Skip to main content
Log in

The effect of acetylated particle distribution and type of resin on physical and mechanical properties of poplar particleboard

Einfluss der Verteilung acetylierter Späne im Plattenquerschnitt und der Harzart auf die physikalischen und mechanischen Eigenschaften von Pappelspanplatten

  • Originals Originalarbeiten
  • Published:
European Journal of Wood and Wood Products Aims and scope Submit manuscript

Abstract

This paper presents the results of a study on using acetylated particles for particleboard production. A three-layer board with distributed acetylated particles on the surface layers and a single-layer board with a uniform distribution of acetylated particles were fabricated. Three levels of acetylation of  0, 8.4 and 17.3% weight percentage gain (WPG), i.e., zero, medium and high levels of acetylation, were applied. The boards were fabricated with 4 wt% methylene diphenyl diisocyanate (MDI) and 10 wt% urea formaldehyde (UF) adhesive. The results indicated that the mechanical properties of the boards were negatively affected by acetylated particles. Overall, MDI-bonded particleboards gave superior mechanical performance, water resistance, and thickness swell to UF-bonded particleboards. The strength of UF-bonded boards decreased much more than that of MDI-bonded boards as acetylation level increased. The MDI-bonded single-layer boards made using medium-level acetylation were recognized to have suitable mechanical properties, and the MDI-bonded three-layer boards made from high level acetylation showed suitable dimensional stability.

Zusammenfassung

Vorgestellt werden die Ergebnisse einer Studie über die Verwendung von acetylierten Spänen zur Herstellung von Spanplatten. Es wurden eine dreischichtige Platte mit acetylierten Spänen in den Deckschichten und eine einschichtige Platte mit 50% acetylierten Spänen hergestellt. Dabei wurden drei Acetylierungsgrade angewandt  0, 8,4 und 17,3% Gewichtszunahme (WPG), d. h. null, mittlerer und hoher Grad an Acetylierung. Die Platten wurden mit 4 Gew.% Methylendiphenyldiisocyanat (MDI) und 10 Gew.% Harnstoff-Formaldehydharz (UF) hergestellt. Die Ergebnisse zeigten, dass die acetylierten Späne einen negativen Einfluss auf die mechanischen Eigenschaften der Platten hatten. Im Allgemeinen zeigten die MDI-verklebten Spanplatten bessere mechanische Eigenschaften, Wasserresistenz und Dickenquellung als die UF-verklebten Spanplatten. Mit zunehmendem Acetylierungsgrad nahm die Festigkeit der UF-verklebten Platten stärker ab als die der MDI-verklebten Platten. Die MDI-verklebten einschichtigen Platten mit mittlerem Acetylierungsgrad wiesen brauchbare mechanische Eigenschaften auf und die MDI-verklebten dreischichtigen Platten mit hohem Acetylierungsgrad ergaben eine brauchbare Dimensionsstabilität.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1 Abb. 1
Fig. 2 Abb. 2
Fig. 3 Abb. 3
Fig. 4 Abb. 4
Fig. 5 Abb. 5

Similar content being viewed by others

References

  • ANSI A208.1 (1998) Particleboard. American National Standard. Composite Panel Association

  • ASTM  D 1037-99 Standard (1999) Standard test method for evaluating properties of wood-based fiber and particle panel materials. Designation, West Conshohocken, pp  142–171

  • Boquillon N, Elbez G, Schonfeld U (2004) Properties of wheat straw particleboards bonded with different types of resin. J  Wood Sci 50:230–235

    CAS  Google Scholar 

  • Chow P, Bao Z, Youngquist JA, Rowell RM, Muehl JH, Krzysik AM (1996) Properties of hardboard made from acetylated aspen and southern pine. Wood Fiber Sci 28:252–258

    CAS  Google Scholar 

  • Das S, Malmberg MJ, Frazier CE (2007) Care chemistry of wood polymeric isocyanate (PMDI) bonds: effect of wood species. Int J Adhes Adhes 27:250–257

    Article  CAS  Google Scholar 

  • DIN 52362 (1965) Testing of wood chipboards; bending test, determination of bending strength. DIN German Institute for Standardization. Beuth Verlag GmbH, Berlin, Köln

  • Dreher WA, Goldstein IS, Gramer GR (1964) Mechanical properties of acetylated wood. For Prod  J 14:66–68

    Google Scholar 

  • Dziurka D, Tęcka J, Mirski R (2003) The effect of grafting particles with acetoactyl groups on the properties of particleboards. EJPAU 6(2), #02 http://www.ejpau.media.pl/volume6/issue2/wood/art-02.html

  • EN  317 (1993) Particleboards and fiberboards, determination of swelling in thickness after immersion. European Standardization Committee, Brussels

  • EN  312-2 (1996) Particleboards – specifications – part  2: requirements for general-purpose boards for use in dry conditions. European Standardization Committee, Brussels

  • Frazier CE, Ni J (1998) On the occurrence of network interpenetration in the wood-isocyanate adhesive interphase. Int J Adhes Adhes 18:81–87

    Article  CAS  Google Scholar 

  • Grigoriou AH (2003) Waste paper-wood composites bonded with isocyanate. Wood Sci Technol 37:79–89

    Article  CAS  Google Scholar 

  • Halligan AF (1970) A review of thickness swelling in particleboard. Wood Sci Technol 4:301–319

    Article  Google Scholar 

  • ISO 16893 (2003) Wood-based panels – determination of swelling in thickness after immersion in water. ISO International Organization for Standardization

  • Krzysik AM, Yonugquist JA, Muehl JM, Rowell RM, Chow P, Shook SR (1992) Dry-process hardboard from recycled newsprint paper fibers. In: Rowell RM, Laufenberg TL, Rowell JK (eds) Materials interactions relevant to recycling of wood-based materials. Materials Research Society, Pittsburgh, pp  73–79

    Google Scholar 

  • Okino EYA, Teixeira DE, Souza MR, Santana MAE, Sousa ME (2004) Properties of oriented strand board made of wood species from Brazilian planted forests: part  1. 80 mm-long strands of Pinus taeda  L. Holz Roh- Werkst 62:221–224

    Article  CAS  Google Scholar 

  • Papadopoulos AN (2006) Property comparisons and bonding efficiency of UF and PMDI bonded particleboards as affected by key process variables. Bioresources 1:201–208

    Google Scholar 

  • Pizzi A (1989) Wood adhesive, chemical and technology. Marcel Dekker Inc., New York

    Google Scholar 

  • Pizzi A (1994) Advanced wood adhesives technology. Marcel Dekker Inc., New York

    Google Scholar 

  • Rowell RM (1982) Distribution of acetyl groups in southern pine reacted with acetic anhydride. J  Wood Sci 15:172–182

    CAS  Google Scholar 

  • Rowell RM (2005) Handbook of wood chemistry and wood composites. CRC Press, Boca Raton

    Google Scholar 

  • Rowell RM (2006) Acetylation of wood. For Prod  J 56:1–12

    Google Scholar 

  • Rowell RM, Banks WB (1987) Tensile strength and work to failure of acetylated pine and lime flakes. Br Polym  J 19:479–482

    CAS  Google Scholar 

  • Rowell RM, Ellis WD (1981) Bonding of isocyanates to wood. In: Edwards KN (ed) American Chemical Society Symposium Series 172. Washington DC, pp  263–284

  • Rowell RM, Imamura Y, Kawai S, Noimoto M (1989) Dimensional stability, decay resistance and mechanical properties of veneer-faced low density particleboards made from acetylated wood. Wood Fiber Sci 21:67–79

    CAS  Google Scholar 

  • Rowell RM, Simonson R, Tillman A (1986) A simplified procedure for the acetylation of chips for dimensionally stable particleboard products. Paperi ja Puu 68:740–744

    CAS  Google Scholar 

  • Rowell RM, Simonson R, Hess S, Plackett DV, Cronshaw D, Dunningham E (1994) Acetyl distribution in acetylated whole wood and reactivity of isolated wood cell wall components to acetic anhydride. Wood Fiber Sci 26:11–18

    CAS  Google Scholar 

  • Rudkin AW (1950) The role of the hydroxyl group in the gluing of wood. Aust J Appl Sci 1:270–283

    CAS  Google Scholar 

  • Sauter SL (1996) Developing composites from wheat straw. In: Proceeding of the 30th international symposium of Washington State University on particleboard/composite materials, pp  197–214

  • Sellers Jr T (1992) Wood adhesives market builds a promising future on a profitable past. Adhes Age 35:22–25

    Google Scholar 

  • Sheen AD (1992) The preparation of the acetylated wood fiber on a commercial scale. In: Plackett DV, Dunningham EA (eds) Chemical modification of lignocellulosics. FRI Bulletin 176. New Zealand Forest Research Institute, Rotorua, New Zealand, pp 1–8

    Google Scholar 

  • Stamm AJ, Tarkow H (1947) Dimensional stabilization of wood. J  Phys Colloid Chem 51:493–505

    Article  CAS  Google Scholar 

  • Taramian A, Doosthoseini K, Mirshokraii SA, Faezipour M (2007) Particleboard manufacturing: An innovative way to recycle paper sludge. Waste Manage 27:1739–1746

    Article  CAS  Google Scholar 

  • Wang SY, Chen TY, Fann JD (1999) Comparison of internal bond strength and compression shear strength of wood-based materials. J  Wood Sci 45:396–401

    Google Scholar 

  • Xiaoqun MO (2003) Physical properties of medium density wheat straw particleboard using different adhesives. Dissertation, Kansas State University

  • Youngquist JA, Rowell RM (1986) Mechanical properties and dimensional stability of acetylated aspen flack board. Holz Roh- Werkst 44:453–457

    Article  CAS  Google Scholar 

  • Zheng Y, Pan Z, Zhang R, Jenkins BM, Blank S (2006) Properties of medium-density particleboard from saline Athel wood. Ind Crop Prod 23:318–320

    Article  CAS  Google Scholar 

  • Zhou X, Frazier CE, Ni J (2001) Double labeled isocyanate resins for the solid-state NMR detection of urethane linkages to wood. Int J Adhes Adhes 21:259–264

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research was supported by the Center of Excellence of Applied Management of Fast Growing Wood. The authors would like to thank Dr.  M.  Azadfallah for helping to correct this paper.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hamideh Abdolzadeh.

Additional information

Additional corresponding author e-mail address: h_abdolzadeh@ut.ac.ir

Rights and permissions

Reprints and permissions

About this article

Cite this article

Abdolzadeh, H., Doosthoseini, K., Karimi, A.N. et al. The effect of acetylated particle distribution and type of resin on physical and mechanical properties of poplar particleboard. Eur. J. Wood Prod. 69, 3–10 (2011). https://doi.org/10.1007/s00107-009-0390-5

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00107-009-0390-5

Keywords

Navigation