Abstract
In this study, effects of coupling agent addition on adhesive wear, thermal and morphological properties of glass fiber-reinforced polyamide 6,6 (PA6,6) composites were investigated. 1,4-Phenylene-bis-oxazoline (PBO) was used as coupling agent to improve the interfacial adhesion between glass fiber and PA6,6 matrix. While coupling agent loading level was changed as 0.5, 1.0 and 2.0 wt%, glass fiber loading level was fixed at 10 wt% in the composites. For tribological characterization of prepared composites, adhesive wear test was performed. Differential scanning calorimeter analysis and thermogravimetric analysis were performed for thermal characterization. In addition to this, scanning electron microscopy analysis was applied to investigate the worn surfaces and fracture surfaces of samples. Applied test results revealed that 2 wt% PBO addition improved the fiber–matrix adhesion and correspondingly adhesive wear resistance of glass fiber-reinforced PA6,6 matrix composites.
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References
Zhou S, Zhang Q, Wu C, Huang J (2013) Effect of carbon fiber reinforcement on the mechanical and tribological properties of polyamide6/polyphenylene sulfide composites. Mater Des 44:493–499
Suresha B (2010) Friction and dry slide wear of short glass fiber reinforced thermoplastic polyurethane composites. J Reinf Plast Compos 29(7):1055–1061
Kumar SS, Kanagaraj G (2016) Investigation on mechanical and tribological behaviors of PA6 and graphite-reinforced PA6 polymer composites. Arab J Sci Eng 41:4347–4357
Sharma M, Bijwe J (2011) Influence of fiber–matrix adhesion and operating parameters on sliding wear performance of carbon fabric polyethersulphone composites. Wear 271:2919–2927
Sharma M, Bijwe J, Mitschang P (2011) Wear performance of PEEK–carbon fabric composites with strengthened fiber–matrix interface. Wear 271:2261–2268
Karsli NG, Demirkol S, Yilmaz T (2016) Thermal aging and reinforcement type effects on the tribological, thermal, thermomechanical, physical and morphological properties of poly(ether ether ketone) composites. Compos Part B Eng 88:253–263
Etcheverry M, Barbosa SE (2012) Glass fiber reinforced polypropylene mechanical properties enhancement by adhesion improvement. Materials 5:1084–1113
Fonseca VM, Fernandes VJ Jr, de Carvalho LH, d’Almeida JRM (2004) Evaluation of the mechanical properties of sisal-polyester composites as a function of the polyester matrix formulation. J Appl Polym Sci 94:1209–1217
Yang J, Xiao J, Zeng J, Bian L, Peng C, Yang F (2013) Matrix modification with silane coupling agent for carbon fiber reinforced epoxy composites. Fiber Polym 14(5):759–766
Erden S, Sever K, Seki Y, Sarikanat M (2010) Enhancement of the mechanical properties of glass/polyester composites via matrix modification glass/polyester composite siloxane matrix modification. Fiber Polym 11(5):732–737
Aberem MB, Feng W, Ait-Kadi A, Riedl B, Brisson J (2005) Modification of glass fiber surface by nylon-6,6 grafting. Compos Interface 12(5):425–443
Shokoohi S, Arefazar A, Khosrokhavar R (2008) Silane coupling agents in polymer-based reinforced composites: a review. J Reinf Plast Compos 27(5):473–485
Srinath G, Gnanamoorthy R (2005) Effect of short fibre reinforcement on the friction and wear behaviour of nylon 66. Appl Compos Mater 12:369–383
Luo W, Liu Q, Li Y, Zhou S, Zou H, Liang M (2016) Enhanced mechanical and tribological properties in polyphenylene sulfide/polytetrafluoroethylene composites reinforced by short carbon fiber. Compos Part B Eng 91:579–588
Xu S, Akchurin A, Liu T, Wood W, Tangpong XW, Akhatov IS, Zhong WH (2015) Mechanical properties, tribological behavior, and biocompatibility of high-density polyethylene/carbon nanofibers nanocomposites. J Compos Mater 49(12):1503–1512
Nirmal U, Lau STW, Hashim J, Devadas A, Yuhazri MY (2015) Effect of kenaf particulate fillers in polymeric composite for tribological applications. Text Res J 85(15):1602–1619
Viña J, García MA, Castrillo MA, Viña I, Argüelles A (2008) Wear behavior of a glass fiber-reinforced PEI composite. J Thermoplast Compos 21:79–286
Padhi PK, Satapathy A, Nakka AM (2015) Processing, characterization, and wear analysis of short glass fiber-reinforced polypropylene composites filled with blast furnace slag. J Thermoplast Compos 28(5):656–671
Bajpai PK, Singh I, Madaan J (2012) Frictional and adhesive wear performance of natural fibre reinforced polypropylene composites. Proc Inst Mech Eng Part J J Eng Tribol 227(4):385–392
Gul O, Yilmaz S, Yilmaz T (2015) Effect of CBC and G-POSS on tribological behaviour of polyamide 6 and short glass fiber reinforced polyamide 6 composites. Acta Phys Pol A 127:1121–1123
Tiwari S, Bijwe J, Panier S (2011) Adhesive wear performance of polyetherimide composites with plasma treated carbon fabric. Tribol Int 44:782–788
Nirmal U, Hashim J, Low KO (2012) Adhesive wear and frictional performance of bamboo fibres reinforced epoxy composite. Tribol Int 47:122–133
Nirmal U, Hashim J, Ahmad MMHM (2015) A review on tribological performance of natural fibre polymeric composites. Tribol Int 83:77–104
Correa CE, Betancourt S, Vázquez A, Gañan P (2015) Wear resistance and friction behavior of thermoset matrix reinforced with Musaceae fiber bundles. Tribol Int 87:57–64
Zhang H, Zhang Z, Friedrich K (2007) Effect of fiber length on the wear resistance of short carbon fiber reinforced epoxy composites. Compos Sci Technol 67:222–230
Tiwari S, Bijwe J (2013) Various ways to strengthen the fiber–matrix interface for enhanced composite performance. Surf Interface Anal 45:1838–1848
Shanmugam D, Thiruchitrambalam M, Thirumurugan R (2016) Wear behavior of Palmyra palm leaf stalk fiber (PPLSF) reinforced polyester composites. Compos Interface 23(2):89–103
Zhang Y, Zhu S, Liu Y, Yang B, Wang X (2015) The mechanical and tribological properties of nitric acid-treated carbon fiber-reinforced polyoxymethylene composites. J Appl Polym Sci 132:41812(1–8)
Tiwari S, Bijwe J, Panier S (2012) Enhancing the adhesive wear performance of polyetherimide composites through nano-particle treatment of the carbon fabric. J Mater Sci 47:2891–2898
Kukureka SN, Hooke CJ, Rao M, Liao P, Chen YK (1999) The effect of fibre reinforcement on the friction and wear of polyamide 66 under dry rolling–sliding contact. Tribol Int 32:107–116
Kim SS, Shin MW, Jang H (2012) Tribological properties of short glass fiber reinforced polyamide 12 sliding on medium carbon steel. Wear 274–275:34–42
Demirci MT, Düzcükoğlu H (2014) Wear behaviors of polytetrafluoroethylene and glass fiber reinforced polyamide 66 journal bearings. Mater Des 57:560–567
Yang B, Leng J, He B, Liu H, Zhang Y, Duan Z (2012) Influence of fiber length and compatibilizer on mechanical properties of long glass fiber reinforced polyamide 6,6. J Reinf Plast Compos 31(16):1103–1112
Alsewailem FD, Gupta RK (2006) Effect of impact modifier types on mechanical properties of rubber-toughened glass-fibre-reinforced nylon 66. Can J Chem Eng 84:693–703
Tjong Sie Chin, Shi-Ai Xu, Li Robert Kwok-Yiu, Mai Yiu-Wing (2002) Short glass fiber-reinforced polyamide 6,6 composites toughened with maleated SEBS. Compos Sci Technol 62:2017–2027
Karayannidis GP, Bikiaris DN, Papageorgiou GZ, Bakirtzis V (2002) Rubber toughening of glass fiber reinforced nylon-6,6 with functionalized block copolymer SEBS-g-MA. Adv Polym Technol 21(3):153–163
Lu C, Chen L, Ye R, Cai X (2008) Chain extension of polyamide 6 using bisoxazoline coupling agents. J Macromol Sci B 47:986–999
Lu C, Chen T, Zhao X, Ren X, Cai X (2007) Chemical modification of polyamide-6 by chain extension with 2,2′-bis(2-oxazoline). J Polym Sci Part B Polym Phys 45:1976–1982
Karsli NG (2015) Enhancing the fracture toughness of glass fiber reinforced polyamide 6,6 composites with the addition of chain extender. Polym Compos. https://doi.org/10.1002/pc.23803
Davim JP, Silva LR, Festas A, Abrão AM (2009) Machinability study on precision turning of PA66 polyamide with and without glass fiber reinforcing. Mater Des 30:228–234
Cadena NL, Cue-Sampedro R, Siller HR, Arizmendi-Morquecho AM, Rivera-Solorio CI, Di-Nardo S (2013) Study of PVD AlCrN coating for reducing carbide cutting tool deterioration in the machining of titanium alloys. Materials 6:2143–2154
Navarro CH, Moreno KJ, Arizmendi-Morquecho A, Chávez-Valdez A, García-Miranda S (2012) Preparation and tribological properties of chitosan/hydroxyapatite composite coatings applied on ultra-high molecular weight polyethylene substrate. J Plast Film Sheet 28:279–297
Aguilera-Camacho LD, Hernández-Navarro C, Moreno KJ, García-Miranda JS, Arizmendi-Morquecho A (2015) Improvement effects of CaO nanoparticles on tribological and microhardness properties of PMMA coating. J Coat Technol Res 12:347–355
Sahin AE, Karsli NG, Sinmazcelik T (2016) Comparison of the mechanical, thermomechanical, thermal, and morphological properties of pumice and calcium carbonate-filled poly(phenylene sulphide) composites. Polym Compos 37:3160–3166
Karsli NG, Aytac A (2013) Tensile and thermomechanical properties of short carbon fiber reinforced polyamide 6 composites. Compos Part B Eng 51:270–275
Chipara M, Lozano K, Hernandez A, Chipara M (2008) TGA analysis of polypropylene-carbon nanofibers composites. Polym Degrad Stabil 93:871–876
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This study was financially supported by the Kocaeli University Scientific Research Projects Unit under project number 2016/005 and it was performed in Kocaeli University Advanced Material Technology Laboratory.
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Karsli, N.G., Yilmaz, T. & Gul, O. Effects of coupling agent addition on the adhesive wear, frictional and thermal properties of glass fiber-reinforced polyamide 6,6 composites. Polym. Bull. 75, 4429–4444 (2018). https://doi.org/10.1007/s00289-018-2278-1
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DOI: https://doi.org/10.1007/s00289-018-2278-1