Synthesis and thermal decomposition of haloalkoxy-sym-triazines 5. Thermal decomposition of 2-methoxy(methylthio)-4-[1,3-dichloropropoxy(3-chloro-1-propoxy)]-6-dimethylamino-sym-triazines
- 21 Downloads
2-Methoxy (methylthio)-4-(1, 3-dichloropropoxy)-and 2-methoxy (methylthio)-4-(3-chloro-1-propoxy)-6-dimethylamino-sym-triazines were synthesized and subjected to thermolysis, as a result of which chloromethyltetrahydrooxazolo-, N-2, 3-di-chloropropyl-sym-triazines and tetrahydrooxazino-and tetrahydrothiazino-sym-triazines, respectively, were obtained. The thermolysis of haloalkoxy-sym-triazines proceeds via a concerted mechanism.
KeywordsOrganic Chemistry Thermal Decomposition Thermolysis Methylthio Concerted Mechanism
Unable to display preview. Download preview PDF.
- 1.V. V. Dovlatyan and A. V. Dovlatyan, Khim. Geterotsikl. Soedin., No. 1, 124 (1979).Google Scholar
- 2.V. V. Dovlatyan, A. V. Dovlatyan, K. A. Éliazyan, and R. G. Mirzoyan, Khim. Geterotsikl. Soedin., No. 10, 1420 (1977).Google Scholar
- 3.V. V. Dovlatyan, K. A. Éliazyan, and A. V. Dovlatyan, Khim. Geterotsikl. Soedin., No. 7, 989 (1977).Google Scholar
- 4.K. Fukui and H. Fujimoto, Bull. Chem. Soc. Jpn.,39, 2116 (1956).Google Scholar