Skip to main content
Log in

Evaluating the wettability of MUF resins and pMDI on two different OSB raw materials

Ermittlung der Benetzbarkeit von MUF Harz und pMDI auf zwei unterschiedlichen Rohstoffen für die OSB Produktion

  • Originals Originalarbeiten
  • Published:
European Journal of Wood and Wood Products Aims and scope Submit manuscript

Abstract

In this paper, the wettability of two different wood species as raw material for Oriented Strand Board (OSB) is analyzed. One species is pine, a common material for the production of OSB; the other species, poplar, and especially hybrid poplar, is newly used in OSB and might require a modified board production process compared to pine. Therefore, strands of hybrid poplar obtained from a central European poplar plantation were compared to pine strands in terms of surface characteristics and contact angles after application of the adhesives. For the contact angle measurement droplets of two types of adhesives, melamine urea formaldehyde (MUF) resin and polymeric methylene diphenyl diisocyanate (pMDI), were applied onto the surface of the strands. pMDI exhibited larger contact angles on poplar than on pine; but for both wood species the contact angles were low when compared to MUF. MUF values were much higher, but relatively similar numbers were measured for both wood species.

Zusammenfassung

In dieser Arbeit wird die Benetzbarkeit von zwei unterschiedlichen Holzarten, welche als Rohstoffe für die Erzeugung von OSB in Frage kommen, untersucht. Zum einen wurde Kiefer, ein gängiges Rohmaterial für die Erzeugung von OSB, zum anderen Pappel, die speziell in Form von Hybridpappelholz zunehmend Verwendung in der OSB-Herstellung untersucht Pappel, die speziell in Form von Hybridpappelholz zunehmend Verwendung in der OSB-Herstellung findet. Zu diesem Zweck wurden im Rahmen dieser Arbeit OSB-Späne (Strands) einer zentraleuropäischen Pappelplantage mit Kieferspänen hinsichtlich Oberflächenenergie und Benetzungsverhalten verglichen. Für die Kontaktwinkelmessung wurden die Harze Melaminharnstoff Formaldehyd (MUF) und polymeres Diphenylmethandiisocyanat (pMDI) in Tropfenform auf die Späne aufgetragen und die Kontaktwinkel gemessen. Das pMDI-Harz zeigte größere Kontaktwinkel auf Pappel als auf Kiefer, jedoch waren die Kontaktwinkel auf beiden Holzarten gering im Vergleich zu jenen von MUF. Die mit MUF gemessenen Kontaktwinkel zeigten im Vergleich zu pMDI wesentlich höhere Werte mit geringen Unterschieden zwischen den beiden Holzarten.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1 Abb. 1
Fig. 2 Abb. 2
Fig. 3 Abb. 3
Fig. 4 Abb. 4

Similar content being viewed by others

References

  • Beaudoin M, Hernandez RE, Koubaa A, Poliquin J (1992) Interclonal, intraclonal and within-tree variation in wood density of polar hybrid clones. Wood Fiber Sci 24(2):147–153

    Google Scholar 

  • Boehme C, Hora G (1996) Water absorption and contact angle measurement of native European, North American and tropical wood species to predict gluing properties. Holzforschung 50(3):269–276

    Article  CAS  Google Scholar 

  • Bogner A (1991) Improving adhesive quality by modification of wood surface. Holz Roh Werkst 49(7–8):271–275

    Article  CAS  Google Scholar 

  • Conrad MPC, Smith GD, Fernlund G (2004) Fracture of wood composites and wood-adhesive joints: a comparative review. Wood Fiber Sci 36(1):26–39

    CAS  Google Scholar 

  • de Meijer M, Haemers S, Cobben W, Militz H (2000) Surface energy determinations of wood: comparison of methods and wood species. Langmuir 16(24):9352–9359

    Article  Google Scholar 

  • Feist WC, Hon DN-S (1984) Chemistry of weathering and protection. In: Rowell RM (ed) The chemistry of solid wood, vol 207. Advances in Chemistry. American Chemical Society, Washington. pp 401–451

  • Fowkes FM (1964) Attractive forces at interfaces. Ind Eng Chem 56(12):40

    Article  CAS  Google Scholar 

  • Geimer RL, Crist JB (1980) Structural flakeboard from short-rotation, intensively cultured hybrid populus clones. Forest Prod J 30(6):42–48

    Google Scholar 

  • Gindl M, Sinn G, Gindl W, Reiterer A, Tschegg S (2001) A comparison of different methods to calculate the surface free energy of wood using contact angle measurements. Colloids Surf A 181(1–3):279–287

    Article  CAS  Google Scholar 

  • Gindl M, Reiterer A, Sinn G, Stanzl-Tschegg SE (2004) Effects of surface ageing on wettability, surface chemistry, and adhesion of wood. Holz Roh Werkst 62(4):273–280

    Article  CAS  Google Scholar 

  • Good RJ (1993) Contact angle, wettability and adhesion: a critical review. In: Mittal KL (ed) Contact angle, wettability and adhesion. VSP, Utrecht, pp 3–36

    Google Scholar 

  • Gunnells DW, Gardner DJ, Wolcott MP (1994) Temperature-dependence of wood surface-energy. Wood Fiber Sci 26(4):447–455

    CAS  Google Scholar 

  • Hameed M, Roffael E (1999) On the wettability of sapwood and heartwood of various woodspecies (Pine, Douglas fir and Larch). Holz Roh Werkst 57(4):287–293

    Article  CAS  Google Scholar 

  • Herczeg A (1965) Wettability of wood. Forest Prod J 15(11):499–505

    CAS  Google Scholar 

  • Hernandez RE, Koubaa A, Beaudoin M, Fortin Y (1998) Selected mechanical properties of fast-growing poplar hybrid clones. Wood Fiber Sci 30(2):138–147

    CAS  Google Scholar 

  • Higuchi T (1997) Biochemistry and molecular biology of wood. Springer, Berlin

    Book  Google Scholar 

  • Janssen D, De Palma R, Verlaak S, Heremans P, Dehaen W (2006) Static solvent contact angle measurements, surface free energy and wettability determination of various self-assembled monolayers on silicon dioxide. Thin Solid Films 515(4):1433–1438

    Article  CAS  Google Scholar 

  • Kaelble DH (1970) Dispersion-polar surface tension properties of organic solids. J Adhes 2(2):66–81

    Article  CAS  Google Scholar 

  • Kamke FA, Lee JN (2007) Adhesive penetration in wood—a review. Wood Fiber Sci 39(2):205–220

    CAS  Google Scholar 

  • Kretschmann DE, Isebrands JG, Stanosz G, Dramm JR, Olstad A, Cole D, Samsel J (1999) Structural lumber properties of hybrid poplar. Res. Pap. FPL–RP–573. US Department of Agriculture, Forest Service, Forest Products Laboratory, Madison

  • Liptakova E, Kudela J, Bastl Z, Spirovova I (1995) Influence of mechanical surface-treatment of wood on the wetting process. Holzforschung 49(4):369–375

    Article  CAS  Google Scholar 

  • Maloney TM, Lentz MT, Canbron G (1995) Oriented strandboard from Douglas fir, hemlock, spruce, cedar, and poplar. Res. Rept. 3808–2996. Wood Materials and Engineering Laboratory, Washington State Univ., Pullman, WA

  • Nguyen T, Johns WE (1979) Effects of aging and extraction on the surface free-energy of Douglas-fir and redwood. Wood Sci Technol 13(1):29–40

    Article  CAS  Google Scholar 

  • Nussbaum RM (1999) Natural surface inactivation of Scots pine and Norway spruce evaluated by contact angle measurements. Holz Roh Werkst 57(6):419–424

    Article  Google Scholar 

  • Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13(8):1741–1747

    Article  CAS  Google Scholar 

  • Peters JJ, Bender DA, Wolcott MP, Johnson JD (2002) Selected properties of hybrid poplar clear wood and composite panels. Forest Prod J 52(5):45–54

    Google Scholar 

  • Rabel W (1971) Einige Aspekte der Benetzungstheorie und ihre Anwendung auf die Untersuchung und Veränderung der Oberflächeneigenschaften von Polymeren. Farbe und Lack 77(10):997–1005

    CAS  Google Scholar 

  • Röhle H, Ali W, Hartmann K-U, Steinke C (2010) Wachstum und Biomasseproduktion schnellwachsender Baumarten im Kurzumtrieb. In: Bemmann A, Knust C (eds) Agrowood—Kurzumtriebsplantagen in Deutschland und europäische Perspektiven. Weißensee Verlag, Berlin, pp 103–116

    Google Scholar 

  • Scheikl M, Dunky M (1996) Computerized static and dynamic contact-angle measuring methods in connection with wettability of wood. Holz Roh Werkst 54(2):113–117

    Article  CAS  Google Scholar 

  • Scheikl M, Dunky M (1998) Measurement of dynamic and static contact angles on wood for the determination of its surface tension and the penetration of liquids into the wood surface. Holzforschung 52(1):89–94

    Article  CAS  Google Scholar 

  • Semple KE, Vaillant MH, Kang KY, Oh SW, Smith GD, Mansfield SD (2007) Evaluating the suitability of hybrid poplar clones for the manufacture of oriented strand boards. Holzforschung 61(4):430–438

    Article  CAS  Google Scholar 

  • Shen Q, Nylund J, Rosenholm JB (1998) Estimation of the surface energy and acid-base properties of wood by means of wetting method. Holzforschung 52(5):521–529

    Article  CAS  Google Scholar 

  • Shi SQ, Gardner DJ (2001) Dynamic adhesive wettability of wood. Wood Fiber Sci 33(1):58–68

    CAS  Google Scholar 

  • Sinn G, Gindl M, Reiterer A, Stanzl-Tschegg S (2004) Changes in the surface properties of wood due to sanding. Holzforschung 58(3):246–251

    Article  CAS  Google Scholar 

  • Smith GD (2005) The lap-shear strength of bonds between Oriented Strand Board (OSB) like strands coated with pMDI resin. Holz Roh Werkst 63(4):311–312

    Article  CAS  Google Scholar 

  • van Oss CJ, Good RJ, Chaudhury MK (1988) Additive and nonadditive surface-tension components and the interpretation of contact angles. Langmuir 4(4):884–891

    Article  Google Scholar 

  • Wagenführ R (1999) Anatomie des Holzes. DRW-Verlag, Leinfelden-Echterdingen

    Google Scholar 

  • Walinder MEP, Strom G (2001) Measurement of wood wettability by the Wilhelmy method—Part 2. Determination of apparent contact angles. Holzforschung 55(1):33–41

    Article  CAS  Google Scholar 

  • Wegener G (1999) Oriented structural boards (OSB) from fast-growing poplar and willow in Industrial end uses of fast grown species. Paper presented at the Proceedings of the Eurowood Technical Workshop, Florence, Italy

  • Whitesides GM, Biebuyck HA, Folkers JP, Prime KL (1991) Acid-Base Interactions in Wetting. J Adhes Sci Technol 5(1):57–69

    Article  CAS  Google Scholar 

  • Young T (1805) An essay on the cohesion of fluids. Trans R Soc 95:65–87

    Article  Google Scholar 

  • Zhang XL, Gardner DJ, Muszynski L (2009) Ultrasonic atomization of pMDI wood resin. Wood Fiber Sci 41(1):84–89

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jörn Rathke.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rathke, J., Sinn, G. Evaluating the wettability of MUF resins and pMDI on two different OSB raw materials. Eur. J. Wood Prod. 71, 335–342 (2013). https://doi.org/10.1007/s00107-013-0675-6

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00107-013-0675-6

Keywords

Navigation