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Influence of thermo-vacuum treatment on thermal degradation of various wood species

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Abstract

Solid wood has a certain amount of resistance to fire exposure. Recently, there is also great interest in characterization of the thermal behaviour of treated wood due to increasing demand of such products within the perspective of sustainability of environment. The objective of this study was to evaluate and predict the thermal decomposition process of samples from different wood species, Norway spruce (Picea abies Karst.), common ash (Fraxinus excelsior L.) and Turkey oak (Quercus cerris L.), so that such data can be used for enhanced design of wood products for more effective and better utilization in different applications. Spruce and ash samples were treated at a temperature of 190 °C for 2 h while Turkey oak specimens were steamed at a temperature of 110 °C for 24 h before they were thermally treated at a temperature of 160 °C for 3 h. A thermo-gravimetric analysis of the samples highlighted intraspecific differences in mass loss and the stage of thermal degradation between treated and untreated specimens. The degradation of the wood was characterized by twofold reaction stages, with an exception of Norway spruce samples, which exhibited a one-stage reaction. In addition, thermal treatments affected chemical composition of wood. The obtained results will be helpful in determining the applicability of these materials according to their thermal degradation properties.

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References

  • Cademartori PHG, dos Santos PS, Serrano L, Labidi J, Gatto DA (2013) Effect of thermal treatment on physicochemical properties of Gympie messmate wood. Ind Crops Prod 45:360–366

    Article  CAS  Google Scholar 

  • Esteves B, Pereira H (2008) Wood modification by heat treatment: a review. Bioresources 4:370–404

    Google Scholar 

  • Ferrari S, Cuccui I, Allegretti O (2013a) Thermo-vacuum modification of some European softwood and hardwood species treated at different conditions. Bioresources 8(1):1100–1109

    Article  Google Scholar 

  • Ferrari S, Allegretti O, Cuccui I, Moretti N, Marra M, Todaro L (2013b) A revaluation of turkey oak wood (Quercus cerris L.) through combined steaming and thermo-vacuum treatments. BioResources 8(4):5051–5066

    Article  Google Scholar 

  • Gasparovic L, Korenova Z, Jelemensky L (2010) Kinetic study of wood chips decomposition by TGA. Chem Pap 4:174–181

    Google Scholar 

  • Grønli MG, Varhegyi G, Di Blasi C (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind Eng Chem Res 41:4201–4208

    Article  Google Scholar 

  • Helsen L, Van den Bulck E, Mullens S, Mullens J (1999) Low-temperature pyrolysis of CCA-treated wood: thermogravimetric analysis. J Anal Appl Pyrol 52:65–86

    Article  CAS  Google Scholar 

  • Hill CA (2007) Wood modification: chemical, thermal and other processes (vol 5). Wiley, New York

    Google Scholar 

  • ISO 14040 (2006) Environmental management—Life cycle assessment - Principles and framework (ISO 14040:2006). International Standard. ISO, Geneva, p. 20

    Google Scholar 

  • ISO 14044 (2006) Environmental management—Life cycle assessment - Requirements and guidelines (ISO 14044:2006), ISO, Geneva

  • John MJ, Thomas S (2008) Biofibres and biocomposites. Carbohyd Polym 71:343–364

    Article  CAS  Google Scholar 

  • Jones JC (2015) Letter: fire loads and the calorific value of wood. Fuel 159:975

    Article  CAS  Google Scholar 

  • Kim UJ, Eom SH, Wada M (2010) Thermal decomposition of native cellulose: influence on crystallite size. Polym Degrad Stabil 95:778–781

    Article  CAS  Google Scholar 

  • Martinka J, Hroncová E, Chrebet T, Balog K (2014) The influence of spruce wood heat treatment on its thermal stability and burning process. Eur J Wood Prod 72:477–486

    Article  CAS  Google Scholar 

  • Mészáros E, Jakab E, Várhegyi G (2007) TG/MS, Py-GC/MS and THM-GC/MS study of the composition and thermal behavior of extractive components of Robinia pseudoacacia. J Anal Appl Pyrolysis 79:61–70

    Article  Google Scholar 

  • Mohan D, Pittman CU, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: A critical review. Energ Fuel 20:848–889

    Article  CAS  Google Scholar 

  • Poletto M, Dettenborn J, Pistor V, Zeni M. Zattera A (2010) Materials produced from plant biomass. Part I: evaluation of thermal stability and pyrolysis of wood. Mater Res 13:375–379

    Article  CAS  Google Scholar 

  • Popescu MC, Popescu CM, Lisa G, Sakata Y (2011) Evaluation of morphological and chemical aspects of different wood species by spectroscopy and thermal methods. J Mol Struct 988:65–72

    Article  CAS  Google Scholar 

  • Prime RB, Bair HE, Vyazovkin S, Gallagher PK, Riga A (2009) Thermogravimetric Analysis (TGA). In: Menczel JD, Prime RB (eds) Thermal Analysis of Polymers: Fundamentals and Applications. Wiley, Hoboken

    Google Scholar 

  • Qu T, Guo W, Shen L, Xiao J, Zhao K (2011) Experimental study of biomass pyrolysis based on three major components: Hemicellulose, cellulose, and lignin. Ind Eng Chem Res 50:10424–10433

    Article  CAS  Google Scholar 

  • Raveendran K, Ganesh A, Khilar KC (1996) Pyrolysis characteristics of biomass and biomass components. Fuel 75:987–998

    Article  CAS  Google Scholar 

  • Sebio-Puñal T, Naya S, López-Beceiro J, Tarrío-Saavedra J, Artiaga R (2012) Thermogravimetric analysis of wood, holocellulose, and lignin from five wood species. J Therm Anal Calorim 109:1163–1167

    Article  Google Scholar 

  • Stamm AJ (1956) Thermal degradation of wood and cellulose. Ind Eng Chem 48:413–417

    Article  CAS  Google Scholar 

  • Strezov V, Moghtaderi B, Lucas J (2003) Thermal study of decomposition of selected biomass samples. J Therm Anal Calorim 72:1041–1048

    Article  CAS  Google Scholar 

  • TAPPI UM 250 (1991) Acid-soluble lignin in wood and pulp, in: 1991 TAPPI Useful Methods, Tappi

  • Todaro L, Dichicco P, Moretti N, D’Auria M (2013) Effect of combined steam and heat treatments on extractives and lignin in sapwood and heartwood of Turkey oak (Quercus cerris L.) wood. Bioresources 8:1718–1730

    Article  Google Scholar 

  • Todaro L, Rita A, Cetera P, D’Auria M (2015a) Thermal treatment modifies the calorific value and ash content in some wood species. Fuel 140:1–3

    Article  CAS  Google Scholar 

  • Todaro L, Rita A, Moretti N, Cuccui I, Pellerano A (2015b) Assessment of thermo-treated bonded wood performance: comparisons among Norway spruce, common ash, and Turkey oak. Bioresources 10:772–781

    CAS  Google Scholar 

  • Várhegyi G, Grønli MG, Di Blasi C (2004) Effects of sample origin, extraction, and hot-water washing on the devolatilization kinetics of chestnut wood. Ind Eng Chem Res 43:2356–2367

    Article  Google Scholar 

  • Yaman S (2004) Pyrolysis of biomass to produce fuels and chemical feedstocks. Energ Convers Manage 45:651–671

    Article  CAS  Google Scholar 

  • Yang H, Yan R, Chen H, Zheng C, Lee DH, Liang DT (2006) In-depth investigation of biomass pyrolysis based on three major components: hemicellulose, cellulose and lignin. Energ Fuel 20:388–393

    Article  CAS  Google Scholar 

  • Yao F, Wu Q, Lei Y, Guo W, Xu Y (2008) Thermal decomposition kinetics of natural fibers: Activation energy with dynamic thermogravimetric analysis. Polym Degrad Stabil 93:90–98

    Article  CAS  Google Scholar 

  • Yildiz S, Geze ED, Yildiz UC (2006) Mechanical and chemical behavior of spruce wood modified by heat. Build Environment 41:1762–1766

    Article  Google Scholar 

  • Yin Y, Berglund L, Salmén L (2010) Effect of steam treatment on the properties of wood cell walls. Biomacromolecules 12:194–202

    Article  PubMed  Google Scholar 

Download references

Acknowledgements

This work was supported by the Italian Ministry of Education, University and Research MIUR-PRIN 2015 (Grant No. 2015YW8JWA) granted to LT. The research was also carried out in the framework of the project ‘Smart Basilicata’, which was approved by MIUR (Notice n.84/Ric 2012, PON 2007–2013 of 2 March 2012) and funded with the Cohesion Fund 2007–2013 of the Basilicata Regional authority. The authors’ thanks are due to Prof. G. Gorrasi for the technical assistance.

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Correspondence to Angelo Rita.

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Todaro, L., Rita, A., Pucciariello, R. et al. Influence of thermo-vacuum treatment on thermal degradation of various wood species. Eur. J. Wood Prod. 76, 541–547 (2018). https://doi.org/10.1007/s00107-017-1230-7

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  • DOI: https://doi.org/10.1007/s00107-017-1230-7

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