were investigated by impedance spectroscopy, cyclic voltammetry and charge–discharge techniques. The maximum capacitance ‘C’ was observed with redox additives-based electrolyte system comprising 1 M H2SO4–0.3 M KI (1072 F g− 1), which is very much higher than conventional 1 M H2SO4 (61.3 F g− 1) aqueous electrolyte-based ultracapacitors. It corresponds to an energy density of 20.49 Wh kg− 1 at 2.1 A g− 1 for redox additive-based electrolyte, which is six times higher as compared to that of pristine electrolyte (1 M H2SO4) having energy density of only 3.36 Wh kg− 1. The temperature dependence behavior of fabricated cell was also analyzed, which shows increasing pattern in its capacitance values in a temperature range of 5–70 °C. Under cyclic stability test, redox electrolyte-based system shows almost 100% capacitance retention up to 5000 cycles and even more. For comparison, ultracapacitors based on polymer gel electrolyte polyvinyl alcohol (PVA) (10 wt%)—{H2SO4 (1 M)–KI (0.3 M)} (90 wt%) have been fabricated and characterized with the same electrode materials.

Notes

Acknowledgements

The authors are grateful to Madhya Pradesh Council of Science and Technology, Madhya Pradesh, India, for providing financial support to Dr. S.K.Tripathi through Grant-in-Aid for Scientific Research vide Sanction No. [3683/CST/R&D/Phy & Engg. Sc/2012; Bhopal, Dated: 03.11.2012]. The authors are also greatly acknowledge the Jaypee University of Engineering and Technology Guna, Madhya Pradesh, India, for providing experimental facilities and other infrastructural facilities to perform experimental work. The authors are thankful to Dr. Amrita Jain for providing her support in the execution of this work.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Dharmendra Jain
    • 1
  • Jitendra Kanungo
    • 1
  • S. K. Tripathi
    • 2
  1. 1.Department of Electronics & Communication EngineeringJaypee University of Engineering and TechnologyGunaIndia
  2. 2.Department of PhysicsMahatma Gandhi Central UniversityEast ChamparanIndia

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