, Volume 32, Issue 4, pp 16–19 | Cite as

Developments in Physical Chemistry and Basic Principles of Extractive Metallurgy in 1979

  • H. Y. Sohn
Technical Article


Extractive Metallurgy Zinc Chloride Sulfide Capacity Molybdenum Trioxide Benzoylacetone 
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  1. 1.
    H.Y. Sohn and M.E. Wadsworth, eds., Rate Processes of Extractive Metallurgy, Plenum, New York, 1979.Google Scholar
  2. 2.
    H.Y. Sohn and R.P. Goel, “Principles of Roasting,” Mineral Sci. Eng., 11 (1979) pp. 137–153.Google Scholar
  3. 3.
    Yu. B. Makarov, L.I. Blokhina, G.N. Zviadadze, and I.N. Karyazina, “Reduction of Nickel and Cobalt by Hydrogen from Complex Oxide Systems,” Russ. Metallurgy, No. 1 (1978) pp. 31–35.Google Scholar
  4. 4.
    A.S. Grintsov, V.V. Skorokhod, I.V. Uvarova, and Yu. M. Solonin, “Comparison of Various Catalysts in the Hydrogen Reduction of Molybdenum Trioxide,” Russ. Metallurgy, No. 2 (1978) pp. 25–29.Google Scholar
  5. 5.
    D.R. Swinbourne and B. Harris, “Kinetics of Copper (I) Sulphide Chlorination,” Trans. Inst. Mining Met., 88, (1979) pp. C93–C98.Google Scholar
  6. 6.
    Y.K. Rao, “Mechanisms and the Intrinsic Rates of Reduction of Metallic Oxides,” Met. Trans., 10B (1979) pp. 243–255.Google Scholar
  7. 7.
    H.Y. Sohn, “The Law of Additive Reaction Times in Fluid-Solid Reactions,” Met. Trans. 9B (1978) pp. 89–96.Google Scholar
  8. 8.
    Y.K. Rao, S.K. El-Rahaiby, and M.M. Al-Kahtany, “Discussion of the Law of Additive Reaction Times in Fluid-Solid Reactions,” Met. Trans., 10B (1979) pp. 295–296.Google Scholar
  9. 9.
    H.Y. Sohn, “Discussion of ‘the Law of Additive Reaction Times in Fluid-Solid Reactions’ — Author’s Reply,” Met. Trans., 10B (1979) pp. 296–297.Google Scholar
  10. 10.
    H.Y. Sohn and R.L. Braun, “Simultaneous Fluid-Solid Reactions in Porous Solids: Reactions Between One Solid and Two Fluid Reactants,” Chem. Eng. Sci., in press.Google Scholar
  11. 11.
    H.Y. Sohn and H.-J. Sohn, “The Effect of Bulk Flow Due to Volume Change in the Gas Phase on Gas-Solid Reactions,” Ind. Eng. Chem. Process Des. Dev., in press.Google Scholar
  12. 12.
    W.J. Rankin, “Reduction of Chromite by Graphite and Carbon Monoxide,” Trans. Inst. Mining Met., 88 (1979) pp. C107–C113.Google Scholar
  13. 13.
    A.G. Vodop’yanov, B.G. Zlokazov, G.N. Kozhevnikov, and L.A. Ovchinnikova, “The Mechanism of the Reduction of Silica by Carbon,” Russ. Metallurgy, No. 2 (1978) pp. 30–36.Google Scholar
  14. 14.
    A.G. Vodop’yanov, G.N. Kozhevnikov, and R.G. Zakharov, “Reduction of Alumina with Carbon,” Russ. Metallurgy, No. 3 (1978) pp. 10–13.Google Scholar
  15. 15.
    R. Padilla and H.Y. Sohn, “The Reduction of Stannic Oxide with Carbon,” Met. Trans., 10B (1979) pp. 109–115.CrossRefGoogle Scholar
  16. 16.
    L. Gourtsoyannis and W.G. Davenport, “Condensation of Zinc Vapour from Zinc Smelting Gases,” Trans. Inst. Mining Met., 88 (1979) pp. C175–C181.Google Scholar
  17. 17.
    Y. Fukunaka and J.M. Toguri, “The Oxidation of Liquid Ni3S2”, Met. Trans. 10B (1979) pp. 191–201.CrossRefGoogle Scholar
  18. 18.
    M.M. Vetyukov, Yu. V. Borisoglebskii, and N.G. Nerobeeva, “Kinetics of Reaction Between Aluminum Dissolved in a Cryolite-Alumina Melt and Anode Gases,” Soviet J. Non-Ferrous Metals, 17(12)(1976) pp. 30–33.Google Scholar
  19. 19.
    J.A. Clarke and D.J. Fray, “Oxidation of Zinc Vapour by Hydrogen — Water Vapour Mixtures,” Trans. Inst. Mining Met., 88 (1979) pp. C161–C166.Google Scholar
  20. 20.
    P.J. Meschter and H.J. Grabke, “Kinetics of the Water-Gas Shift Reaction on an ‘FeO’ Surface,” Met. Trans. 10B (1979) pp. 323–329.Google Scholar
  21. 21.
    J.A. Megy and H. Freund, “The Separation of Zirconium and Hafnium in a Molten Salt-Molten Zinc System,” Met. Trans. 10B (1979) pp. 413–421.CrossRefGoogle Scholar
  22. 22.
    A. Yazawa, “Thermodynamic Evaluations of Extractive Metallurgical Processes,” Met. Trans. 10B, (1979) pp. 307–321.CrossRefGoogle Scholar
  23. 23.
    S.R. Shatynski, “The Thermochemistry of Transition Metal Carbides,” Oxidation of Metals, 13 (1979) pp. 105–118.CrossRefGoogle Scholar
  24. 24.
    F.J. Tavera and W.G. Davenport, “Equilibriations of Copper Matte and Fayalite Slag under Controlled Partial Pressures of SO,,” Met. Trans. 10B (1979) pp. 237–241.Google Scholar
  25. 25.R.C.
    Sharma and Y.A. Chang, “Thermodynamics and Phase Relationships of Transition Metal-Sulfur Systems: Part III. Thermodynamic Properties of the Fe-S Liquid Phase and the Calculation of the Fe-S Phase Diagram,” Met. Trans. 10B (1979) pp. 103–108.CrossRefGoogle Scholar
  26. 26.
    A. Bronson and G.R.St. Pierre, “Determination of Sulfide Capacities of CaO-SiO2 Slags Containing CaF2 and B2O3 by an Encapsulation Method,” Met. Trans. 10B (1979) pp. 375–380.CrossRefGoogle Scholar
  27. 27.
    K.S. Song and D.R. Gaskell, “The Free Energies of Mixing of Melts in the System 2FeO·SiO2-2MnO·SiO2 and 2.33 FeO·TiO2-2.33 MnO·TiO2,” Met. Trans. 10B (1979) pp. 15–20.Google Scholar
  28. 28.
    G.J.W. Kor, “Equilibria Between Liquid Mn-Si Alloys and MnO-SiO2-CaO-MgO Slags,” Met. Trans., 10B (1979) pp. 367–374.Google Scholar
  29. 29.
    C. Borgianni and P. Granati, “Montecarlo Calculations of Ionic Structure in Silicate and Alumino-Silicate Melts,” Met. Trans., 10B (1979) pp. 21–25.CrossRefGoogle Scholar
  30. 30.
    V.S. Sibanda and E.H. Baker, “Thermodynamic Studies of Dilute Solutions of Bismuth in Copper at 1100°C,” Trans. Inst. Mining Met., 88 (1979) pp. C129–C130.Google Scholar
  31. 31.
    E.H. Baker, “Thermodynamic Properties and Phase Equilibria of Cadmium-Aluminium Alloys in Temperature Range 900–1100°C,” Trans. Inst. Mining Met., 87, (1978) pp. C278–283.Google Scholar
  32. 32.
    D.G. Jones and D.H. Philipp, “Arsenic Activity in Copper at 1100°C,” Trans. Inst. Mining Met., 88 (1979) pp. C7–C10.Google Scholar
  33. 33.
    Y. A. Chang and D. C. Hu, “On the Gibbs Energy Interaction Parameters of Oxygen and Nitrogen in Liquid Alloys,” Met. Trans., 10B (1979) pp. 43–48.CrossRefGoogle Scholar
  34. 34.
    K. Grjotheim and J.B. See, “The Hall-Héroult Process and Alternative Processes for the Manufacture of Metallic Aluminium,” Mineral Sci. Eng. 11 (1979) pp. 80–98.Google Scholar
  35. 35.
    P.B. Munoz, J.D. Miller, and M.E. Wadsworth, “Rate Mechanism for the Acid Ferric Sulfate Leaching of Chalcopyrite,” Met. Trans., 10B (1979) pp. 149–158.Google Scholar
  36. 36.
    F. Habashi and T. Toor, “Aqueous Oxidation of Chalcopyrite in Hydrochloric Acid,” Met. Trans., 10B, (1979) pp. 49–56.CrossRefGoogle Scholar
  37. 37.
    J.B. Hiskey, “Kinetics of Uranium Dioxide Dissolution in Ammonium Carbonate,” Trans. Inst. Mining Met., 88, (1979) pp. C145–C152.Google Scholar
  38. 38.
    J.J. Byerley, G.L. Rempel, and G.F. Garrido, “Copper Catalysed Leaching of Magnetite in Aqueous Sulfur Dioxide,” Hydrometallurgy, 4 (1979) pp. 317–336.CrossRefGoogle Scholar
  39. 39.
    J.C. Merchuk, R. Shai, and D. Wolf, “Experimental Study of Copper Extraction with LIX-64N by Means of Motionless Mixers,” Ind. Eng. Chem. Process Des. Dev., 19 (1980) pp. 91–97.CrossRefGoogle Scholar
  40. 40.
    K. Inoue, H. Okubo, and F. Nakashio, “Extraction Kinetics of Copper with Benzoylacetone During Drop Formation,” J. Chem. Eng. Japan, 12 (1979) pp. 19–23.CrossRefGoogle Scholar
  41. 41.
    K. Inoue, T. Tsuji, and I. Nakamori, “Extractive Kinetics of Zinc Chloride with Long-Chain Alkylamine,” J. Chem. Eng. Japan, 12 (1979) pp. 375–362.Google Scholar
  42. 42.
    K. Kondo, K. Kita, I. Koida, J. Irie, and F. Nakashio, “Extraction of Copper with Liquid Surfactant Membranes Containing Benzoylacetone,” J. Chem. Eng. Japan, 12 (1979) pp. 203–209.CrossRefGoogle Scholar
  43. 43.
    E.H. Cho and C.H. Pitt, “Kinetics and Thermodynamics of Silver Cyanide Adsorption on Activated Charcoal,” Met. Trans., 10B (1979) pp. 165–169.Google Scholar
  44. 44.
    E.H. Cho, S.N. Dixon, and C.H. Pitt, “The Kinetics of Gold Cyanide Adsorption on Activated Charcoal,” Met. Trans., 10B (1979) pp. 185–189.Google Scholar
  45. 45.
    W. Kunda and R. Hitesman, “The Reduction of Cobalt from Its Aqueous Ammine Ammonium Sulphate System Using Hydrogen Under Pressure,” Hydrometallurgy, 4 (1979) pp. 347–375.CrossRefGoogle Scholar
  46. 46.
    K. Osseo-Asare and T.H. Brown, “A Numerical Method for Computing Hydrometallurgical Activity-Activity Diagrams,” Hydrometallurgy, 4 (1979) pp. 217–232.CrossRefGoogle Scholar
  47. 47.
    P.B. Linkson, B.D. Phillips, and C.D. Rowles, “Computer Methods for the Generation of Eh-pH Diagrams,” Mineral Sci. Eng., 11 (1979) pp. 65–79.Google Scholar
  48. 48.
    I.L. Jenkins, “Solvent Extraction Chemistry in the Atomic Energy Industry — A Review,” Hydrometallurgy, 4 (1979) pp. 1–20.CrossRefGoogle Scholar
  49. 49.
    I.L. Jenkins, “Ion Exchange in the Atomic Energy Industry with Particular Reference to Actinide and Fission Product Separation — A Review,” Hydrometallurgy, 5 (1979) pp. 1–13.CrossRefGoogle Scholar
  50. 50.
    A.J. Van der Zeeuw, “Metals Extraction with Carboxylic Acids I. Composition of Complexes with Nickel, Cobalt (II) and Iron (III),” Hydrometallurgy, 4 (1979) pp. 21–37.CrossRefGoogle Scholar
  51. 51.
    A.J. Van der Zeeuw, “Metals Extraction with Carboxylic Acids II. Effect of Temperature on the Extraction of Cu, Ni, Co (II), Zn, Fe (III) and Co (III),” Hydrometallurgy, 4 (1979) pp. 39–50.CrossRefGoogle Scholar
  52. 52.
    K. Inoue, T. Tsuji, and I. Nakamori, “Extraction Equilibrium of Zinc Chloride with Long-Chain Alkylamine,” J. Chem. Eng. Japan, 12 (1979) pp. 353–357.CrossRefGoogle Scholar
  53. 53.
    E. Hogfeldt and J. Zelinka, “The Extraction of Mercury (II) from Concentrated HBr solutions by Benzene. A Comparison of Various Representations of Single-Ion Activity Coefficients in Concentrated Aqueous Solutions,” Hydrometallurgy, 4 (1979) pp. 337–346.CrossRefGoogle Scholar
  54. 54.
    R.J. Whewell and M.A. Hughes, “The Modelling of Equilibrium Data for the Liquid-Liquid Extraction of Metals Part III. An Improved Chemical Model for the Copper/LIX 64N System,” Hydrometallurgy, 4 (1979) pp. 109–124.CrossRefGoogle Scholar
  55. 55.
    R.J. Whewell, M.A. Hughes, and P.D. Middlebrook, “The Modelling of Equilibrium Data for the Liquid-Liquid Extraction of Metals Part IV. The Effect of the Diluent on the Copper/LIX 64N System,” Hydrometallurgy, 4 (1979) pp. 125–133.CrossRefGoogle Scholar
  56. 56.
    C.A. Fleming and A.J. Monhemius, “On the Extraction of Various Base Metal Chlorides for Polar Organic Solvents into Cation and Anion Exchange Resins,” Hydrometallurgy, 4 (1979) pp. 159–167.CrossRefGoogle Scholar
  57. 57.
    E.H. Cho and C.H. Pitt, “The Adsorption of Silver Cyanide on Activated Charcoal,” Met. Trans., 10B (1979) pp. 159–164.Google Scholar
  58. 58.
    I.Z. Pevzner, V. Ya Tumarinson, and Ya. B. Rozen, “A Study of Some Sections in the Na2O-Al2O3-CO2-H2O System at 80°C,” Soviet J. Non-Ferrous Metals, 17(10) (1976) pp. 45–46.Google Scholar
  59. 59.
    V.A. Ettel, M.A. Mosiou, and E.A. Devuyst, “A Novel Oxidant for Nickel Hydrometallurgy,” Hydrometallurgy, 4 (1979) pp. 247–257.CrossRefGoogle Scholar
  60. 60.
    A.L. Lux and M.C. Flemings, “Refining by Fractional Solidification,” Met. Trans., 10B (1979) pp. 71–78.Google Scholar
  61. 61.
    A.L. Lux and M.C. Flemings, “Refining by Fractional Melting,” Met. Trans., 10B (1979) pp. 79–84.Google Scholar
  62. 62.
    J. Szekely, A.H. Dilawari, and R. Metz, “The Mathematical and Physical Modeling of Turbulent Recirculating Flows,” Met. Trans., 10B (1979) pp. 33–41.CrossRefGoogle Scholar
  63. 63.
    M. Salcudean and R.I.L. Guthrie, “A Three Dimensional Representation of Fluid Flow Induced Ladles or Holding Vessies by the Action of Liquid Metal Jets,” Met. Trans., 10B (1979) pp. 423–428.CrossRefGoogle Scholar
  64. 64.
    J. Szekely and Y. Kajiwara, “The Interaction Between Gas and Liquid Flow in a Simulated Blast Furnace: A Preliminary Investigation,” Met. Trans., 10B (1979) pp. 447–450.CrossRefGoogle Scholar
  65. 65.
    G.H. Kaiura and J.M. Toguri, “Densities of the Molten FeS, FeS-Cu2S and Fe-S-O Systems — Utilizing a Bottom-Balance Archimedean Technique,” Can. Met. Quart., 18 (1979) pp. 155–164.CrossRefGoogle Scholar
  66. 66.
    B.V. Patrov, V.M. Mozhaev, M.V. Bushunova, E.B. Klebanov, and L.V. Vorozhtsova,” Investigation of the Molar Volume, Surface Tension, and Interfacial Tension in the LiF-NaF-BaF2 System for the Electroslag Remelting of Silver Alloy,” Soviet Non-Ferrous Metals Res., 5 (1977) pp. 226–228.Google Scholar
  67. 67.
    Yu. V. Borisoglebskii, M.M. Vetyukov, and D.K. Tuen, “Density of Melts in the NaCl-KCl-AlCl3 Ternary System,” Soviet Non-Ferrous Metals Res., 6 (1978) pp. 113–115.Google Scholar
  68. 68.
    Y. Sato, K.-I. Kobayashi, and T. Ejima, “Density of LiCl-NaCl-AlCl3 Ternary Melt,” J. Jap. Inst. Metals, 43 (1979) pp. 97–104.Google Scholar
  69. 69.
    L. Segers, A. Fontana, and R. Winand, “Electrical Conductivity, Viscosity and Density of Molten Slags of the System CaO-SiO2-MnO,” Trans. Inst. Mining Met., 88 (1979) pp. C53–C56.Google Scholar
  70. 70.
    G.A. Toporishchev and L.B. Bruk, “Viscosity and Polymerization in Silicate Melts,” Russ. Metallurgy, No. 6 (1977) pp. 52–56Google Scholar
  71. 71.
    Y. Ouchi and E. Kato, “The Effects of Alkaline Earth Metal Oxides, Nickel Oxide, and Cobalt Oxide on the Viscosity of Lead-Metasilicate Melts,” J. Jap. Inst. Metals, 43 (1979) pp. 625–633.Google Scholar
  72. 72.
    T. Ejima, K. Shimakage, T. Yoko, K. Nakashima, and K. Takei, “Viscosity of Molten ZnCl2-MCl2 (M = Cd, Pb, Sn, Ba) Binary Systems,” J. Jap. Inst. Metals, 43 (1979) pp. 577–583.Google Scholar
  73. 73.
    H. Keller, K. Schwedtfeger, and K. Hennesen, “Trace Diffusivity of Ca45 and Electrical Conductivity in CaO-SiO2 Melts,” Met. Trans., 10B, (1979) pp. 67–70.CrossRefGoogle Scholar
  74. 74.
    V.P. Chesnokov, B.V. Linchevskiy, “Nitrogen Diffusion in Liquid Nickel and Its Alloys with Chromium, Molybdenum and Tungsten,” Russ. Metallurgy, No. 5 (1977) pp. 46–48.Google Scholar
  75. 75.
    S. Sato and O.J. Kleppa, “Thermochemistry of Liquid Alloys of Transition Metals: I. The Systems Mn-Cu and Mn-Su,” Met. Trans., 10B (1979) pp. 63–66.CrossRefGoogle Scholar
  76. 76.
    I.N. Zedina and S.E. Vaysburd, “Enthalpy of FeS-Ni3S2-Cu2S Melts,” Russ. Metallurgy, No. 3 (1978) pp. 46–48.Google Scholar
  77. 77.
    F.R.A. Jorgensen and F.J. Moyle, “Solid-Vapour Equilibria in the FeCl3-AlCl3-Cl2 System,” Proc. Australas. Inst. Mining Met., No. 269 (1979) pp. 29–35.Google Scholar

Copyright information

© The Minerals, Metals & Materials Society 1980

Authors and Affiliations

  • H. Y. Sohn
    • 1
  1. 1.University of UtahSalt Lake City

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