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Review of gas–liquid mass transfer enhancement by nanoparticles from macro to microscopic

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Abstract

Gas–liquid mass transfer is an extremely common process in the chemical industry and enhancing this process can help achieve high efficiency and low energy consumption. The addition of nanoparticles in the liquid phase is an important method for enhancing such transfers. In this paper, the preparation methods of nanofluids are briefly described and the parameters associated with nanofluid transport, such as mass-transfer coefficient, liquid volumetric mass-transfer coefficient, mass transfer interface area, and gas holdup, are introduced. Then, the latest experiments and mechanisms for the effect of nanofluids on the gas–liquid mass transfer process are reviewed from the viewpoint of transport parameters. The reasons for the enhancement of gas–liquid mass transfer by nanofluids are given: shuttle effect, mixing of the gas–liquid boundary layer, and inhibition of bubble coalescence. Finally, the problems existing in current research are assessed and, toward enhancing gas–liquid mass transfer using nanoparticles, future research directions are proffered.

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References

  1. Bigdeli MB, Fasano M, Cardellini A, Chiavazzo E, Asinari P (2016) A review on the heat and mass transfer phenomena in nanofluid coolants with special focus on automotive applications. Renew Sustain Energy Rev 60:1615–1633

    Article  Google Scholar 

  2. Dhuriya R, Dalia V, Sunthar P (2018) Diffusiophoretic enhancement of mass transfer by nanofluids. Chem Eng Sci 176:632–640

    Article  Google Scholar 

  3. Saidur R, Leong KY, Mohammad HA (2011) A review on applications and challenges of nanofluids. Renew Sustain Energy Rev 15:1646–1668

    Article  Google Scholar 

  4. Choi SUS, Eastman J. (1995) Enhancing thermal conductivity of fluids with nanoparticles

  5. Krishnamurthy S, Lhattacharya P, Phelan PE, Prasher RS (2006) Enhanced mass transport in nanofluids. Nano Lett 6:419–423

    Article  Google Scholar 

  6. Ma X, Su F, Chen R, Zhang Y (2007) Heat and mass transfer enhancement of the bubble absorption for a binary nanofluid. J Mech Sci Technol 21:1813–1818

    Article  Google Scholar 

  7. Zhu H, Shanks BH, Heindel TJ (2008) Enhancing CO-Water Mass Transfer by Functionalized MCM41 Nanoparticles. Ind Eng Chem Res 47:7881–7887

    Article  Google Scholar 

  8. Jeong M, Lee JW, Lee SJ, Kang YT (2017) Mass transfer performance enhancement by nanoemulsion absorbents during CO2 absorption process. Int J Heat Mass Transf 108:680–690

    Article  Google Scholar 

  9. Pang C, Wu W, Sheng W, Zhang H, Kang YT (2012) Mass transfer enhancement by binary nanofluids (NH3/H2O + Ag nanoparticles) for bubble absorption process. International Journal of Refrigeration-Revue Internationale Du Froid 35:2240–2247

    Article  Google Scholar 

  10. Wang T, Yu W, Liu F, Fang M, Farooq M, Luo Z (2016) Enhanced CO2 Absorption and Desorption by Monoethanolamine (MEA)-Based Nanoparticle Suspensions. Ind Eng Chem Res 55:7830–7838

    Article  Google Scholar 

  11. Liu L, Wang M, Liu YF (2015) Experimental Investigation on Preparation and Stability of Al2O3/CuO-water Nanofluids. In: Carl J (ed) Proceedings of the 2015 Asia-Pacific Energy Equipment Engineering Research Conference. Atlantis Press, Paris, pp 99–102

    Google Scholar 

  12. Prakash V, Rai B, Tyagi VK, Niyogi UK (2015) Dispersion and characterizations of nanofluids prepared with CuO and CNT nanoparticle. J Indian Chem Soc 92:1245–1251

    Google Scholar 

  13. Yu W, Xie HQA (2012) Review on Nanofluids: Preparation, Stability Mechanisms. and Applications Journal of Nanomaterials 17

  14. Ghadimi A, Saidur R, Metselaar HSC (2011) A review of nanofluid stability properties and characterization in stationary conditions. Int J Heat Mass Transf 54:4051–4068

    Article  Google Scholar 

  15. Jama M, Singh T, Gamaleldin SM, Koc M, Samara A, Isaifan RJ et al (2016) Critical Review on Nanofluids: Preparation, Characterization, and Applications. J Nanomater

  16. Zhu HT, Lin YS, Yin YS (2004) A novel one-step chemical method for preparation of copper nanofluids. J Colloid Interface Sci 277:100–103

    Article  Google Scholar 

  17. Wu W, Liu S, Hong H, Chen S. (2012) Stability Analysis of Water-Based Nanofluids Prepared by Using Supersonic Dispersion Method. In: Manufacturing Science and Technology, Pts 1–8. Edited by Fan W. pp. 6174–6180

  18. Yang L, Du K, Niu X, Li Y, Zhang Y (2011) An experimental and theoretical study of the influence of surfactant on the preparation and stability of ammonia-water nanofluids. International Journal of Refrigeration-Revue Internationale Du Froid 34:1741–1748

    Article  Google Scholar 

  19. Hong TK, Yang HS, Choi CJ (2005) J Appl Phys 97:1–4

    Article  Google Scholar 

  20. Lee S-Y, Mo K-S, Choi J-H, Hur NH, Kim Y-K, Oh B-K et al (2015) Enhancement of CH4-water mass transfer using methyl-modified mesoporous silica nanoparticles. Korean J Chem Eng 32:1744–1748

    Article  Google Scholar 

  21. Olle B, Bucak S, Holmes TC, Bromberg L, Hatton TA, Wang DIC (2006) Enhancement of oxygen mass transfer using functionalized magnetic nanoparticles. Ind Eng Chem Res 45:4355–4363

    Article  Google Scholar 

  22. Lu S, Xing M, Sun Y, Dong X (2013) Experimental and Theoretical Studies of CO2 Absorption Enhancement by Nano-Al2O3 and Carbon Nanotube Particles. Chin J Chem Eng 21:983–990

    Article  Google Scholar 

  23. Lu S, Zhao Y, Song J, Li Y (2017) Experimental studies of CO2 absorption enhancement in water-based nanofluids of carbon nanotubes. Braz J Chem Eng 34:597–606

    Article  Google Scholar 

  24. Lu S-m, Xing M, Li Y, Song J. (2014) Theoretical and Experimental Research of CO2 Absorption Enhancement by Carbon Nano-tube. In: Micro-Nano Technology Xv. Edited by Tang F; pp. 388–393

  25. Lu S, Song J, Li Y, Xing M, He Q (2015) Improvement of CO2 absorption using AL(2)O(3) nanofluids in a stirred thermostatic reactor. Can J Chem Eng 93:935–941

    Article  Google Scholar 

  26. Park S-W, Choi B-S, Kim S-S, Lee B-D, Lee J-W (2008) Absorption of carbon dioxide into aqueous colloidal silica solution with diisopropanolamine. J Ind Eng Chem 14:166–174

    Article  Google Scholar 

  27. Zhang Y, Zhao B, Jiang J, Zhuo Y, Wang S (2016) The use of TiO2 nanoparticles to enhance CO2 absorption. International Journal of Greenhouse Gas Control 50:49–56

    Article  Google Scholar 

  28. Faraj SHE, Esfahany MN, Jafari-Asl M, Etesami N (2014) Hydrogen Sulfide Bubble Absorption Enhancement in Water-Based Nanofluids. Ind Eng Chem Res 53:16851–16858

    Article  Google Scholar 

  29. Kim JH, Jung CW, Kang YT (2014) Mass transfer enhancement during CO2 absorption process in methanol/Al2O3 nanofluids. Int J Heat Mass Transf 76:484–491

    Article  Google Scholar 

  30. Pineda IT, Kang YT (2016) CO2 absorption enhancement by nanoabsorbents in Taylor-Couette absorber. Int J Heat Mass Transf 100:39–47

    Article  Google Scholar 

  31. Wu W-D, Liu G, Chen S-X, Zhang H (2013) Nanoferrofluid addition enhances ammonia/water bubble absorption in an external magnetic field. Energy and Buildings 57:268–277

    Article  Google Scholar 

  32. Samadi Z, Haghshenasfard M, Moheb A (2014) CO2 Absorption Using Nanofluids in a Wetted-Wall Column with External Magnetic Field. Chemical Engineering & Technology 37:462–470

    Article  Google Scholar 

  33. Taheri M, Mohebbi A, Hashemipour H, Rashidi AM (2016) Simultaneous absorption of carbon dioxide (CO2) and hydrogen sulfide (H2S) from CO2-H2S-CH4 gas mixture using amine-based nanofluids in a wetted wall column. Journal of Natural Gas Science and Engineering 28:410–417

    Article  Google Scholar 

  34. Yang L, Du K, Cheng B, Jiang Y, (2010) Ieee. The Influence of Al2O3 Nanofluid on the Falling Film Absorption with Ammonia-water. In: 2010 Asia-Pacific Power and Energy Engineering Conference

  35. Zhang LY, Liu YY, Wang Y, Li HQ, Yang XH, Jin LW, et al. (2016) Experimental study on enhanced falling film absorption process using H2O/LiBr nanofluids

  36. Zhang LY, Li Y, Wang Y, Cao LX, Meng XZ (2016) Asme. Effect of nanoparticles on H2O/LiBr falling film absorption process

  37. Peyravi A, Keshavarz P, Mowla D (2015) Experimental Investigation on the Absorption Enhancement of CO2 by Various Nanofluids in Hollow Fiber Membrane Contactors. Energy Fuel 29:8135–8142

    Article  Google Scholar 

  38. Golkhar A, Keshavarz P, Mowla D (2013) Investigation of CO2 removal by silica and CNT nanofluids in microporous hollow fiber membrane contactors. J Membr Sci 433:17–24

    Article  Google Scholar 

  39. Darabi M, Rahimi M, Dehkordi AM (2017) Gas absorption enhancement in hollow fiber membrane contactors using nanofluids: Modeling and simulation. Chem Eng Process 119:7–15

    Article  Google Scholar 

  40. Kim J-K, Jung JY, Kang YT (2007) Absorption performance enhancement by nano-particles and chemical surfactants in binary nanofluids. International Journal of Refrigeration-Revue Internationale Du Froid 30:50–57

    Article  Google Scholar 

  41. Zhao B, Li Y, Tong HL, Zhuo YQ, Zhang L, Shi H et al (2005) Study on the reaction rate of sulfite oxidation with cobalt ion catalyst. Chem Eng Sci 60:863–868

    Article  Google Scholar 

  42. Setoura K, Ito S, Miyasaka H (2017) Stationary bubble formation and Marangoni convection induced by CW laser heating of a single gold nanoparticle. Nanoscale 9:719–730

    Article  Google Scholar 

  43. Jiang JZ, Zhao B, Cao M, Zhuo YQ, Wang SJ (2015) Effect of nanoparticles on oxygen absorption enhancement during sulfite forced oxidation. Int J Heat Mass Transf 90:1098–1104

    Article  Google Scholar 

  44. Keshishian N, Esfahany MN, Etesami N (2013) Experimental investigation of mass transfer of active ions in silica nanofluids. International Communications in Heat and Mass Transfer 46:148–153

    Article  Google Scholar 

  45. Lee JW, Pineda IT, Lee JH, Kang YT (2016) Combined CO2 absorption/regeneration performance enhancement by using nanoabsorbents. Appl Energy 178:164–176

    Article  Google Scholar 

  46. Nagy E, Feczko T, Koroknai B (2007) Enhancement of oxygen mass transfer rate in the presence of nanosized particles. Chem Eng Sci 62:7391–7398

    Article  Google Scholar 

  47. Pasieka J, Coulombe S, Servio P (2014) The Effect of Hydrophilic and Hydrophobic Multi-Wall Carbon Nanotubes on Methane Dissolution Rates in Water at Three Phase Equilibrium (V-L-w-H) Conditions. Ind Eng Chem Res 53:14519–14525

    Article  Google Scholar 

  48. Pineda IT, Lee JW, Jung I, Kang YT (2012) CO2 absorption enhancement by methanol-based Al2O3 and SiO2 nanofluids in a tray column absorber. International Journal of Refrigeration-Revue Internationale Du Froid 35:1402–1409

    Article  Google Scholar 

  49. Jiang J-Z, Liu L, Sun B-M (2017) Model study of CO2 absorption in aqueous amine solution enhanced by nanoparticles. International Journal of Greenhouse Gas Control 60:51–58

    Article  Google Scholar 

  50. Yoon S, Chung JT, Kang YT (2014) The particle hydrodynamic effect on the mass transfer in a buoyant CO2-bubble through the experimental and computational studies. Int J Heat Mass Transf 73:399–409

    Article  Google Scholar 

  51. Nedeltchev S (2017) Theoretical prediction of mass transfer coefficients in both gas-liquid and slurry bubble columns. Chem Eng Sci 157:169–181

    Article  Google Scholar 

  52. Sheng W, Wu W, Zhang H, Pang C, Wu R. (2012) Mechanism Analysis on Performance Enhancement of Ammonia Bubble Absorption by Nanofluid. In: Materials Science and Information Technology, Pts 1–8. Edited by Zhang CS. pp. 195–201

  53. Amani P, Amani M, Mehrali M, Vajravelu K (2017) Influence of quadrupole magnetic field on mass transfer in an extraction column in the presence of MnFe2O4 nanoparticles. J Mol Liq 238:145–154

    Article  Google Scholar 

  54. Ghanadi AM, Nasab AH, Bastani D, Kordi AAS (2015) The Effect of Nanoparticles on the Mass Transfer in Liquid-Liquid Extraction. Chem Eng Commun 202:600–605

    Article  Google Scholar 

  55. Sara ON, Icer F, Yapici S, Sahin B (2011) Effect of suspended CuO nanoparticles on mass transfer to a rotating disc electrode. Exp Thermal Fluid Sci 35:558–564

    Article  Google Scholar 

  56. Kim K, Lee J, Seo K, Kim MG, Ha KS, Kim C (2016) Enhancement of methane-water volumetric mass transfer coefficient by inhibiting bubble coalescence with electrolyte. J Ind Eng Chem 33:326–329

    Article  Google Scholar 

  57. Roizard C, Poncin S, Lapicque F, Py X, Midoux N (1999) Behavior of fine particles in the vicinity of a gas bubble in a stagnant and a moving fluid. Chem Eng Sci 54:2317–2323

    Article  Google Scholar 

  58. Jung J-Y, Lee JW, Kang YT (2012) CO2 absorption characteristics of nanoparticle suspensions in methanol. J Mech Sci Technol 26:2285–2290

    Article  Google Scholar 

  59. Ma X, Su F, Chen J, Bai T, Han Z (2009) Enhancement of bubble absorption process using a CNTs-ammonia binary nanofluid. International Communications in Heat and Mass Transfer 36:657–660

    Article  Google Scholar 

  60. Pineda IT, Choi CK, Kang YT (2014) CO2 gas absorption by CH3OH based nanofluids in an annular contactor at low rotational speeds. International Journal of Greenhouse Gas Control 23:105–112

    Article  Google Scholar 

  61. Turanov AN, Tolmachev YV (2009) Heat- and mass-transport in aqueous silica nanofluids. Heat Mass Transf 45:1583–1588

    Article  Google Scholar 

  62. Yang L, Du K, Niu XF, Cheng B, Jiang YF (2011) Experimental study on enhancement of ammonia-water falling film absorption by adding nano-particles. International Journal of Refrigeration-Revue Internationale Du Froid 34:640–647

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (51606065). We thank Richard Haase, Ph.D., from Liwen Bianji, Edanz Group China (www.liwenbianji.cn/ac), for editing the English text of a draft of this manuscript.

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Correspondence to Jia-Zong Jiang.

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Jiang, JZ., Zhang, S., Fu, XL. et al. Review of gas–liquid mass transfer enhancement by nanoparticles from macro to microscopic. Heat Mass Transfer 55, 2061–2072 (2019). https://doi.org/10.1007/s00231-019-02580-7

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