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Cu(II) sorption performance of silane-modified poly(NaSS-co-MA-co-AAm) and poly(NaSS-co-MA-co-NIPAM) terpolymers

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Abstract

This study reports the adsorption of Cu(II) ion by 3-(2-aminoethylamino) propyldimethoxymethylsilane-modified terpolymers. Water-soluble poly(sodium 4-styrenesulfonate-co-maleic anhydride-co-acrylamide) [poly(NaSS-co-MA-co-AAm)] and poly(sodium 4-styrenesulfonate-co-maleic anhydride-co–N-isopropylacrylamide) [poly(NaSS-co-MA-co-NIPAM)] terpolymers were synthesized and then modified with silane to make them water-insoluble. 1H-NMR and FT-IR spectroscopy was used to study the chemical composition of the terpolymers. Also, acid number and viscosity of the polymers were determined. Cu(II) ion adsorption parameters (adsorbent dosage, contact time, pH and metal ion concentration) were studied, and the equilibrium data were evaluated using adsorption isotherm models; Freundlich isotherm gave the best fit. Cu(II) adsorption performance of poly(NaSS-co-MA-co-AAm) and poly(NaSS-co-MA-co-NIPAM) terpolymers was found to be 53.42 and 43.10%, respectively. The terpolymers can be used for removal of Cu(II) from aqueous media.

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Acknowledgement

The authors are thankful to Selcuk University Research Foundation (project number: BAP-14201016) for funding the study.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Selcuk University, Konya, Turkey

    Ahmet Okudan & Emre Ozviran

  2. Department of Biochemistry, Faculty of Science, Selcuk University, Konya, Turkey

    Gulsin Arslan & Idris Sargin

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  1. Ahmet Okudan
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  2. Emre Ozviran
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Correspondence to Ahmet Okudan.

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Okudan, A., Ozviran, E., Arslan, G. et al. Cu(II) sorption performance of silane-modified poly(NaSS-co-MA-co-AAm) and poly(NaSS-co-MA-co-NIPAM) terpolymers. Polym. Bull. 77, 5407–5421 (2020). https://doi.org/10.1007/s00289-019-03025-1

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  • DOI: https://doi.org/10.1007/s00289-019-03025-1

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