Skip to main content
Log in

Differential pulse Polarographic study of simple and mixed ligand complexes of cadmium(II) with some dicarboxylate anions and imidazole

  • Full papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The composition and stability of binary and ternary complexes of Cd(II) with phthalate and adipate anions as primary ligands and imidazole as a secondary ligand have been investigated using differential pulse d.p. polarography. The formation constants of simple mixed species have been calculated, as well as the mixing and stabilization constants. The overall formation constants of the mixed species are correlated and discussed in terms of statistical consideration and charge neutralization. The equilibria between the various mixed-ligand species in solution and their equilibrium are also given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. F. Flick, H. F. Kraybill and J. M. Dimitroff, Environ. Res., 4, 71 (1971).

    Article  CAS  Google Scholar 

  2. P. E. Caroll, J. Amer. Med. Assoc., 198, 267 (1966).

    Google Scholar 

  3. S. A. Gunn, T. C. Gould and W. A. D. Anderson, Bull, Pathol., 8, 42 (1967), 8, 68 (1967).

    Google Scholar 

  4. H. S. Schroeder and J. J. Balassa, Am. J. Physiol., 209, 433 (1965).

    CAS  Google Scholar 

  5. S. A. Dressing, R. P. Mass and C. M. Weiss, Bull. Environ, Contan. Toxicol., 28, 172 (1982).

    Article  CAS  Google Scholar 

  6. J. A. Titus and R. M. Pfister, Bull. Environ. Contam. Toxicol, 28, 703 (1982).

    Article  Google Scholar 

  7. Yen-Wan Hung, Bull. Environ. Contam. Toxicol, 28, 546 (1982).

    Article  CAS  Google Scholar 

  8. J. M. White, E. Doody and N. C. Li, J. Am. Chem. Soc., 76, 6219 (1954).

    Article  Google Scholar 

  9. D. R. Crow, J. Electroanal. Chem. 16, 137 (1968).

    Article  CAS  Google Scholar 

  10. M. Shivhare and M. Singh, Indian J. Chem., 21 A, 246 (1982).

    Google Scholar 

  11. C. Tanford, J. Am. Chem. Soc., 74, 211 (1952).

    Article  CAS  Google Scholar 

  12. I. Gramberg and S. Sjoberg, Acta Chem. Scand., 135, 193 (1981).

    Article  Google Scholar 

  13. N. Saha and H. Sigel, J. Am. Chem. Soc., 104, 4100, (1982).

    Article  CAS  Google Scholar 

  14. C. Tanford, and M. L. Wagner, J. Am. Chem. Soc., 75, 434 (1953).

    Article  CAS  Google Scholar 

  15. J. M. Dillard and K. W. Hanck, Anal. Chem., 48, 216 (1976).

    Article  Google Scholar 

  16. H. M. Killa, M. G. Abd El-Wahed and H.A. Dessouki, Polyhedron, 4, 1219 (1985).

    Article  CAS  Google Scholar 

  17. H. M. Killa, J. Chem. Soc., Faraday Trans. I., 81, 2659 (1985).

    Article  CAS  Google Scholar 

  18. R. G. Bidkar, D. G. Dhuley and R. A. Bhobe, Indian J. Chem., 15A, 63 (1977).

    CAS  Google Scholar 

  19. J. M. Gaur, S. C. Baghel and R. S. Sharma, J. Indian Chem. Soc. LVI, 255 (1979).

    Google Scholar 

  20. I. Leden, Z. Phys. Chem., 188A, 160 (1941).

    Google Scholar 

  21. R. Sundaresan and A. K. Sundaram, Proc. Ind. Acad., 79 A, 161 (1974).

    Google Scholar 

  22. S. L. Jain, J. Kishan and R. C. Kapoor, Indian J. Chem., 18A, 133 (1979).

    CAS  Google Scholar 

  23. A. Gergely, I. Nagyapal and S. Markas, J. Inorg. Nucl. Chem., 37, 551 (1975).

    Article  CAS  Google Scholar 

  24. V. S. Sharma and J. Schubett, J. Chem. Edu., 46, 506 (1969).

    Article  CAS  Google Scholar 

  25. D. D. Perrin and V. S. Sharma, J. Chem. Soc., A, 2060 (1969).

    Google Scholar 

  26. J. I. Waters and Dewitt, J. Am. Chem. Soc., 82, 1333 (1960).

    Article  Google Scholar 

  27. J.J. Tedesco and J. Martinez, J. Inorg. Nucl. Chem., 42, 95 (1980)).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Killa, H.M. Differential pulse Polarographic study of simple and mixed ligand complexes of cadmium(II) with some dicarboxylate anions and imidazole. Transition Met Chem 17, 55–58 (1992). https://doi.org/10.1007/BF03325416

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03325416

Keywords

Navigation