Growth and characterization of barium complex of 1,3,5-triazinane-2,4,6-trione in gel: a corrosion inhibiting material
- 44 Downloads
Good quality prismatic crystals of industrially applicable corrosion inhibiting barium complex of 1,3,5-triazinane-2,4,6-trione have been grown by conventional gel method. The crystal structure, packing, and nature of bonds are revealed in the single crystal X-ray diffraction analysis. The crystal has a three-dimensional polymeric structure having a triclinic crystal system with the space group P-1. The powder X-ray diffraction analysis confirms its crystalline nature. The functional groups present in the crystal are identified by Fourier transform infrared spectroscopy. Elemental analysis confirms the stoichiometry of the elements present in the complex. Thermogravimetric analysis and differential thermal analysis reveal its good thermal stability. The optical properties like band gap, refractive index and extinction coefficient are evaluated from the UV–visible spectral analysis. The singular property of the material, corrosion inhibition efficiency achieved by the adsorption of the sample molecules is determined by the weight loss method.
The corresponding author (K. Rajendra Babu) is grateful to Kerala State Council for Science, Technology and Environment (1009/2016/KSCSTE), Govt. of Kerala for awarding the Emeritus Scientist fellowship. The authors thank STIC, Cochin University of Science and Technology for providing facilities for various analyses. We are also grateful to STIC, SAIF, IIT Madras for providing us with single crystal XRD data. The authors also thank Dr. Archana S. R., Assistant Professor, Department of Chemistry, S N College for Women, Kollam for giving suggestions regarding the corrosion inhibition study.
- 2.D. G. Ladha, P. M. Wadhwani, S. Thakur, M. Lone, P. C. Jha, N. K. Shah, Anal. Bioanal. Electrochem 7, 59 (2015)Google Scholar
- 4.S. Mistri, S. Garcia-Granda, E. Zangrando, S.C. Manna, Indian J. Chem. 53A, 135 (2014)Google Scholar
- 6.J. A. Wojtowicz, J. Swim. Pool Spa India, 4,9 (2001)Google Scholar
- 7.L. J. Christmann, B.W.G. Deichert, N.Y. Flushing, Serial no. 612955, now patent no. 2830020, filed on 1 Oct 1956Google Scholar
- 8.L. A. Bryan, W.A. Tidridge, Serial no. 129983, now patent no. 3215660, filed on 8 Aug 1961Google Scholar
- 9.L.A. Bryan, W.A. Tidridge, Serial no. 129958, now patent no. 3137583, filed on 8 Aug 1961Google Scholar
- 10.C.-Z. Chen, Z.-B. Lin, J.-Q. Shi, X.-Y. Huan, D.-S. Gao, D. Li, H.-Y. Jiang, Chin. J. Struct. Chem. 13, 468 (1994)Google Scholar
- 12.BRUKER AXS, APEX2 User Manual version 1.22, BrukerAXSInc., Madison, 2004Google Scholar
- 15.S. Surinwong, T.J. Prior, A. Rujiwatra, Chiang Mai J. Sci. 41(2), 414 (2014)Google Scholar
- 20.R. Newman, R.N. Badger, 1661 From the Gates and Crellin Laboratories of Chemistry, California Institute of technology, PasadenaGoogle Scholar