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Mineralogical and Physical Changes during Sintering of Plastic Red Clays from Sanaga Swampy Valley, Cameroon

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Interceram - International Ceramic Review

Abstract

The sintering behavior and mechanical properties of four alluvial clays sampled from the Sanaga River (sampling sites: Nanga-Eboko, Mbandjock, Batschenga, and Ebebda), central region of Cameroon were investigated. Specimens were shaped by cold pressing and fired between 850 and 1100°C. X-ray diffraction, energy-dispersive X-ray spectroscopy, and scanning electron microscopy were used to monitor microstructural modifications and thermal phase transformations. Linear shrinkage, density, open/closed porosity, and water absorption were used to assess the effects of firing cycle on the mechanical properties of the fired compacts. The results showed that between 850 and 1050°C the mineralogical phases are mainly quartz and feldspar. Mullite, spinel, and cristoballite appear at 1100°C together with viscous phases. The values of apparent density (2.62–2.76 g/cm3), open porosity, and flexural strength (3–30 MPa) of the brown compacts suggest the possible use of these clays for earthenware ceramics such as building bricks, roof and floor tiles.

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Nzeukou, N.A., Traina, K., Medjo, E.R. et al. Mineralogical and Physical Changes during Sintering of Plastic Red Clays from Sanaga Swampy Valley, Cameroon. Interceram. - Int. Ceram. Rev. 63, 186–192 (2014). https://doi.org/10.1007/BF03401056

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