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Kinetics and Catalysis

, Volume 46, Issue 1, pp 43–46 | Cite as

Kinetics of the carbomethoxylation of methylacetylene-allene mixtures catalyzed by palladium complexes

  • G. A. Korneeva
  • E. M. Karas’kova
  • M. G. Makarov
  • E. V. Slivinskii
Article
  • 28 Downloads

Abstract

Pathways leading to the desired product and by-product (copolymer of allene and CO) were determined for the carbomethoxylation of allene—methylacetylene mixtures catalyzed by the PdCl2(Ph3P)2—HCl—ortho—phenanthroline system. Ratios for the rates of these transformations were found. Allene ⇄ methylacetylene isomerization under carbomethoxylation conditions was observed.

Keywords

Physical Chemistry Catalysis Palladium Ph3P Phenanthroline 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • G. A. Korneeva
    • 1
  • E. M. Karas’kova
    • 1
  • M. G. Makarov
    • 2
  • E. V. Slivinskii
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia
  2. 2.Mendeleev University of Chemical TechnologyMoscowRussia

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