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JOM

, Volume 8, Issue 10, pp 1474–1483 | Cite as

Sulfur Equilibria Between Gases and Slags Containing FeO

  • George R. St. Pierre
  • John Chipman
Transaction

Abstract

FeO slags with additions of CaO, SiO2, and MgO were equilibrated with atmospheres of SO2 containing additions of CO and O2. At low partial pressures of oxygen, sulfur is present as sulfide, and at higher pressures, as sulfate. At constant oxygen and sulfur pressures, sulfur absorption as sulfide is nearly independent of the ratio CaO/FeO, but is decreased by addition of SiO2 or MgO. The presence of CaO is necessary for absorption of sulfur as sulfate.

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Copyright information

© The Minerals, Metals & Materials Society 1956

Authors and Affiliations

  • George R. St. Pierre
    • 1
  • John Chipman
    • 2
  1. 1.Inland Steel Co.East ChicagoUSA
  2. 2.Massachusetts Institute of TechnologyCambridgeUSA

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