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Modeling Of Hydrogen Distributionin A Duplex Stainless Steel

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Abstract

Quite a number of models for hydrogen distribution in steels and welds have been developed in the past 20 years. They reach from simple analytical models to more complex two and three dimensional finite element simulations. So far, these models have been used to simulate hydrogen distribution in homogeneous microstructure. This paper contributes to numerical simulation of hydrogen distribution in heterogeneous microstructure, e.g. in a duplex stainless steel microstructure consisting of two phase fractions. Under appropriate conditions, such as cathodic protection, it is possible that hydrogen is absorbed leading to material embrittlement and possibly initiating hydrogen assisted cracking. In order to avoid hydrogen assisted cracking in duplex stainless steels, it is of great interest to know more about the diffusion behavior of the ferrite and austenite phase. A numerical model has been developed that operates on the mesoscale and enables simulation of hydrogen transport in the various phases of a metallic material.

As a first application of this model, hydrogen distribution in a duplex stainless steel 1.4462, consisting of approximately equal portions of ferrite and austenite, was simulated using the finite element program package ANSYS. The results reflect the dependency of hydrogen distribution on the microstructural alignment of the ferrite and austenite phase fractions. Crack-critical areas can thus be identified, provided the critical strain-hydrogen combination is known for the respective microstructural phase.

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References

  1. Alvarez-Armas I.:Duplex Stainless Steels: Brief History and Some Recent Alloys. Recent Patents on Mechanical Engineering, Vol. 1 (2008), No. 1, pp. 51–57.

    Google Scholar 

  2. Lo K.H., Shek C.H. and Lai J.K.L.: Recent developments in stainless steels. Materials Science and Engineering R, Vol. 65 (2009), No. 4–6, pp. 39–104.

    Article  Google Scholar 

  3. Olden V., Thaulow C., Johnsen R., Østby E. and Berstad T.: Influence of hydrogen from cathodic protection on the fracture susceptibility of 25%Cr duplex stainless steel — Constant load SENT testing and FE-modelling using hydrogen influenced cohesive zone elements. Engineering Fracture Mechanics, Vol. 76 (2009), No. 7 pp. 827–844.

    Article  Google Scholar 

  4. Oltra R. and Bouillot C.: Experimental investigation of the role of hydrogen in stress corrosion cracking of duplex stainless steel. In: Hydrogen-transport and cracking in metals. A. Turnbull (ed.), 1994, pp. 17-27.

  5. Huang J.-H. and Altstetter C.J.: Cracking of Duplex Stainless Steel Due to Dissolved Hydrogen. Metallurgical and Materials Transaction A, Vol. 26 (1995), No. 5, pp. 1079–1085.

    Article  Google Scholar 

  6. Kikuchi Y., Lundin C. and Khan K.: Measurement of diffusible hydrogen content and hydrogen effects on the cracking potential of duplex stainless steel weldments (Part 1). Transactions Of JWRI, Vol. 20 (1991), No. 2, pp. 95–104.

    CAS  Google Scholar 

  7. Boellinghaus Th., Hoffmeister H. and Dangeleit A.: A scatterband for hydrogen diffusion coefficients in micro-alloyed and low carbon structural steels. Welding In the World, Vol. 35 (1995), No. 2, pp. 83–96.

    CAS  Google Scholar 

  8. Boellinghaus Th., Hoffmeister H. and Middel C.: Scatterbands for hydrogen diffusion coefficients in steel having a ferritic or martensitic microstructure and steels having an austenitic microstructure at room temperature. Welding In the World, Vol. 37 (1996), No. 1, pp. 16–23.

    CAS  Google Scholar 

  9. Unger D.J. and Aifantis E.C.: On the theory of stress-assisted diffusion II. Acta Mechanica, Vol. 47 (1983), No. 1–2, pp. 117–151.

    Article  Google Scholar 

  10. Boellinghaus Th. and Hoffmeister H.: Numerical Model for Hydrogen-Assisted Cracking. Corrosion, Vol. 56 (2000), No. 6, pp. 611–622.

    Article  CAS  Google Scholar 

  11. Boellinghaus Th. and Hoffmeister H.: Finite Element Calculations of Pre- and Post-Heating Procedures for Sufficient Hydrogen Removal in Butt Joints. In: Mathematical Modelling of Weld Phenomena 3, H. Cerjak (ed.), 1997, pp. 726-756.

  12. Turnbull A.: Modelling of Environment Assisted Cracking. Corrosion Science, Vol. 34 (1993), No. 6, pp. 921–960.

    Article  CAS  Google Scholar 

  13. Maroef I., Olson D.L., Eberhart M. and Edwards G.R.: Hydrogen trapping in ferritic steel weld metal. International Materials Reviews, Vol. 47 (2002), No. 4, pp. 191–223.

    Article  CAS  Google Scholar 

  14. Brauser S., Kannengießer Th.: Hydrogen absorption of different welded duplex steels. International Journal of Hydrogen Energy, Vol. 35 (2010), No. 9, pp. 4368–4374.

    Article  CAS  Google Scholar 

  15. Beyer K., Brauser S. and Kannengießer Th.:Trägergas-Heißextraktion zur Analyse der Wasserstoffeinlagerung und -effusion in Duplexgefügen. (Analysis of the hydrogen-occlusion and effusion in duplex microstructures using carrier gas hot extraction). In: Tagung Werkstoffprüfung (Conference on Materials Testing), M. Pohl (ed.), December 2010, Neu-Ulm.

  16. ThyssenKrupp: Nirosta® 4462 (uns s 31803/uns s 32205) ferritic-austenitic duplex steel with high strength and corrosion resistance, 2009, Online: http://www.thyssenkrupp-nirosta.de/fileadmin/media/PDF/4462_en.pdf, [last status: 19.02.2011].

  17. Viyanit E.: Numerical Simulation of Hydrogen Assisted Cracking in Supermartensitic Stainless Steel Welds. Helmut-Schmidt-University/University of the Federal Armed Forces Hamburg, PhD.-Thesis, 2005, 196 pages.

  18. P. Wongpanya, Th. Böllinghaus, G. Lothongkum, H. Hoffmeister: Numerical Modelling of Cold Crack Initiation and Propagation in S 1100 QL Steel Root Welds, Welding in the World, Vol. 53 (2009), No. 3/4, pp. R34–R43.

    Article  CAS  Google Scholar 

  19. Olden V., Thaulow C., Johnsen R., Østby E. and Berstad T.: Application of hydrogen influenced cohesive laws in the prediction of hydrogen induced stress cracking in 25%Cr duplex stainless steel. Engineering Fracture Mechanics, Vol. 75 (2008), No. 8, pp. 2333–2351.

    Article  Google Scholar 

  20. Turnbull A., Hutchings R.B.: Analysis of hydrogen atom transport in a two-phase alloy. Materials Science and Engineering A, Vol. 177 (1994), No. 1–2, pp. 161–171.

    Article  CAS  Google Scholar 

  21. Owczarek E. and Zakroczymski T.: Hydrogen transport in a duplex stainless steel. Acta Materialia, Vol. 48 (2000), No. 12, pp. 3059–3070.

    Article  CAS  Google Scholar 

  22. Dabah E., Lisitsyn V. and Eliezer D.: Performance of hydrogen trapping and phase transformation in hydrogenated duplex stainless steels. Materials Science and Engineering A, Vol. 527 (2010), No. 18–19, pp. 4851–4857.

    Article  Google Scholar 

  23. Ansys Inc.: Element reference, 2009, Online: http://www1.ansys.com/customer/content/documentation/120/ans_elem.pdf, [last status: 19.02.2011].

  24. Menezes A., Abreu H., Kundu S., Bhadeshia H.K.D.H. and Kelly P.M.: Crystallography of Widmanstätten austenite in duplex stainless steel weld metal. Science and Technology of Welding and Joining, Vol. 14 (2009), No. 1, pp. 4–10.

    Article  CAS  Google Scholar 

  25. Chen S.S., Wu T.I. and Wu J.K.: Effects of deformation on hydrogen degradation in a duplex stainless steel. Journal Of Materials Science, Vol. 39 (2004), No. 1, pp. 67–71.

    Article  CAS  Google Scholar 

  26. Kaçar R.: Effect of solidification mode and morphology of microstructure on the hydrogen content of duplex stainless steel weld metal. Materials & Design, Vol. 25 (2004), No. 1, pp. 1–9.

    Article  Google Scholar 

  27. Olden V., Thaulow C. and Johnsen R.: Modelling of hydrogen diffusion and hydrogen induced cracking in supermartensitic and duplex stainless steels. Materials and Design, Vol. 29 (2008), No. 10, pp. 1934–1948.

    Article  CAS  Google Scholar 

  28. Langley R. A.: Hydrogen trapping, diffusion and recombination in austenitic stainless steels. Journal of Nuclear Materials, Vol. 128-129 (1984), pp. 622–628.

    Article  CAS  Google Scholar 

  29. Mehrer H.: Diffusion in Solids, Fundamentals, Methods,Materials, Diffusion-Controlled Processes. Springer-Verlag Berlin Heidelberg, 2007, ISBN 978-3-540-71486-6, pp. 547–581.

    Google Scholar 

  30. Yoshikazu H. and Shu W.M.: Iron (Ruthenium and Osmium)-Hydrogen Systems. Solid State Phenomena, Vol. 73-75 (2000), pp. 65–114.

    Article  Google Scholar 

  31. Brass A.M. and Chene J.: Influence of deformation on the hydrogen behavior in iron and nickel base alloys: a review of experimental data. Metallurgical and Materials Transaction A, Vol. 242 (1998), No. 1–2, pp. 210–221.

    Google Scholar 

  32. Głowacka A., Woniak M.J, Nolze G. and Witnicki W.A.: Hydrogen induced phase transformations in austenitic-ferritic steel. Solid State Phenomena, Vol. 112 (2006), pp. 133–140.

    Article  Google Scholar 

  33. Yang Q., Qiao L.J., Chiovelli S. and Luo J.L.: Critical hydrogen charging conditions for martensite transformation and surface cracking in type 304 stainless steels. Scripta Materialia, Vol. 40 (1999), No. 11, pp. 1209–1214.

    Article  CAS  Google Scholar 

  34. Rozenak P. and Bergman R.: X-ray phase analysis of martensitic transformations in austenitic stainless steels electrochemically charged with hydrogen. Material Science & Engineering A, Vol. 437 (2006), No. 2, pp. 366–378.

    Article  Google Scholar 

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Correspondence to Tobias Mente.

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Mente, T., Bollinghaus, T. Modeling Of Hydrogen Distributionin A Duplex Stainless Steel. Weld World 56, 66–78 (2012). https://doi.org/10.1007/BF03321397

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