Abstract
This study investigates the influence of different types of reinforcing fillers on the mechanical properties and wettability of wood–plastic composite material. Micro-sized glass fibers (GF) and carbon fibers (CF) and nano-sized montmorillonite (MMT) were used to reinforce a polypropylene/wood flour composite. Clear improvement of the tensile strength and modulus, up to 20 and 29 %, respectively, was observed when GF was loaded; the impact strength was reduced by 7 %; the hardness of the composite was improved by up to 7 %. No significant change in the tensile strength was observed after the CF loading; the tensile modulus was improved by 18 %; the impact strength of the composite was reduced and hardness was improved by 19 and 7 %, respectively. The MMT enhanced the tensile modulus by 34 %; the other studied mechanical properties, tensile and impact strengths, as well as the hardness of the composite decreased by 12, 32 and 15 %, respectively. The water absorption level decreased with all three filler type loadings. The morphology of the composites was examined using a scanning electron microscope (SEM).
Zusammenfassung
In dieser Studie wird der Einfluss verschiedener Arten von Verstärkerfüllstoffen auf die mechanischen Eigenschaften und die Benetzbarkeit von Holz-Kunststoff-Verbundwerkstoffen (WPC) untersucht. Zur Verstärkung eines Polypropylen (PP)/Holzmehl (WF)-Verbundwerkstoffs wurden mikroskalige Glas- (GF) und Karbonfasern (CF) sowie nanoskaliger Montmorillonit (MMT) verwendet. Bei Zugabe von Glasfasern konnte eine deutliche Verbesserung der Zugfestigkeit und des Elastizitätsmoduls um bis zu 20 bzw. 29 % verzeichnet werden. Die Schlagfestigkeit ging um 7 % zurück und die Härte verbesserte sich um 7 %. Nach Zugabe von Karbonfasern war keine signifikante Änderung der Zugfestigkeit zu verzeichnen. Der Elastizitätsmodul verbesserte sich um 18 %, die Schlagfestigkeit ging um 19 % zurück und die Härte verbesserte sich um 7 %. Durch Zugabe von Montmorillonit verbesserte sich der Elastizitätsmodul um 34 %, die Zugfestigkeit ging um 12 %, die Schlagfestigkeit um 32 % und die Härte um 15 % zurück. Die Wasseraufnahme nahm bei allen drei Füllstoffen ab. Die Morphologie der Verbundwerkstoffe wurde mittels Rasterelektronenmikroskop (SEM) untersucht.
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References
Bledzki AK, Faruk O (2003) Wood fibre reinforced polypropylene composites: effect of fibre geometry and coupling agent on physico-mechanical properties. Appl Compos Mater 10:365–379
Chung DDL (2010) Composite materials: Science and applications. Springer, London
Cui Y, Tao J (2009) Fabrication and mechanical properties of glass fiber-reinforced wood plastic hybrid composite. J Appl Polym Sci 112:1250–1257
Deka BK, Maji TK (2010) Effect of coupling agent and nanoclay on properties of HDPE, LDPE, PP, PVC blend and Phargamites karka nanocomposites. Compos Sci Technol 70:1755–1761
Faruk O, Matuana LM (2008) Nanoclay reinforced HDPE as a matrix for wood–plastic composites. Compos Sci Technol 68:2073–2077
Giraldi ALFM, Bartoli JR, Velasco JI, Mei LHI (2005) Glass fibre recycled poly(ethylene terephthalate) composites: mechanical and thermal properties. Polym Test 24:507–512
Gu R, Kokta BV, Michalkova D, Dimzoski B, Fortelny I, Slouf M, Krulis Z (2010) Characteristics of wood–plastic composites reinforced with organo-nanoclays. J Reinf Plast Compos 29:3566–3586
Guo G, Park CB, Lee YH, Sain M (2007) Flame retarding effects of nanoclay on wood-fiber composites. Polym Eng Sci 47:330–336
Gwon JG, Lee SY, Chun SJ, Doh GH, Kim JH (2011) Physical and mechanical properties of wood–plastic composites hybridized with inorganic fillers. J Compos Mater 46:301–309
Huuhilo T, Martikka O, Butylina S, Kärki T (2010) Mineral fillers for wood–plastic composites. Wood Mater Sci Eng 1:34–40
Jeamtrakull S, Kositchaiyong A, Markpin T, Rosarpitak V, Sombatsompop N (2012) Effect of wood constituents and content, and glass fiber reinforcement on wear behavior of wood/PVC composite. Composites Part B 43:2721–2729
Jiang H, Kamdem DP, Bezubic B, Ruede P (2003) Mechanical properties of poly(vinyl chloride)/wood flour/glass fiber hybrid composite. J Vinyl Add Technol 9:138–145
Kalia S, Kaith BS, Kaur I (2009) Pretreatments of natural fibers and their application as reinforcing material in polymer composites–a review. Polym Eng Sci 49:1253–1272
Keener TJ, Stuart RK, Brown TK (2004) Maleated coupling agents for natural fibre composites. Compos A 35:357–362
Klyosov AK (2007) Wood–plastic composites. Wiley-Interscience, New Jersey
Lee YH, Kuboki T, Park CB, Sain M, Kontopoulou M (2010) The effect of clay dispersion on the mechanical, physical, and flame-retarding properties of wood fiber/polyethylene/clay nanocomposites. J Appl Polym Sci 118:452–461
Nuñez AJ, Strum PC, Kenny JM, Aranguren MI, Marcovich NE, Reboredo MM (2003) Mechanical characterization of polypropylene-wood flour composites. J Appl Polym Sci 88:1420–1428
Panthapulakkal S, Sain M (2007) Studies on the water absorption properties of short hemp–glass fiber hybrid polypropylene composites. J Compos Mater 41:1871–1883
Rizvi GM, Semeralul H (2008) Glass-fiber-reinforced wood/plastic composites. J Vinyl Additive Technol 11:39–42
Salehi-Mobarakeh H, Brisson J, Ait-Kadi A (1998) Ionic interphase of glass fibre/polyamide 6,6 composite. Polym Compos 18:264–274
Thomason JL, Vlug MA (1996) Influence of fibre length and concentration on the properties of glass fibre-reinforced polypropylene: 1. Tensile and flexural modulus. Compos A 27:477–484
Thwe MM, Liao K (2003) Durability of bamboo-glass fiber reinforced polymer matrix composites. Compos Sci Technol 63:375–387
Tungjitpornkull S, Chaochanchaikul K, Sombatsompop N (2007) Mechanical characterization of E- chopped strand glass fiber reinforced wood/PVC composite. J Thermoplast Compos Mater 20:535–550
Xanthos M (2005) Functional Fillers for Plastics. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Yang C, Li G, Qi R, Huang M (2012) Glass fiber/wood flour modified high density polyethylene composite. J Appl Polym Sci 123:2084–2089
Yeh S-K, Gupta RK (2010) Nanoclay-reinforced, polypropylene-based wood–plastic composites. Polym Eng Sci 55:2013–2020
Zhang Y, Zhang J, Shi J, Toghiani H, Xue Y, Pittman CU Jr (2009) Flexural properties and micromorphologies of wood flour/carbon nanofiber/maleated polypropylene/polypropylene composites. Compos A 40:948–953
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Turku, I., Kärki, T. The effect of carbon fibers, glass fibers and nanoclay on wood flour-polypropylene composite properties. Eur. J. Wood Prod. 72, 73–79 (2014). https://doi.org/10.1007/s00107-013-0754-8
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DOI: https://doi.org/10.1007/s00107-013-0754-8