Abstract
The techniques used in the United States for producing calcium metal are described. The methods and attempts to produce high-purity calcium from the crude calcium prepared by the current processes are discussed. A vaporization technique for the distillation of crude calcium is described in detail, and a fractional distillation technique for preparing special high-purity calcium is reported.
Similar content being viewed by others
References
H. E. Bakken: Purifying Calcium, US Patent 1,814,073 (July 14, 1931), assigned to American Magnesium Corp.
J. Herenguel: Chimie Industrie, April 1934, Special No. pp. 701–3.
G. D. Bagley: Chem. and Eng. News, vol. 22, p. 921.
A. F. Matthews: Calcium; Minerals Yearbook, US Bureau of Mines, 1941, p. 798.
P. P. Alexander: Metals and Alloys, vol. 9, p. 270.
H. A. Wilhelm. J. Chem. Ed., vol. 37, p. 56.
C. C. Loomis: Trans. Electrochem. Soc., vol. 89, p. 207.
H. A. Wilhelm: The Metal Thorium, American Society for Metals, Metals Park, Ohio, 1958, pp 78–103.
C. E. Nighman: Calcium; Minerals Yearbook, US Bureau of Mines, 1945, pp. 818–819.
A. N. Volsky N. V. Vialkina, N. P. Zereva, I. L. Kaltsman, and T. S. Posobilo: Proc. UN Intern. Conf. Peaceful Uses of Atomic Energy, 2nd Geneva, vol. 28, p. 170.
J. F. Smith, O. N. Carlson, and R. W. Vest: J. Electrochem., vol. 103, p. 409.
Josef Veprek-Siska: Chemicke Listy, vol. 56, p. 481.
G. Wehner: Freiberg. Forsch. B., vol. 17, p. 18.
A. S. Mikulinskii: Trudy Ural. Nauch.-Issledovatel Khim. Inst., 1957, No. 4, pp. 184–93 (see Chem. Abstr., vol. 54, p. 954f).
W. Biltz and W. Wagner: Z. anorg. chem., vol. 134, pp. 1–5.
C. L. Mantell and C. Hardy: Calcium Metallurgy and Technology, Reinhold Publishing Corp., New York, 1945.
W. J. McCreary: Journal of Metals, vol. 10, p. 615.
H. Brown and P. Woodberry: USAEC Report MHC-5, Jan. 1949.
J. E. Lee, Jr., and C. D. Susano: USAEC Report Y-347, Feb. 1949, SECRET.
Author information
Authors and Affiliations
Additional information
The work included in this paper was performed in the Ames Laboratory of the US Atomic Energy Commission.
Rights and permissions
About this article
Cite this article
Wilhelm, H.A., Carlson, O.N. Methods for producing high-purity calcium. JOM 16, 170–174 (1964). https://doi.org/10.1007/BF03378262
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03378262