Abstract
Except for small amounts of neutral compounds, the ethanol extracts from fossil Sequoia wood contained over 80% polymeric substances. The bulk of materials was separated into fractions by column chromatography and investigated by means of UV- and FTIR spectroscopy. According to the results the polymeric products are a type of Brauns lignins. Both spectroscopic data revealed considerable changes in. composition and constitution of lignin.
Zusammenfassung
Die Ethanolextrakte einer fossilen Sequoia enthalten neben einem geringen Anteil neutraler Komponenten über 80% polymere Substanzen. Die Hauptmenge wurde durch Säulen-Chromatographie in Fraktionen aufgetrennt und anhand von UV- und FTIR-Spektren charakterisiert. Die polymeren Extrakte erwiesen sich dabei als eine Art von Brauns-Lignin. Beide spektroskopische Methoden weisen auf beträchtliche Veränderungen der chemischen Zusammensetzung des Lignins hin.
Similar content being viewed by others
References
Aulin-Erdtman G, Sanden G (1968) Spectographic Contributions to Lignin Chemistry. IX. Absorption Properties of some 4-Hydroxyphenol, Guaiacyl and 4-Hydroxy-3,5-dimethoxyphenyl Type Model Compounds for Hardwood Lignins. Acta Chem. Scand. 22: 1187–1209
Collier W, Kalasinsky VF, Schultz TP (1997) Infrared Study of Lignin: Assignment of Methoxyl C-H Bending and Stretching Bands. Holzforschung 51: 167–168
Faix O, Schweers W (1974) Vergleichende Untersuchungen an Polymermodellen des Lignins (DHP’s) verschiedener Zusammensetzungen. 4. Mitt. UV-spektrokopische Untersuchungen. Holzforschung 28: 94–98
Faix O, Beinhoff O (1988) FTIR spectra of milled wood lignins and lignin polymer models (DHP’s) with enhanced resolution obtained by deconvolution. Wood Chem. Technol. 8(4): 505–522
Faix O (1991) Classification of lignins from different botanical origins by FT-IR spectroscopy. Holzforschung 45(suppl.): 21–27
Faix O (1992) Fourier Transformation Infrared Spectroscopy. In: Lin SY, Dence CH (Eds.): Methods in Lignin Chemistry, Springer Verlag Berlin Heidelberg
Fengel D, Wegener G, Feckl J (1981) Contribution to Characterization of Analytical and Technical Lignins. (2) Physical-chemical and electron microscopical studies. Holzforschung 45(suppl.): 111–118
Fengel D, Ludwig M (1991) Möglichkeiten und Grenzen der FTIR-Spectroskopie bei der Charakterisierung von Cellulose. Das Papier 45: 45–51
Fengel D (1991) Aging and fossilization of wood and its components. Wood Sei. Technol. 25: 153–177
Hergert HL (1971) Infrared Spectra. In: Sarkanen KV, Ludwig CH (Eds.) Lignins. John Willey and Sons
Kawamura L, Higuchi T (1964) Studies on the properties of lignins of plants’ various taxonomical positions II. On the IR absorption spectra of lignins. Mokuzai Gakkaishi 10: 200–206
Lai YZ, Sarkanen KV (1971) Isolation and structural studies In: Sarkanen KV, Ludwig CH (Eds.) Lignins. John Willey and Sons
Lin SY (1992) Ultraviolet Spectrophotometry. In: Lin SY, Dence CW (Eds.): Methods in Lignin Chemistry. Springer-Verlag Berlin Heidelberg
Michel AJ, Watson AJ, Higgins HG (1965) An infrared spectroscopic study of delignification of Eucalyptus regnans, Tappi 48(9): 520
Obst JR, Mc Millan HJ, Blanchette RA, Christensen DJ, Faix O, Han CS, Küster TA, Landucci LL, Newman RH, Pettersen RC, Schwandt VH, Weselowski MF (1991) Characterization of Canadian arctic fossil woods. In: Christie RL, Mc MillanNJ (Eds.): Tertiary fossil forests of the Geodetic Hills, Axel Heiberg Island, Arctic Archipelago. Geological survey of Canada. Bulletin 403: 123–146
Pearl IA (1976) The Chemistry of Lignins. Macrel Dekker Inc., New York
Sakakibara A, Sasaya T, Miki K, Takahashi H (1987) Lignans and Brauns’ lignins from softwoods. Holzforschung 41: 1–11
Sarkanen KV, Ludwig CH (1971) Lignins. Occurence, Formation, Structure, Reactions. Willey-Interscience (John Willey and Sons Inc.) New York, London, Sydney, Toronto
Uçar G, Staccioli G, Stoll M (1996) Chemical composition und ultrastructure of a fossil wood from the genus of ancestral Sequoia. Holz Roh-Werkstoff 54: 411–421
Wayman M, Azhar MR, Koran Z (1971) Morphology and chemistry of two ancient woods. Wood and Fiber 3: 153–165
Author information
Authors and Affiliations
Additional information
This work was supported by the Research Fund of the University of Istanbul. Project number: 810/190496
The FTIR spectra were taken at the Institute for Wood Research, University of Munich.
Rights and permissions
About this article
Cite this article
Uçar, G., Balaban, M. & Gören, N. Ethanol extractives of fossil Sequoia wood. Holz als Roh- und Werkstoff 56, 430–436 (1998). https://doi.org/10.1007/s001070050347
Issue Date:
DOI: https://doi.org/10.1007/s001070050347