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Applied Physics A

, 124:334 | Cite as

Synthesis, crystal growth, optical, thermal, and mechanical properties of a nonlinear optical single crystal: ammonium sulfate hydrogen sulphamate (ASHS)

  • K. Sudhakar
  • S. Nandhini
  • S. Muniyappan
  • T. Arumanayagam
  • P. Vivek
  • P. Murugakoothan
Article

Abstract

Ammonium sulfate hydrogen sulphamate (ASHS), an inorganic nonlinear optical crystal, was grown from the aqueous solution by slow evaporation solution growth technique. The single-crystal XRD confirms that the grown single crystal belongs to the orthorhombic system with the space group of Pna21. Powder XRD confirms the crystalline nature and the diffraction planes were indexed. Crystalline perfection of grown crystal was analysed by high-resolution X-ray diffraction rocking curve technique. UV–Vis–NIR studies revealed that ASHS crystal has optical transparency 65% and lower cut-off wavelength at 218 nm. The violet light emission of the crystal was identified by photoluminescence studies. The particle size-dependent second-harmonic generation efficiency for ASHS crystal was evaluated by Kurtz–Perry powder technique using Nd:YAG laser which established the existence of phase matching. Surface laser damage threshold value was evaluated using Nd:YAG laser. Optical homogeneity of the crystal was evaluated using modified channel spectrum method through birefringence study. Thermal analysis reveals that ASHS crystal is stable up to 213 °C. The mechanical behaviour of the ASHS crystal was analysed using Vickers microhardness study.

References

  1. 1.
    D.S. Chemla, J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals (Academic Press, Orlando, 1987), p. 01Google Scholar
  2. 2.
    M. Packiya raj, S.M. Ravi Kumar, R. Srineevasan, R. Ravisankar, J. Taibah Univ. Sci. 11, 76 (2017)CrossRefGoogle Scholar
  3. 3.
    P. Kerkoc, J. Hulliger, J. Cryst. Growth 99, 1023 (1990)ADSCrossRefGoogle Scholar
  4. 4.
    A. Abu El-Fadl, S. Bin Anooz, Cryst. Res. Technol. 41, 487–493 (2006)CrossRefGoogle Scholar
  5. 5.
    F.A. Kanda, A.J. King, J. Am. Chem. Soc. 73, 2315 (1951)CrossRefGoogle Scholar
  6. 6.
    J. Schreuer, Ζ. Kristallogr. NCS 214, 309 (1999)Google Scholar
  7. 7.
    P. Vivek, R. RoopKumar, P. Murugakoothan, J. Cryst. Growth 412, 40 (2015)ADSCrossRefGoogle Scholar
  8. 8.
    M. Rajalakshmi, R. Indirajith, M. Palanichamy, R. Gopalakrishnan, Spectrochim. Acta A Mol. Biomol. Spectrosc. 84, 43 (2011)ADSCrossRefGoogle Scholar
  9. 9.
    S.K. Kurtz, T.T. Perry, J. Appl. Phys. 39, 3798 (1968)ADSCrossRefGoogle Scholar
  10. 10.
    J. Ramajothi, S. Dhanuskodi, J. Cryst. Growth 289, 217 (2006)ADSCrossRefGoogle Scholar
  11. 11.
    L.N. Wang, X.Q. Wang, G.H. Zhang, X.T. Liu, Z.H. Sun, G.H. Sun, L. Wang, W.T. Yu, D. Xu, J. Cryst. Growth 327, 133 (2011)ADSCrossRefGoogle Scholar
  12. 12.
    G.C. Bhar, A.K. Chaudhury, P. Kumbhakar, Appl. Surf. Sci. 161, 155 (2000)ADSCrossRefGoogle Scholar
  13. 13.
    N.L. Boling, M.D. Crisp, G. Dube, Appl. Opt. 12, 650 (1973)ADSCrossRefGoogle Scholar
  14. 14.
    P. Vijayakumar, G. AnandhaBabu, P. Ramasamy, Mat. Res. Bull. 47, 957 (2012)CrossRefGoogle Scholar
  15. 15.
    N. Vijayan, G. Bhagavannarayana, K. Nagarajan, V. Upadhyaya, Mater. Chem. Phys. 115, 656 (2009)CrossRefGoogle Scholar
  16. 16.
    P. Krishnan, K. Gayathri, G. Bhagavannarayana, V. Jayaramakrishnan, S. Gunasekaran, G. Anbalagan, Spectrochim. Acta A Mol. Biomol. Spectrosc. 112, 152 (2013)ADSCrossRefGoogle Scholar
  17. 17.
    J.H. West Brook, H. Conrad, The Science of Hardness Testing and Its Research Applications. (American Society for Metals, Metals Park, 1971)Google Scholar
  18. 18.
    W. Mott, Micro Indentation Hardness Testing (Butterworths, London, 1956), p. 9Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • K. Sudhakar
    • 1
  • S. Nandhini
    • 1
  • S. Muniyappan
    • 1
  • T. Arumanayagam
    • 1
  • P. Vivek
    • 2
  • P. Murugakoothan
    • 1
  1. 1.MRDL, PG and Research Department of PhysicsPachaiyappa’s CollegeChennaiIndia
  2. 2.Department of PhysicsSri Sankara Arts and Science College (Autonomous)KancheepuramIndia

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