Synthesis and thermal decomposition of haloalkoxy-sym-triazines 5. Thermal decomposition of 2-methoxy(methylthio)-4-[1,3-dichloropropoxy(3-chloro-1-propoxy)]-6-dimethylamino-sym-triazines
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2-Methoxy (methylthio)-4-(1, 3-dichloropropoxy)-and 2-methoxy (methylthio)-4-(3-chloro-1-propoxy)-6-dimethylamino-sym-triazines were synthesized and subjected to thermolysis, as a result of which chloromethyltetrahydrooxazolo-, N-2, 3-di-chloropropyl-sym-triazines and tetrahydrooxazino-and tetrahydrothiazino-sym-triazines, respectively, were obtained. The thermolysis of haloalkoxy-sym-triazines proceeds via a concerted mechanism.
KeywordsOrganic Chemistry Thermal Decomposition Thermolysis Methylthio Concerted Mechanism
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