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Sulfur Equilibria Between Gases and Slags Containing FeO

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Abstract

FeO slags with additions of CaO, SiO2, and MgO were equilibrated with atmospheres of SO2 containing additions of CO and O2. At low partial pressures of oxygen, sulfur is present as sulfide, and at higher pressures, as sulfate. At constant oxygen and sulfur pressures, sulfur absorption as sulfide is nearly independent of the ratio CaO/FeO, but is decreased by addition of SiO2 or MgO. The presence of CaO is necessary for absorption of sulfur as sulfate.

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References

  1. J. H. Nead: AIME Trans., 1924, vol. 70, p. 176.

    Google Scholar 

  2. J. H. Whitely: Journal West Scotland Iron and Steel Inst., 1923, vol. 31, p. 42.

    Google Scholar 

  3. A. N. Diehl: AISI Year Book, 1926, p. 404.

    Google Scholar 

  4. C. H. Herty, A. R. Belzea, E. B. Burkart, and C. C. Miller: AIME Trans., 1925, vol. 71, p. 512.

    Google Scholar 

  5. W. Koch and K. Fink: Archiv für Eisenhuttenwesen, 1951, vol. 22 p 371

    Article  Google Scholar 

  6. R. W. Gurry and L. S. Darken: Journal ACS, 1950, vol. 72, p. 3906.

    Google Scholar 

  7. G. Derge and S. Marshall: Journal of Metals, 1951, vol. 3, p. 511.

    Google Scholar 

  8. F. D. Richardson and C. J. B. Fincham: Journal Iron and Steel Inst., London, 1954, vol. 178, p. 4.

    Google Scholar 

  9. F. D. Richardson: Discussions Faraday Soc., 1948, No, 4, p. 340.

    Google Scholar 

  10. F. D. Richardson and G. Withers: Journal Iron and Steel Inst., London, 1950, vol. 165, p. 66.

    Google Scholar 

  11. L. S. Darken and R. W. Gurry: Journal ACS, 1945, vol. 67, p. 798; 1946, vol. 68, p. 798.

    Google Scholar 

  12. H. R. Larson and J. Chipman: AIME Trans., 1953, vol. 197, p. 1089; Journal of Metals, September 1953.

    Google Scholar 

  13. G. St. Pierre and J. Chipman: Journal ACS, 1954, vol. 76, p. 4787.

    Google Scholar 

  14. J. A. Cordier and J. Chipman: AIME Trans., 1955, vol. 203, p. 905; Journal of Metals, August 1955.

    Google Scholar 

  15. Basic Open Hearth Steelmaking, AIME, New York, 1951.

  16. P. Bardenheur and W. Geller: Mitt. Kaiser-Wilhelm Inst, für Eisenforschung, 1934, vol. 16, p. 77.

    Google Scholar 

  17. T. B. King: The Physical Chemistry of Melts, Inst. of Mining and Metallurgy, London, 1953.

    Google Scholar 

  18. F. Harders, H. Grewe, and W. Oelsen: Stahl und Eisen, 1951, vol. 71, p. 973.

    Google Scholar 

  19. K. L. Fetters and J. Chipman: AIME Trans., 1940, vol. 140, p. 170.

    Google Scholar 

  20. N. J. Grant and J. Chipman: AIME Trans., 1946, vol. 167, p. 134.

    Google Scholar 

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Authors and Affiliations

  1. Inland Steel Co., East Chicago, Ind., USA

    George R. St. Pierre (Junior Member AIME, Supervising Research Metallurgist)

  2. Massachusetts Institute of Technology, Cambridge, Mass., USA

    John Chipman (Member AIME, Professor of Metallurgy)

Authors
  1. George R. St. Pierre
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  2. John Chipman
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Additional information

TP 4281C. Manuscript, Nov. 29, 1955. Chicago Meeting, February 1955.

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St. Pierre, G.R., Chipman, J. Sulfur Equilibria Between Gases and Slags Containing FeO. JOM 8, 1474–1483 (1956). https://doi.org/10.1007/BF03377850

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  • DOI: https://doi.org/10.1007/BF03377850

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